scholarly journals A Comparative Study of the Micropore Structure between the Transitional and Marine Shales in China

Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-14
Author(s):  
Pengfei Jiao ◽  
Genshun Yao ◽  
Shangwen Zhou ◽  
Zhe Yu ◽  
Shiluo Wang
Keyword(s):  
Natural Gas ◽  
Shale Gas ◽  
Ordos Basin ◽  
Organic Carbon Content ◽  
Type I ◽  
Gas Generation ◽  
Longmaxi Formation ◽  
Micropore Structure ◽  
Marine Shale ◽  
Longmaxi Shale

To compare the micropore structure of marine-continental transitional shale with marine shale, organic geochemical, field emission scanning electron microscopy, and low-temperature nitrogen adsorption experiments were conducted on shale samples from the Shanxi Formation in the eastern Ordos Basin and the Longmaxi Formation in the southern Sichuan Basin. The results show that Shanxi Formation shale has a smaller specific surface area and pore volume than Longmaxi Formation shale; therefore, the transitional shales fail to provide sufficient pore spaces for the effective storage and preservation of natural gas. Both the transitional and marine shales are in an overmature stage with high total organic carbon content, but they differ considerably in pore types and development degrees. Inorganic pores and fractures are dominantly developed in transitional shales, such as intragranular pores and clay mineral interlayer fractures, while organic nanopores are rarely developed. In contrast, organic pores are the dominant pore type in the marine shales and inorganic pores are rarely observed. The fractal analysis also shows that pore structure complexity and heterogeneity are quite different. These differences were related to different organic types, i.e., type I of marine shale and type III of transitional shale. Marine Longmaxi shale has experienced liquid hydrocarbon cracking, gas generation, and pore-forming processes, providing good conditions for natural gas to be preserved. However, during the evolution of transitional Shanxi shale, gas cannot be effectively preserved due to the lack of the above evolution processes, leading to the poor gas-bearing property. The detailed comparison of the micropore structure between the transitional and marine shales is of great importance for the future exploitation of marine-continental transitional shale gas in China.

Well logging evaluation of the shale gas potential in the lower Silurian Longmaxi Formation, Weiyuan, southern Sichuan Basin, China

2021 ◽  
pp. 1-64
Author(s):  
Guangzhao Zhou ◽  
Zhiming Hu ◽  
Xiangui Liu ◽  
Xianggang Duan ◽  
Jin Chang
Keyword(s):  
Spatial Distribution ◽  
Shale Gas ◽  
Sichuan Basin ◽  
Vitrinite Reflectance ◽  
Well Logging ◽  
Carbonaceous Shale ◽  
Organic Carbon Content ◽  
Type I ◽  
Longmaxi Formation ◽  
Marine Shale

Recent observations of shale gas breakthroughs have in the Weiyuan marine shale gas play in the Sichuan Basin have attracted great interest. To better understand these breakthroughs, we use core description, FIB-SEM data, XRD data, organic geochemistry, and well logging data, to better understand the reservoir characteristics carbonaceous shale, calcareous shale, and siliceous shale lithology, with a focus on the organic-rich shale units. We find conventional well log methods are effective in mapping the spatial distribution of the organic-rich shale in the Weiyuan area where the. total organic carbon content in the Longmaxi Formation ranges from 1.35%-6.95%, averaging 4.42%. The kerogen is Type I-II and the vitrinite reflectance (Ro) is greater than 2.57%, which indicates that the formation is susceptible to shale gas accumulation. The clay mineral content ranges from 48 wt.% to 63 wt.% (avg. 51 wt.%).with illite and chlorite averaging 73.8% and 25.7%, respectively. The brittle mineral quartz and plagioclase content ranges from 32 wt.% to 61 wt.% (avg. 47 wt.%). Compared to the surrounding litholgic units, the marine shale exhibits relatively high GR, CNL, AC, RT, K, and U values and relatively low DEN, PE and Th/U values, allowing us to construct. Cross-plots to define the units of interest. Using the same process, we quantify the TOC content providing a spatial distribution of organic-rich shale using conventional well logging.

scholarly journals Coupling between Source Rock and Reservoir of Shale Gas in Wufeng-Longmaxi Formation in Sichuan Basin, South China

Energies ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2679
Author(s):  
Yuying Zhang ◽  
Shu Jiang ◽  
Zhiliang He ◽  
Yuchao Li ◽  
Dianshi Xiao ◽  
...  
Keyword(s):  
Source Rock ◽  
Shale Gas ◽  
Sichuan Basin ◽  
Gas Content ◽  
Potential Zone ◽  
Hydrocarbon Generation ◽  
Gas Generation ◽  
Longmaxi Formation ◽  
Siliceous Shale ◽  
Organic Pores

In order to analyze the main factors controlling shale gas accumulation and to predict the potential zone for shale gas exploration, the heterogeneous characteristics of the source rock and reservoir of the Wufeng-Longmaxi Formation in Sichuan Basin were discussed in detail, based on the data of petrology, sedimentology, reservoir physical properties and gas content. On this basis, the effect of coupling between source rock and reservoir on shale gas generation and reservation has been analyzed. The Wufeng-Longmaxi Formation black shale in the Sichuan Basin has been divided into 5 types of lithofacies, i.e., carbonaceous siliceous shale, carbonaceous argillaceous shale, composite shale, silty shale, and argillaceous shale, and 4 types of sedimentary microfacies, i.e., carbonaceous siliceous deep shelf, carbonaceous argillaceous deep shelf, silty argillaceous shallow shelf, and argillaceous shallow shelf. The total organic carbon (TOC) content ranged from 0.5% to 6.0% (mean 2.54%), which gradually decreased vertically from the bottom to the top and was controlled by the oxygen content of the bottom water. Most of the organic matter was sapropel in a high-over thermal maturity. The shale reservoir of Wufeng-Longmaxi Formation was characterized by low porosity and low permeability. Pore types were mainly <10 nm organic pores, especially in the lower member of the Longmaxi Formation. The size of organic pores increased sharply in the upper member of the Longmaxi Formation. The volumes of methane adsorption were between 1.431 m3/t and 3.719 m3/t, and the total gas contents were between 0.44 m3/t and 5.19 m3/t, both of which gradually decreased from the bottom upwards. Shale with a high TOC content in the carbonaceous siliceous/argillaceous deep shelf is considered to have significant potential for hydrocarbon generation and storage capacity for gas preservation, providing favorable conditions of the source rock and reservoir for shale gas.

scholarly journals The characteristics of hydrocarbon generation, reserving performances of fine-grained rock, and preservation conditions of coal measure shale gas of an epicontinental sea basin: A case study of the Late Palaeozoic shale gas in the Huanghebei Area of Western Shandong

2018 ◽  
Vol 37 (1) ◽  
pp. 453-472 ◽  
Author(s):  
Ying Li ◽  
Zengxue Li ◽  
Huaihong Wang ◽  
Dongdong Wang
Keyword(s):  
Coal Seam ◽  
Shale Gas ◽  
Late Paleozoic ◽  
Organic Carbon Content ◽  
Hydrocarbon Generation ◽  
Average Content ◽  
Gas Generation ◽  
Geological Structures ◽  
Fine Grained ◽  
Western Shandong

In China, marine and land transitional fine-grained rocks (shale, mudstone, and so on) are widely distributed and are known to have large accumulated thicknesses. However, shale gas explorations of these types of rock have only recently been initiated, thus the research degree is very low. Therefore, this study was conducted in order to improve the research data regarding the gas accumulation theory of marine and continental transitional fine-grained rock, as well as investigate the shale gas generation potential in the Late Paleozoic fine-grained rock masses located in the Huanghebei Area of western Shandong Province. The hydrocarbon generation characteristics of the epicontinental sea coal measures were examined using sedimentology, petrography, geochemistry, oil and gas geology, tectonics, and combined experimental testing processes. The thick fine-grained rocks were found to have been deposited in the sedimentary environments of the tidal flats, barriers, lagoons, deltas, and rivers during the Late Paleozoic in the study area. The most typical fine-grained rocks were located between the No. 5 coal seam of the Shanxi Formation and the No. 10 coal seam of the Taiyuan Formation, with an average thickness of 84.8 m. These formations were mainly distributed in the western section of the Huanghebei Area. The total organic carbon content level of the fine-grained rock was determined to be 2.09% on average, and the higher content levels were located in the western section of the Huanghebei Area. The main organic matter types of the fine-grained rock were observed to be kerogen II, followed by kerogen III. The vitrinite reflectance ( Ro) of the fine-grained rock was between 0.72 and 1.25%, which indicated that the gas generation of the dark fine-grained rock was within a favorable range, and the maturity of the rock was mainly in a medium stage in the northern section of the Huanghebei Area. It was determined that the average content of brittle minerals in the fine-grained rock was 55.7%. The dissolution pores and micro-cracks were the dominating pores in the fine-grained rock, followed by intergranular pores and intercrystalline pores. It was also found that both the porosity and permeability of the fine-grained rock were very low in the study area. The desorption gas content of the fine-grained rock was determined to be between 0.986 and 4.328 m3/t, with an average content of 2.66 m3/t. The geological structures were observed to be simple in the western section of the Huanghebei Area, and the occurrence impacts on the shale gas were minimal. However, the geological structures were found be complex in the eastern section of the study area, which was unfavorable for shale gas storage. The depths of the fine-grained rock were between 414.05 and 1290.55 m and were observed to become increasingly deeper from the southwestern section to the northern section. Generally speaking, there were found to be good reservoir forming conditions and great resource potential for marine and continental transitional shale gas in the study area.

Logging Evaluation Method and its Application for Measuring the Total Organic Carbon Content in Shale

2014 ◽  
Vol 962-965 ◽  
pp. 51-54
Author(s):  
Zhi Feng Wang ◽  
Yuan Fu Zhang ◽  
Hai Bo Zhang ◽  
Qing Zhai Meng
Keyword(s):  
Organic Carbon ◽  
Total Organic Carbon ◽  
Shale Gas ◽  
Sichuan Basin ◽  
Evaluation Method ◽  
Organic Carbon Content ◽  
Geochemical Analysis ◽  
Data Logging ◽  
Longmaxi Formation ◽  
Sedimentary Structures

The acquisition of the total organic carbon (TOC) content mainly relies on the geochemical analysis and logging data. Due to geochemical analysis is restricted by coring and experimental analysis, so it is difficult to get the continuous TOC data. Logging evaluation method for measuring TOC is very important for shale gas exploration. This paper presents a logging evaluation method that the shale is segmented according to sedimentary structures. Sedimentary structures were recognized by core, thin section and scanning electron microscope. Taking Wufeng-Longmaxi Formation, Silurian, Muai Syncline Belt, south of Sichuan Basin as research object, the shale is divided into three kinds: massive mudstone, unobvious laminated mudstone, and laminated mudstone. TOC within each mudstone are calculated using GR, resistivity and AC logging data, and an ideal result is achieved. This method is more efficient, faster and the vertical resolution is higher than △logR method.

The Gas Content Characteristics of Nanopores Developed in a Normal Pressure Shale Gas Reservoir in Southeast Chongqing, Sichuan Basin, China

2021 ◽  
Vol 21 (1) ◽  
pp. 698-706
Author(s):  
Fangwen Chen ◽  
Qiang Zheng ◽  
Hongqin Zhao ◽  
Xue Ding ◽  
Yiwen Ju ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Shale Gas ◽  
Normal Pressure ◽  
Gas Content ◽  
Organic Carbon Content ◽  
Gas Reservoir ◽  
Free Gas ◽  
Shale Gas Reservoir ◽  
Adsorbed Gas ◽  
Longmaxi Shale

To evaluate the gas content characteristics of nanopores developed in a normal pressure shale gas reservoir, the Py1 well in southeast Chongqing was selected as a case study. A series of experiments was performed to analyze the total organic carbon content, porosity and gas content using core material samples of the Longmaxi Shale from the Py1 well. The results show that the adsorbed gas and free gas content in the nanopores developed in the Py1 well in the normal pressure shale gas reservoir range from 0.46–2.24 m3/t and 0.27–0.83 m3/t, with average values of 1.38 m3/t and 0.50 m3/t, respectively. The adsorbed gas is dominant in the shale gas reservoir, accounting for 53.05–88.23% of the total gas with an average value of 71.43%. The Gas Research Institute (GRI) porosity and adsorbed gas content increase with increasing total organic carbon content. The adsorbed gas and free gas contents both increase with increasing porosity value, and the rate of increase in the adsorbed gas content with porosity is larger than that of free gas. Compared with the other five shale reservoirs in America, the Lower Silurian Longmaxi Shale in the Py1 well developed nanopores but without overpressure, which is not favorable for shale gas enrichment.

scholarly journals Shale favorable area optimization in coal-bearing series: A case study from the Shanxi Formation in Northern Ordos Basin, China

2017 ◽  
Vol 36 (5) ◽  
pp. 1295-1309 ◽  
Author(s):  
Wei Guo ◽  
Weijun Shen ◽  
Shangwen Zhou ◽  
Huaqing Xue ◽  
Dexun Liu ◽  
...  
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Total Organic Carbon ◽  
Shale Gas ◽  
Ordos Basin ◽  
Sedimentary Facies ◽  
Gas Content ◽  
Burial Depth ◽  
Organic Carbon Content ◽  
River Channels

Shales in the Well district of Yu 106 of the Shanxi Formation in the Eastern Ordos Basin is deposited in the swamp between delta plains, distributary river channels, natural levee, the far end of crevasse splay, and depression environments. According to organic geochemistry, reservoir physical property, gas bearing capacity, lithology experimental analysis, combined with the data of drilling, logging, testing and sedimentary facies, the reservoir conditions of shale gas and the distribution of an advantageous area in Shanxi Formation have been conducted. The results show that the total organic carbon content of the Shanxi Formation is relatively high, with an average content value of 5.28% in the segment 2 and 3.02% in segment 1, and the organic matter is mainly kerogen type II2 and III. The maturity of organic matter is high with 1.89% as the average value of Ro which indicates the superior condition for gas generation of this reservoir. The porosity of shales is 1.7% on average, and the average permeability is 0.0415 × 10−3 µm2. The cumulative thickness is relatively large, with an average of 75 m. Brittle mineral and clay content in shales are 49.9% and 50.1%, respectively, but the burial depth of shale is less than 3000 m. The testing gas content is relatively high (0.64 × 104 m3/d), which shows a great potential in commercial development. The total organic carbon of the segment 2 is higher than that of the segment 1, and it is also better than segment 1 in terms of gas content. Based on the thickness of shale and the distribution of sedimentary facies, it is predicted that the advantageous area of shale gas in the segment 2 is distributed in a striped zone along the northeast and the northsouth direction, which is controlled by the swamp microfacies between distributary river channels.

scholarly journals Mechanisms of shale gas generation and accumulation in the Ordovician Wufeng-Longmaxi Formation, Sichuan Basin, SW China

2017 ◽  
Vol 44 (1) ◽  
pp. 69-78 ◽  
Author(s):  
Tenger BORJIGIN ◽  
Baojian SHEN ◽  
Lingjie YU ◽  
Yunfeng YANG ◽  
Wentao ZHANG ◽  
...  
Keyword(s):  
Shale Gas ◽  
Sichuan Basin ◽  
Gas Generation ◽  
Longmaxi Formation ◽  
Sw China
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