scholarly journals Laser-Induced Fluorescence Study on Reactions of C+(2P) and C(1D,1S) With Alcohols Leading to CH(X2Π) Radicals at Thermal Energy

1987 ◽  
Vol 7 (5-6) ◽  
pp. 333-341 ◽  
Author(s):  
Masaharu Tsuji ◽  
Ichiro Nagano ◽  
Nobuaki Nishiyama ◽  
Hiroshi Sekiya ◽  
Yukio Nishimura

Thermal energy reactions of C+(2P) and C(1D,1S) with CH3OH, C2H5OH, n-C3H7OH and i-C3H7OH to give CH(X2Π) radicals have been investigated by observing laser-induced fluorescence (LIF) spectra of CH(A—X) in a flowing afterglow. In the hydride ion abstraction by C+(2P), only CH3OH exhibited the CH(A—X) LIF spectrum with a vibrational distribution of 1.0 : 0.62 for v″ = 0 and 1, respectively. On the other hand, the CH(A—X) LIF spectra exclusively from v″ = 0 were observed in the reactions of C(1D,1S) with all alcohols studied. By isotopic substitution for CH3OH it was shown that the CH(X) radicals arise from the selective attack on the methyl site in the reactions of C+(2P) and C(1D,1S) with methanol.

1986 ◽  
Vol 5 (6) ◽  
pp. 385-392 ◽  
Author(s):  
R. Naaman

The reactions of Ba with CF3I dimers and CH3IAr complexes were studied applying the laser induced fluorescence (LIF) technique. It was found that the BaI produced from the dimers contains about 20 kcal/mole less vibrational energy than the BaI produced in the corresponding monomeric reaction. The CH3IAr on the other hand, yielded only a slightly colder vibrational distribution than the monomers.


2020 ◽  
Vol 12 (5) ◽  
pp. 1921 ◽  
Author(s):  
Makiko Ukai ◽  
Masaya Okumiya ◽  
Hideki Tanaka

A desiccant air handling unit is one of the major types of dehumidification handling systems and requires hot water or hot air to regenerate sorption materials. If solar thermal energy is used as the heat source for regeneration, in general, a backup electrical heater, backup boiler, or combined heat and power (CHP) is installed in order to maintain a stable hot water supply. In this study, effective control is proposed for a desiccant air handling system that uses solar thermal energy (flexible control), and its energy performance is compared to that of a traditional control (the fixed control) through a system simulation. The diurnal behavior shows that the system with a fixed control without a backup boiler cannot process the latent load properly (28 GJ of unprocessed latent load for July and August). On the other hand, the system with a flexible control without a backup boiler is able to process required latent heat load. Based on the fact that the fixed control needs a backup boiler to process the latent load, the system with a fixed control with a backup boiler is considered for the energy performance comparison. The simulation results show that the primary energy-based coefficient of performance (hereafter, COP) of the system with a flexible control without a backup boiler reaches 1.56. On the other hand, the primary energy-based COP of the system with a fixed control with a backup boiler reaches only 1.43. This proves that the flexible control contributes to the higher energy performance of the system and maximizes the use of solar thermal energy more than the fixed control.


1999 ◽  
Vol 173 ◽  
pp. 249-254
Author(s):  
A.M. Silva ◽  
R.D. Miró

AbstractWe have developed a model for theH2OandOHevolution in a comet outburst, assuming that together with the gas, a distribution of icy grains is ejected. With an initial mass of icy grains of 108kg released, theH2OandOHproductions are increased up to a factor two, and the growth curves change drastically in the first two days. The model is applied to eruptions detected in theOHradio monitorings and fits well with the slow variations in the flux. On the other hand, several events of short duration appear, consisting of a sudden rise ofOHflux, followed by a sudden decay on the second day. These apparent short bursts are frequently found as precursors of a more durable eruption. We suggest that both of them are part of a unique eruption, and that the sudden decay is due to collisions that de-excite theOHmaser, when it reaches the Cometopause region located at 1.35 × 105kmfrom the nucleus.


Author(s):  
A. V. Crewe

We have become accustomed to differentiating between the scanning microscope and the conventional transmission microscope according to the resolving power which the two instruments offer. The conventional microscope is capable of a point resolution of a few angstroms and line resolutions of periodic objects of about 1Å. On the other hand, the scanning microscope, in its normal form, is not ordinarily capable of a point resolution better than 100Å. Upon examining reasons for the 100Å limitation, it becomes clear that this is based more on tradition than reason, and in particular, it is a condition imposed upon the microscope by adherence to thermal sources of electrons.


Author(s):  
K.H. Westmacott

Life beyond 1MeV – like life after 40 – is not too different unless one takes advantage of past experience and is receptive to new opportunities. At first glance, the returns on performing electron microscopy at voltages greater than 1MeV diminish rather rapidly as the curves which describe the well-known advantages of HVEM often tend towards saturation. However, in a country with a significant HVEM capability, a good case can be made for investing in instruments with a range of maximum accelerating voltages. In this regard, the 1.5MeV KRATOS HVEM being installed in Berkeley will complement the other 650KeV, 1MeV, and 1.2MeV instruments currently operating in the U.S. One other consideration suggests that 1.5MeV is an optimum voltage machine – Its additional advantages may be purchased for not much more than a 1MeV instrument. On the other hand, the 3MeV HVEM's which seem to be operated at 2MeV maximum, are much more expensive.


2005 ◽  
Vol 19 (3) ◽  
pp. 129-132 ◽  
Author(s):  
Reimer Kornmann

Summary: My comment is basically restricted to the situation in which less-able students find themselves and refers only to literature in German. From this point of view I am basically able to confirm Marsh's results. It must, however, be said that with less-able pupils the opposite effect can be found: Levels of self-esteem in these pupils are raised, at least temporarily, by separate instruction, academic performance however drops; combined instruction, on the other hand, leads to improved academic performance, while levels of self-esteem drop. Apparently, the positive self-image of less-able pupils who receive separate instruction does not bring about the potential enhancement of academic performance one might expect from high-ability pupils receiving separate instruction. To resolve the dilemma, it is proposed that individual progress in learning be accentuated, and that comparisons with others be dispensed with. This fosters a self-image that can in equal measure be realistic and optimistic.


Author(s):  
Stefan Krause ◽  
Markus Appel

Abstract. Two experiments examined the influence of stories on recipients’ self-perceptions. Extending prior theory and research, our focus was on assimilation effects (i.e., changes in self-perception in line with a protagonist’s traits) as well as on contrast effects (i.e., changes in self-perception in contrast to a protagonist’s traits). In Experiment 1 ( N = 113), implicit and explicit conscientiousness were assessed after participants read a story about either a diligent or a negligent student. Moderation analyses showed that highly transported participants and participants with lower counterarguing scores assimilate the depicted traits of a story protagonist, as indicated by explicit, self-reported conscientiousness ratings. Participants, who were more critical toward a story (i.e., higher counterarguing) and with a lower degree of transportation, showed contrast effects. In Experiment 2 ( N = 103), we manipulated transportation and counterarguing, but we could not identify an effect on participants’ self-ascribed level of conscientiousness. A mini meta-analysis across both experiments revealed significant positive overall associations between transportation and counterarguing on the one hand and story-consistent self-reported conscientiousness on the other hand.


2019 ◽  
Vol 50 (2) ◽  
pp. 80-93
Author(s):  
Jort de Vreeze ◽  
Christina Matschke

Abstract. Not all group memberships are self-chosen. The current research examines whether assignments to non-preferred groups influence our relationship with the group and our preference for information about the ingroup. It was expected and found that, when people are assigned to non-preferred groups, they perceive the group as different to the self, experience negative emotions about the assignment and in turn disidentify with the group. On the other hand, when people are assigned to preferred groups, they perceive the group as similar to the self, experience positive emotions about the assignment and in turn identify with the group. Finally, disidentification increases a preference for negative information about the ingroup.


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