Impact Modification of Polyamide 11 by the Reactive Blending with Epoxy Group Modified Polyethylene

2006 ◽  
Vol 6 (12) ◽  
pp. 3915-3918 ◽  
Author(s):  
Yuko Oono ◽  
Yongjin Li ◽  
Kazuo Nakayama ◽  
Hiroshi Shimizu
Keyword(s):  
Epoxy Group ◽  
Reactive Blending ◽  
Polyamide 11 ◽  
Impact Modification

Toughened Poly(Trimethylene Terephthalate) by Reactive Blending with PTW

2018 ◽  
Vol 777 ◽  
pp. 70-74
Author(s):  
Kun Yan Wang
Keyword(s):  
Fracture Toughness ◽  
Impact Strength ◽  
Glycidyl Methacrylate ◽  
Epoxy Group ◽  
Hydroxyl Groups ◽  
Reactive Blending ◽  
Izod Impact ◽  
Trimethylene Terephthalate ◽  
Poly Ethylene ◽  
Fractured Surface

New toughened poly (trimethylene terephthalate) (PTT) materials were obtained by reactive blending with poly (ethylene-butylacrylate-glycidyl methacrylate) (PTW). Morphology observation showed the well-dispersed domains of PTW in PTT matrix. The notched impact strength of the blends with 30wt% PTW is obviously higher than that of pure PTT. PTT-g-PTW copolymer as compatibilizer was formed by the interfacial reaction between the end epoxy group of PTW and the carboxylic or hydroxyl groups at the chain ends of PTT in the blends. Large number of stretched polymeric fibrils are uniformly distributed on the Izod impact fractured surface, which leads to an improvement in fracture toughness due to the consumption of fracture energy.

Reactive Blending in a Twin Screw Extruder

1996 ◽  
Vol 11 (2) ◽  
pp. 139-146 ◽  
Author(s):  
A. De Loor ◽  
P. Cassagnau ◽  
A. Michel ◽  
L. Delamare ◽  
B. Vergnes
Keyword(s):  
Twin Screw Extruder ◽  
Reactive Blending ◽  
Screw Extruder ◽  
Twin Screw

scholarly journals Reaction Mechanism and Mechanical Property Improvement of Poly(Lactic Acid) Reactive Blending with Epoxy Resin

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2429
Author(s):  
Krittameth Kiatiporntipthak ◽  
Nanthicha Thajai ◽  
Thidarat Kanthiya ◽  
Pornchai Rachtanapun ◽  
Noppol Leksawasdi ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Epoxy Resin ◽  
Softening Temperature ◽  
Poly Lactic Acid ◽  
Mechanical And Thermal Properties ◽  
Nanoparticle Dispersion ◽  
Reactive Blending ◽  
Partial Miscibility ◽  
Epoxy Blends ◽  
Epoxy Content

Polylactic acid (PLA) was melt-blended with epoxy resin to study the effects of the reaction on the mechanical and thermal properties of the PLA. The addition of 0.5% (wt/wt) epoxy to PLA increased the maximum tensile strength of PLA (57.5 MPa) to 67 MPa, whereas the 20% epoxy improved the elongation at break to 12%, due to crosslinking caused by the epoxy reaction. The morphology of the PLA/epoxy blends showed epoxy nanoparticle dispersion in the PLA matrix that presented a smooth fracture surface with a high epoxy content. The glass transition temperature of PLA decreased with an increasing epoxy content owing to the partial miscibility between PLA and the epoxy resin. The Vicat softening temperature of the PLA was 59 °C and increased to 64.6 °C for 0.5% epoxy. NMR confirmed the reaction between the -COOH groups of PLA and the epoxy groups of the epoxy resin. This reaction, and partial miscibility of the PLA/epoxy blend, improved the interfacial crosslinking, morphology, thermal properties, and mechanical properties of the blends.

Synthesis and Characterization of Reduced Graphene Oxide

2013 ◽  
Vol 678 ◽  
pp. 56-60 ◽  
Author(s):  
Cherukutty Ramakrishnan Minitha ◽  
Ramasamy Thangavelu Rajendrakumar
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Graphite Oxide ◽  
High Performance ◽  
Structural Changes ◽  
Epoxy Group ◽  
Xrd Analysis ◽  
Si Substrates ◽  
Reduced Graphene ◽  
Reduced Graphite Oxide

Reduced graphene oxide is an excellent candidate for various electronic devices such as high performance gas sensors. In this work Graphene oxide was prepared by oxidizing graphite to form graphite oxide. From XRD analysis the peak around 11.5o confirmed that the oxygen was intercalated into graphite. By using hydrazine hydrate, the epoxy group in graphite oxide was reduced then the solution of reduced graphite oxide (rGO) is exfoliated. Raman spectrum of rGO contains both G band (1580 cm-1), D band (1350 cm-1). The remarkable structural changes reveals that reduction of graphene oxide from the values of ID/IG ratio that increase from 0.727 (GO) to 1.414 (rGO). The exfoliated reduced graphite oxide solution is spin coated on to the SiO2/Si substrates.

Fabrication and performance of shape‐stable phase change materials based on epoxy group crosslinking

2021 ◽  
Vol 138 (28) ◽  
pp. 50681
Author(s):  
Lijuan Tao ◽  
Sai Chen ◽  
Haihui Liu ◽  
Na Han ◽  
Wei Li ◽  
...  
Keyword(s):  
Phase Change ◽  
Phase Change Materials ◽  
Epoxy Group ◽  
Stable Phase ◽  
And Performance

Wear behavior of polyamide 11 reinforced with titanate nanotubes

2021 ◽  
pp. 089270572110133
Author(s):  
Ayrton Alef Castanheira Pereira ◽  
José Roberto Moraes d’Almeida
Keyword(s):  
Wear Behavior ◽  
Roughness Parameter ◽  
Sodium Content ◽  
Titanate Nanotubes ◽  
Wear Performance ◽  
Polyamide 11 ◽  
High Sodium ◽  
Parameter Variations ◽  
Key Factor ◽  
Open Question

Besides polyamide 11 (PA 11) outstanding properties, wear performance is considered a key factor for its continued widespread use. TiTanate NanoTubes (TTNT) have a huge potential as reinforcement in polymer matrix nanocomposites, and although nanotubes reinforcement capacity is well understood, its effect on tribological characteristics is still an open question. Thus, the present work has as objective to study the wear behavior of PA 11 and its nanocomposites, highlighting TTNT loading, functionalization and sodium content effects. Seeking the possibility to tailor properties, surface topography is investigated. Based on parameter classification, correlation and functional sense, an ideal roughness parameter set is defined. By taking measurements in X- and Y-axis, parameter variations and sensibility are also analyzed. From the results, maximum wear resistance can be reached in functionalized samples with low TTNT loading and high sodium content. Some roughness parameters demonstrate a moderate to strong correlation with wear performance. Parameter variations are mainly attributed to the non-stationarity of the surface.

A novel recycled polyethylene terephthalate/polyamide 11 (rPET/PA11) thermoplastic blend

2021 ◽  
pp. 147776062110010
Author(s):  
Zahid Iqbal Khan ◽  
Zurina Binti Mohamad ◽  
Abdul Razak Bin Rahmat ◽  
Unsia Habib ◽  
Nur Amira Sahirah Binti Abdullah
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Flexural Strength ◽  
Polyethylene Terephthalate ◽  
Practical Implication ◽  
Polyamide 11 ◽  
Recycled Polyethylene ◽  
Twin Screw ◽  
Electron Microscopy Analysis ◽  
The Impact

This work explores a novel blend of recycled polyethylene terephthalate/polyamide 11 (rPET/PA11). The blend of rPET/PA11 was introduced to enhance the mechanical properties of rPET at various ratios. The work’s main advantage was to utilize rPET in thermoplastic form for various applications. Three different ratios, i.e. 10, 20 and 30 wt.% of PA11 blend samples, were prepared using a twin-screw extruder and injection moulding machine. The mechanical properties were examined in terms of tensile, flexural and impact strength. The tensile strength of rPET was improved more than 50%, while the increase in tensile strain was observed 42.5% with the addition of 20 wt.% of PA11. The improved properties of the blend were also confirmed by the flexural strength of the blends. The flexural strength was increased from 27.9 MPa to 48 MPa with the addition of 30 wt.% PA11. The flexural strain of rPET was found to be 1.1%. However, with the addition of 10, 20 and 30 wt.% of PA11, the flexural strain was noticed as 1.7, 2.1, and 3.9% respectively. The impact strength of rPET/PA11 at 20 wt.% PA11 was upsurged from 110.53 to 147.12 J/m. Scanning electron microscopy analysis revealed a dispersed PA11 domain in a continuous rPET matrix morphology of the blends. This work practical implication would lead to utilization of rPET in automobile, packaging, and various industries.

scholarly journals A Comprehensive Investigation on 3D Printing of Polyamide 11 and Thermoplastic Polyurethane via Multi Jet Fusion

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2139
Author(s):  
Wei Shian Tey ◽  
Chao Cai ◽  
Kun Zhou
Keyword(s):  
Tensile Strength ◽  
Flexural Strength ◽  
Wear Rate ◽  
Mechanical Performance ◽  
Thermoplastic Polyurethane ◽  
Print Quality ◽  
Polyamide 11 ◽  
Powder Bed

Multi Jet Fusion (MJF) is a recently developed polymeric powder bed fusion (PBF) additive manufacturing technique that has received considerable attention in the industrial and scientific community due to its ability to fabricate functional and complex polymeric parts efficiently. In this work, a systematic characterization of the physicochemical properties of MJF-certified polyamide 11 (PA11) and thermoplastic polyurethane (TPU) powder was conducted. The mechanical performance and print quality of the specimens printed using both powders were then evaluated. Both PA11 and TPU powders showed irregular morphology with sharp features and had broad particle size distribution, but such features did not impair their printability significantly. According to the DSC scans, the PA11 specimen exhibited two endothermic peaks, while the TPU specimen exhibited a broad endothermic peak (116–150 °C). The PA11 specimens possessed the highest tensile strength in the Z orientation, as opposed to the TPU specimens which possessed the lowest tensile strength along the same orientation. The flexural properties of the PA11 and TPU specimens displayed a similar anisotropy where the flexural strength was highest in the Z orientation and lowest in the X orientation. The porosity values of both the PA11 and the TPU specimens were observed to be the lowest in the Z orientation and highest in the X orientation, which was the opposite of the trend observed for the flexural strength of the specimens. The PA11 specimen possessed a low coefficient of friction (COF) of 0.13 and wear rate of 8.68 × 10−5 mm3/Nm as compared to the TPU specimen, which had a COF of 0.55 and wear rate of 0.012 mm3/Nm. The PA11 specimens generally had lower roughness values on their surfaces (Ra < 25 μm), while the TPU specimens had much rougher surfaces (Ra > 40 μm). This investigation aims to uncover and explain phenomena that are unique to the MJF process of PA11 and TPU while also serving as a benchmark against similar polymeric parts printed using other PBF processes.

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