Atomic Force Microscopic Observation of the Molecular Orientation in Ultrathin Films of Alkanoic Acid-Derivatized Porphyrins on a Mica Surface

2002 ◽  
Vol 2 (1) ◽  
pp. 37-40 ◽  
Author(s):  
Toyoko Imae ◽  
Tohru Niwa ◽  
Zhijun Zhang
2011 ◽  
Vol 47 (17) ◽  
pp. 4974 ◽  
Author(s):  
Shigeto Inoue ◽  
Takayuki Uchihashi ◽  
Daisuke Yamamoto ◽  
Toshio Ando

2005 ◽  
Vol 106 ◽  
pp. 117-122 ◽  
Author(s):  
Izabela Szafraniak ◽  
Dietrich Hesse ◽  
Marin Alexe

Self-patterning presents an appealing alternative to lithography for the production of arrays of nanoscale ferroelectric capacitors for use in high density non-volatile memory devices. Recently a self-patterning method, based on the use of the instability of ultrathin films during hightemperature treatments, was used to fabricate nanosized ferroelectrics. This paper reports the use of the method for the preparation of PZT nanoislands on different single crystalline substrates - SrTiO3, MgO and LaAlO3. Moreover, a multi-step deposition procedure in order to control lateral the dimension of the crystals was introduced. The nanostructures obtained were studied by atomic force microscopy, scanning electron microscopy and X-ray diffraction.


2009 ◽  
Vol 13 (07) ◽  
pp. 774-778 ◽  
Author(s):  
Byung-Soon Kim ◽  
Young-A Son

In this study, self-assembled alternating film using poly(diallyldimethylammonium chloride) (PDDAC) and meso-tetrakis(4-carboxyphenyl)porphyrin (MTCP) was prepared as a multilayer deposition on glass substrate. This preparation technique for dye deposition may provide new feasibilities to achieve the manufacture of ultrathin films for nanotechnology application. The deposition films were characterized by UV-vis spectrophotometer and Atomic Force Microscopy (AFM) analysis. The results of UV-vis spectra showed that the absorbance characteristic of the multilayer films linearly increased with an increased number of PDDAC and MTCP bilayers. AFM analysis showed the film surface was relatively uniform and the progressive growth of layers was determined.


2011 ◽  
Vol 480-481 ◽  
pp. 624-628
Author(s):  
Wei Xu ◽  
Qiu Feng An ◽  
Wei Xu

A novel polysiloxane (PSA-PFMS) fabric finishing agent, bearing pendant stearyl acrylate, polyether, epoxy and trifluoropropyl side groups, etc., was synthesized by hydrosilylation of polytrifluoropropylhydromethylsiloxane (PFHMS), stearyl acrylate (SA), allylpolyoxyethylene ether (PEO) and allylglyeidyl ether (AGE). The chemical structure of PSA-PFMS was characterized by infrared spectrum (IR) and proton nuclear magnetic resonance (1H NMR). Film morphology and molecular orientation of PSA-PFMS on silicon wafer substrate surface were observed by atomic force microscope (AFM). Results show that PSA-PFMS can form an inhomogeneous and hydrophobic polysiloxane film with rough, scraggly and microscopic phase separation structures. All of these suggest that the molecular orientation of PSA-PFMS is in such a manner that the stearyl acrylate groups, trifluoropropyl and silicon methyl groups project outward into air, while polyether and Si-O dipole bonds point to the silicon wafer substrate surface. Owing to this highly rough and microscopic phase-separated hydrophobic film and its tight link with fabric, the treated fabrics are altered from hydrophile to hydrophobe with water contact angle of 129.2° and possess favorable washing endurance with WCA of 106.7° after 20 times of standard soaping procedure.


1996 ◽  
Vol 25 (10) ◽  
pp. 857-858 ◽  
Author(s):  
Yushi Oishi ◽  
Takayuki Kato ◽  
Miyuki Kuramori ◽  
Kazuaki Suehiro ◽  
Katsuhiko Ariga ◽  
...  

Structure ◽  
2013 ◽  
Vol 21 (11) ◽  
pp. 1992-2002 ◽  
Author(s):  
Kentaro Noi ◽  
Daisuke Yamamoto ◽  
Shingo Nishikori ◽  
Ken-ichi Arita-Morioka ◽  
Takayuki Kato ◽  
...  

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