Enhanced mechanical properties of ammonia-modified graphene nanosheets/epoxy nanocomposites

RSC Advances ◽  
2015 ◽  
Vol 5 (36) ◽  
pp. 28098-28104 ◽  
Author(s):  
Dong-Dong Zhang ◽  
Dong-Lin Zhao ◽  
Ran-Ran Yao ◽  
Wei-Gang Xie
Keyword(s):  
Mechanical Properties ◽  
Epoxy Matrix ◽  
Graphene Nanosheets ◽  
Amine Functionalization ◽  
Epoxy Nanocomposites ◽  
Obvious Effect ◽  
Mechanical Performances ◽  
Modified Graphene ◽  
Matrix Nanocomposites

The amine-functionalization of GNSs with ammonia had an obvious effect on the mechanical performances of epoxy matrix nanocomposites.

Effects of ionic liquid types on the tribological, mechanical, and thermal properties of ionic liquid modified graphene/polyimide shape memory composites

2021 ◽  
pp. 095400832199676
Author(s):  
Yuting Ouyang ◽  
Qiu Zhang ◽  
Xiukun Liu ◽  
Ruan Hong ◽  
Xu Xu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Ionic Liquid ◽  
Composite Materials ◽  
Shape Memory ◽  
Recovery Rate ◽  
Shape Recovery ◽  
Graphene Nanosheets ◽  
Mechanical And Thermal Properties ◽  
Thermal And Mechanical Properties ◽  
Modified Graphene

Different ionic liquid modified graphene nanosheets (IG) were induced into polyimide (PI) to improve the tribological, thermal, and mechanical properties of shape memory IG/PI composites. The results demonstrated that when using 1-aminoethyl-3-methylimidazole bromide to modify graphene nanosheets (IG-1), the laser-driven shape recovery rate of IG-1/PI composites (IGPI-1) reached 73.02%, which was 49.36% higher than that of pure PI. In addition, the IGPI-1 composite materials reached the maximum shape recovery rate within 15 s. Additionally, under dry sliding, the addition of IG can significantly improve the tribological properties of composite materials. IGPI-1 exhibited the best self-lubricating properties. Compared with pure PI, the friction coefficient (0.19) and wear rate (2.62 × 10–5) mm3/Nm) were reduced by 44.1% and 24.2%, respectively, and the T10% of IGPI-1 increased by 32.2°C. The Tg of IGPI-1 reached 256.5°C, which was 8.4°C higher than that of pure PI. In addition, the tensile strength and modulus of IGPI-1 reached 82.3 MPa and 1.18 GPa, which were significantly increased by 33.6% and 29.8%, respectively, compared with pure PI. We hope that this work will be helpful for the preparation of shape memory materials with excellent tribological, thermal, and mechanical properties.

Moisture Effect on Mechanical Properties of Graphene/Epoxy Nanocomposites

2016 ◽  
Vol 32 (6) ◽  
pp. 673-682 ◽  
Author(s):  
H.-K. Liu ◽  
Y.-C. Wang ◽  
T.-H. Huang
Keyword(s):  
Mechanical Properties ◽  
Graphene Oxide ◽  
Moisture Absorption ◽  
Graphene Nanosheets ◽  
Salt Water ◽  
Testing Machine ◽  
Weight Fraction ◽  
Epoxy Nanocomposites ◽  
Moisture Effect ◽  
Superior Mechanical Properties

Abstract2-D graphene nanosheets (GNS) not only have superior mechanical properties, but stacking of GNS in composites is expected to inhibit moisture absorption. In this paper, moisture effect on tensile strength of graphene/epoxy nanocomposites is investigated. Two kinds of graphene reinforcements are used including graphene oxide (GO) and reduced graphene oxide (RGO) with reinforcement weight fraction WGO or WRGO in the range of 0.5 to 3.0wt%. A dispersion agent acetone is added in nanocomposites to enhance graphene dispersion. To evaluate moisture influence, those nanocomposites are soaked in two kinds of liquid including deionized water (DIW) and salt water (saline solution) for seven kinds of soaking periods of time including 24, 48, 72, 100, 400 hours, 30 days, and 60 days. After soaking test, diffusion coefficients of various composites are evaluated; besides tensile strengths of composites are measured by microforce testing machine. In order to correlate the strength with microstructure evolution, several techniques are adopted to analyze morphologies and functionalities of reinforcements and fracture surface of composites. They include Raman spectroscope, X-ray photoelectron spectroscope, and SEM. 2-D GNS are found to effectively enhance nanocomposites by moisture attack, and their corresponding reinforcing mechanisms are proposed.

Enhanced mechanical properties of epoxy‐matrix nanocomposites reinforced with graphene synthesized in atmospheric plasmas

2020 ◽  
Vol 17 (5) ◽  
pp. 1900244 ◽  
Author(s):  
Kevin Nakahara ◽  
Jacob Knego ◽  
Taylor Sloop ◽  
Chance Bisquera ◽  
Nicole Subler ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Epoxy Matrix ◽  
Atmospheric Plasmas ◽  
Matrix Nanocomposites

MICROSTRUCTURE AND RESISTIVITY OF CARBON NANOTUBE AND NANOFIBER/EPOXY MATRIX NANOCOMPOSITE

2002 ◽  
Vol 01 (05n06) ◽  
pp. 719-723 ◽  
Author(s):  
JIN-HONG DU ◽  
ZHE YING ◽  
SHUO BAI ◽  
FENG LI ◽  
CHAO SUN ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Epoxy Matrix ◽  
Single Walled Carbon Nanotubes ◽  
Epoxy Nanocomposites ◽  
Multiwalled Carbon ◽  
Pure Epoxy ◽  
The Matrix ◽  
Walled Carbon Nanotubes ◽  
Matrix Nanocomposites ◽  
Matrix Nanocomposite

Single-walled carbon nanotubes (SWNTs), multiwalled carbon nanotubes (MWNTs) and vapor-grown carbon nanofibers (VGCNFs)/epoxy matrix nanocomposites were prepared, respectively. The microstructure of the nanocomposites was observed by SEM and the resistivities of the nanocomposites with different concentration of CNTs/VGCNFs were measured. Based on the experimental results, the dispersion of SWNTs and MWNTs were relatively poor but that of VGCNFs is uniform within the matrix. The resistivitiy of pure epoxy is about 1010.5Ω · cm and several orders of magnitude higher than those of SWNT, MWNT and VGCNF/epoxy nanocomposites. The resistivities of the nanocomposites drop with the increase of the CNTs/VGCNFs content in the matrix and the resistivity of VGCNFs/epoxy nanocomposites was much lower than that of CNT/epoxy nanocomposites.

Thiokol oligomer functionalized MWCNTs for epoxy nanocomposites

2020 ◽  
Vol 49 (5) ◽  
pp. 347-353
Author(s):  
Haosheng Wang ◽  
Zewen Li
Keyword(s):  
Mechanical Properties ◽  
Photoelectron Spectroscopy ◽  
Epoxy Matrix ◽  
Interfacial Interaction ◽  
Mechanical And Thermal Properties ◽  
Gravimetric Analysis ◽  
Epoxy Nanocomposites ◽  
Content Type ◽  
The Impact ◽  
Functionalized Mwcnts

Purpose This paper aims to feature preparation and characterization of thiokol oligomer functionalized MWCNTs/epoxy nanocomposites using low molecular weight polyamide as curing agent. Design/methodology/approach First, thiokol oligomer functionalized MWCNTs (MWCNTs-TO) were prepared through hydroxylation, silanization and graft modification of MWCNTs. The nanocomposite specimens were fabricated through sonication and cast moulding process. The authors then investigated the impact of MWCNTs-TO content on mechanical and thermal properties of the nanocomposites. Findings MWCNTs-TO with grafting ratio of 17.5 Wt.% was synthesized and characterized with X-ray photoelectron spectroscopy, thermal gravimetric analysis, Fourier transform infrared and scanning electron microscopy. The obtained epoxy nanocomposites exhibit improved mechanical properties and thermal stability with MWCNTs-TO added. Moreover, desirable results were obtained at 0.75 Wt.% of MWCNTs-TO loading: the young’s modulus, tensile, flexural and impact strength increased by 24.6,72.8,34.8 and 82.7%, respectively, compared to the neat epoxy. The improvement of mechanical properties is mainly attributed to enhanced interfacial interaction and dispersion between the covalent functionalized MWCNTs and epoxy matrix. Research limitations/implications A flexible thiokol oligomer was successfully grafted onto MWCNTs via a mild route. Nanocomposites with excellent interfacial interaction and dispersion between MWCNTs-TO and the epoxy matrix have been successfully fabricated and investigated. Practical implications This method provided a mild and practical approach to improve the performance of MWCNTs epoxy nanocomposites. Originality/value A flexible thiokol oligomer was successfully covalent grafted onto MWCNTs via a mild route. Nanocomposites with excellent interfacial interaction and dispersion between MWCNTs-TO and the epoxy matrix have been successfully fabricated and investigated.

scholarly journals Bioinspired modified graphene oxide/polyurethane composites with rapid self-healing performance and excellent mechanical properties

RSC Advances ◽  
2021 ◽  
Vol 11 (24) ◽  
pp. 14665-14677
Author(s):  
Yahao Liu ◽  
Jian Zheng ◽  
Xiao Zhang ◽  
Yongqiang Du ◽  
Guibo Yu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Graphene Oxide ◽  
Molecular Design ◽  
Self Healing ◽  
Modified Graphene Oxide ◽  
Rational Molecular Design ◽  
Mechanical Performances ◽  
Modified Graphene ◽  
Polyurethane Composites ◽  
Hyperbranched Polyamide

We successfully modified graphene oxide with amino-terminated hyperbranched polyamide(MGO), and obtained novel mussel-inspired MGO/polyurethane composites with outstanding self-healing and mechanical performances via rational molecular design.

Remarkable Mechanical and Thermal Increments of Epoxy Composites by Graphene Nanosheets and Carbon Nanotubes Synergetic Reinforcement

2017 ◽  
Vol 727 ◽  
pp. 546-552
Author(s):  
Xia Jun Wang ◽  
Dong Lin Zhao ◽  
Dong Dong Zhang ◽  
Cheng Li ◽  
Ran Ran Yao
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Carbon Nanotubes ◽  
Epoxy Matrix ◽  
Graphene Nanosheets ◽  
Synergetic Effect ◽  
Epoxy Composites ◽  
Matrix Composites ◽  
Conductivity Enhancement ◽  
Hybrid Fillers

Graphene nanosheets (GNSs) were modified with aqueous ammonia and hydrogen peroxide, to obtain amine (–NH2) functionalized GNSs (AFGNSs) and enhance the bondings between the GNSs and epoxy matrix. We report an easy and efficient approach to improve the mechanical properties and thermal conductivity of epoxy matrix composites by combining one dimensional multi-walled carbon nanotubes and two dimensional AFGNSs. The long and tortuous MWCNTs can bridge adjacent AFGNSs and inhibit their aggregation, resulting in an increased contact surface area between GNS/MWCNT structures and the polymer. A remarkable synergetic effect between the GNSs and MWCNTs on the enhanced mechanical properties and thermal conductivity of the epoxy composites was demonstrated. The addition of 2 wt.% MWCNT-GNS hybrid fillers improved the tensile strength and flexural strength of the pristine epoxy by 20.71% and 55.51%, respectively. Thermal conductivity increased by 93.71% using MWCNT-GNS hybrid fillers compared to non-derivatised epoxy. This study has demonstrated that 2-D GNSs and 1-D MWCNTs have an obvious synergetic reinforcing effect on the mechanical properties and a remarkable thermal conductivity enhancement in epoxy composites which provides an easy and effective way to design and improve the properties of composite materials.

scholarly journals Functionalization of Multi-Walled Carbon Nanotubes Via UV/O3 and Silane Treatments

2007 ◽  
Vol 334-335 ◽  
pp. 797-800
Author(s):  
Peng Cheng Ma ◽  
Jang Kyo Kim ◽  
Ben Zhong Tang
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Epoxy Matrix ◽  
Covalent Bonding ◽  
Combined Process ◽  
Chemical Functionalization ◽  
Multi Walled Carbon Nanotubes ◽  
Ft Ir ◽  
Walled Carbon Nanotubes ◽  
Matrix Nanocomposites

This paper presents a method for chemical functionalization of CNTs through the combined process of UV/O3 treatment and silanization process. FT-IR and TEM were employed to characterize the changes in surface functionalities and morphology. The results indicate improved dispersion and attachment of silane molecules on the surface of CNTs. Epoxy matrix nanocomposites containing functionalized CNTs showed much better dispersion with associated higher mechanical properties than those without functionalization. These findings confirmed the improved interfacial interactions due to covalent bonding between the functionalized CNTs and epoxy resin.

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