scholarly journals Study on the Properties of Epoxy Composites Using Fly Ash as an Additive in the Presence of Nanoclay: Mechanical Properties, Flame Retardants, and Dielectric Properties

2020 ◽  
Vol 2020 ◽  
pp. 1-11
Author(s):  
Tuan Anh Nguyen ◽  
Thi Mai Huong Pham

Small and light fly ash is a by-product of thermal power plants, in which oxides mainly present in fly ash are suitable to reinforce composite materials. Its content accounts for 10, 20, 30, 40, and 50% of those materials. However, due to the smooth surface, it cannot stick completely in plastics. Therefore, in this work, it was studied to combine nanoclay additive (I.30 E) with 1, 3, and 5% by weight to synergize to improve mechanical strength, fire retardation, and electrical properties. Mechanical properties and flame retardant properties have improved markedly. At the combined ratio of 40% by weight of fly ash and 3% nanoclay, nanocomposites have tensile strength values of 64.12 MPa, flexural strength of 89.27 MPa, compressive strength of 215.23 MPa, and impact resistance of Izod 14.45 kJ/m2, oxygen index limited to 26.8% of fire retardant material. In terms of dielectric strength, the electric strength of pure epoxy is 17.5 kV/mm, higher than that before adding nanoclay (12.7 kV/mm). The presence of nanoclays in the material creates a tortuous electric path, slowing the propagation of the power plant, which is the main factor that improves the breaking strength of the nanocomposite.

2020 ◽  
Vol 61 (HTCS6) ◽  
pp. 10-18
Author(s):  
Dung Trong Nguyen ◽  
Lam Van Tang ◽  
Hung Xuan Ngo ◽  
Phi Van Dang ◽  
Cuong Anh Ho ◽  
...  

In Vietnam, thermal power plants produce millions of tons of fly ash per year and cause a lot of problems for the environment. The re-use of fly ash as mineral additives in the production of building materials such as cement, concrete etc is a comprehensive solution that brings high socio-economic efficiency. However, to achieve high efficiency, the technical specifications index of fly ash needs to be studied and evaluated in detail because the content of added fly ash is very important for producing and manufacturing processes. This paper aims to study the influence of Formosa fly ash on the mechanical properties at the early age of cement paste. The mechanical properties of the samples which contain alternatively 10÷30% of fly ash was measured at the early ages (1, 3, and 7 days) by experimental methods. In addition, the microstructure analysis and differential thermal analysis methods have been used to interpret the obtained results.


2021 ◽  
Vol 887 ◽  
pp. 528-535
Author(s):  
V.A. Kalneus ◽  
D.A. Nemushchenko ◽  
V.V. Larichkin ◽  
A.A. Briutov

The article analyses the influence of SiO2 and Al2O3 nanopowders on properties of ceramics consisting of fly ash from thermal power plants, glass waste, and clay binder. Based on studies of physical and mechanical properties of the obtained ceramics (ultimate compressive strength, ultimate three-point bending strength, wear resistance, and water absorption), the paper shows the positive influence of the nanoadditives. The optimal number of SiO2 and Al2O3 nanopowders in the formulation is 0.5 wt. % that has the strongest effect on ultimate compressive strength and water absorption of the fly ash ceramics samples. The direction of further research on improving the properties of ceramic products is an application of the Al2O3 nanopowder as more perspective nanoadditive using clay dispersant.


2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
Tuan Anh Nguyen ◽  
Quang Tung Nguyen

In this study, fly ash (FA) and multiwalled carbon nanotubes (MWCNTs) were used to make environmentally friendly nanocomposites, which have high fire retardant properties and high mechanical properties. Industrial waste such as fly ash has become a major concern during the treatment of environmental pollution. MWCNTs were used in this experiment to enhance the flame retardant properties and mechanical properties of materials with fly ash additives. MWCNTs content (0.03, 0.04, and 0.05 wt.%) and fly ash content (30, 40, and 50 wt.%) were studied for three different levels. The flame retardancy of the material is significantly improved by the addition of fly ash/MWCNTs at different rates, especially at 0.04 wt. % MWCNTs and 40 wt. % fly ash with LOI at 26.8%. Regarding mechanical properties, tensile strength increases as fly ash/MWCNTs increase, up to a critical point. On the other hand, the compressive strength of composite increases continuously as fly ash/MWCNTs increase. Scanning electron microscopy (SEM) was used to observe the morphology of fly ash and MWCNTs as well as its distribution in the matrix. This will help analyze the influence of the effectiveness of the combination of fly ash and MWCNTs to the flame retardancy and mechanical properties of fly ash/MWCNTs/epoxy nanocomposites.


2019 ◽  
Vol 93 ◽  
pp. 02008
Author(s):  
Tribikram Mohanty ◽  
Sauna Majhi ◽  
Purnachandra Saha ◽  
Bitanjaya Das

Due to rapid industrialization extensive quantity of waste materials like fly ash, silica fume, rice ash husk, and ferrochrome ash etc. are generated. Ferrochrome ash is generated from Ferro-alloy industry and fly-ash is produced in thermal power plants are alternative materials which have the potential of being utilized in concrete as a mineral admixture. The present investigation considers the combined influence on strength of concrete using various percentage fly ash and ferrochrome ash as partial replacement of cement. Experiments are carried out to get mechanical properties of ordinary Portland cement by replacement of fly ash by 10%, 20%, 30 % and 3% by ferrochrome ash. Mechanical properties are measured by determining compressive strength, split tensile strength and flexural strength. It can be inferred from the study that a small amount of ferrochrome ash mixed with 30 % fly-ash gives higher compressive strength as compared to fly ash alone. Addition of ferrochrome ash also increases the split tensile strength of concrete. Since ferrochrome ash and fly-ash are both industrial waste, utilization of these waste materials reduced the burden of dumping and greenhouse gas and thereby produce sustainable concrete.


2018 ◽  
Vol 22 (7) ◽  
pp. 2408-2420
Author(s):  
Yu-Chun Chuang ◽  
Limin Bao ◽  
Ching-Wen Lou ◽  
Jia-Horng Lin

In this study, three differently composed polyurethane (PU) composites are developed and then compared with the pure PU foam in terms of combustion resistance and mechanical properties using the compression test, the drop-weight impact test, the horizontal burning test, and the sound absorption test. Flame-retardant fabric (FRF)-PU is composed of PU foam that is enclosed with two cover sheets of FRFs. FR-PU10 is composed of PU foam that contains 10 wt% of flame-retardant agents. FRF-PU10 is composed of PU foam containing 10 wt% of flame-retardant agents and enclosed by two covers sheets of FRFs. Based on the test results, both FR-PU10 and FRF-PU10 are structurally stabilized and have good combustion resistance. The sample using FRFs as cover sheet had the same combustion resistance property and better compression resistance as the sample using flame-retardant agent. The carbonized layer extinguishes the alighted samples and stops the fire spread right after they are out of the source of fire, suggesting the FRF-PU10 is flame retardant. In addition, FRF-PU10 is easier to process and healthier because of the low use of flame retardants. Therefore, in this study, we proposed PU foam composites have good mechanical and flame-retardant properties and are a suitable candidate for productions of vehicles, plants, construction, and staple merchandises.


2016 ◽  
Vol 852 ◽  
pp. 55-60 ◽  
Author(s):  
A. Praveen Kumar ◽  
M. Nalla Mohamed ◽  
K. Kurien Philips ◽  
J. Ashwin

Increasing demand for special materials leads to new inventions. One of the most promising inventions is the concept of composites. Natural fibers have the potential as a reinforcing material as an alternative to the use of glass, carbon and other synthetic fibers in automotive industries. Among various natural fibers, Kenaf is a widely used fiber due to its easy availability, low density, low production cost and satisfactory mechanical properties. To enhance the mechanical properties of natural fibre composites, strengthening of the matrix and fibre is very much essential. A prospective reinforcement in this regard is fly ash, which is abundantly available as a waste product from thermal power plants. In this paper, a new novel natural composite with epoxy as a resin and reinforcing both bio waste (Kenaf) and industrial waste (Fly ash) has been developed. All the laminates were prepared with a total of 4 plies. Laminates without fly ash filler were also fabricated for comparison purpose. A hand lay-up method was used for the fabrication of composites and was tested as per ASTM standards for evaluation of tensile properties. The effect of fly ash weight percentage (5, 10, 15% wt.) on tensile properties was studied experimentally. Due to the incorporation of fly ash fillers into the kenaf fiber composites, there is considerable improvement in the mechanical properties. Overall results supported the effective utilization of natural composites for automotive applications.


Author(s):  
Harshkumar Patel ◽  
Yogesh Patel

Now-a-days energy planners are aiming to increase the use of renewable energy sources and nuclear to meet the electricity generation. But till now coal-based power plants are the major source of electricity generation. Disadvantages of coal-based thermal power plants is disposal problem of fly ash and pond ash. It was earlier considered as a total waste and environmental hazard thus its use was limited, but now its useful properties have been known as raw material for various application in construction field. Fly ash from the thermal plants is available in large quantities in fine and coarse form. Fine fly ash is used in construction industry in some amount and coarse fly ash is subsequently disposed over land in slurry forms. In India around 180 MT fly is produced and only around 45% of that is being utilized in different sectors. Balance fly ash is being disposed over land. It needs one acre of land for ash disposal to produce 1MW electricity from coal. Fly ash and pond ash utilization helps to reduce the consumption of natural resources. The fly ash became available in coal based thermal power station in the year 1930 in USA. For its gainful utilization, scientist started research activities and in the year 1937, R.E. Davis and his associates at university of California published research details on use of fly ash in cement concrete. This research had laid foundation for its specification, testing & usages. This study reports the potential use of pond-ash and fly-ash as cement in concrete mixes. In this present study of concrete produced using fly ash, pond ash and OPC 53 grade will be carried. An attempt will be made to investigate characteristics of OPC concrete with combined fly ash and pond ash mixed concrete for Compressive Strength test, Split Tensile Strength test, Flexural Strength test and Durability tests. This paper deals with the review of literature for fly-ash and pond-ash as partial replacement of cement in concrete.


Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1267
Author(s):  
David Längauer ◽  
Vladimír Čablík ◽  
Slavomír Hredzák ◽  
Anton Zubrik ◽  
Marek Matik ◽  
...  

Large amounts of coal combustion products (as solid products of thermal power plants) with different chemical and physical properties cause serious environmental problems. Even though coal fly ash is a coal combustion product, it has a wide range of applications (e.g., in construction, metallurgy, chemical production, reclamation etc.). One of its potential uses is in zeolitization to obtain a higher added value of the product. The aim of this paper is to produce a material with sufficient textural properties used, for example, for environmental purposes (an adsorbent) and/or storage material. In practice, the coal fly ash (No. 1 and No. 2) from Czech power plants was firstly characterized in detail (X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDX), particle size measurement, and textural analysis), and then it was hydrothermally treated to synthetize zeolites. Different concentrations of NaOH, LiCl, Al2O3, and aqueous glass; different temperature effects (90–120 °C); and different process lengths (6–48 h) were studied. Furthermore, most of the experiments were supplemented with a crystallization phase that was run for 16 h at 50 °C. After qualitative product analysis (SEM-EDX, XRD, and textural analytics), quantitative XRD evaluation with an internal standard was used for zeolitization process evaluation. Sodalite (SOD), phillipsite (PHI), chabazite (CHA), faujasite-Na (FAU-Na), and faujasite-Ca (FAU-Ca) were obtained as the zeolite phases. The content of these zeolite phases ranged from 2.09 to 43.79%. The best conditions for the zeolite phase formation were as follows: 4 M NaOH, 4 mL 10% LiCl, liquid/solid ratio of 30:1, silica/alumina ratio change from 2:1 to 1:1, temperature of 120 °C, process time of 24 h, and a crystallization phase for 16 h at 50 °C.


2021 ◽  
Vol 11 (9) ◽  
pp. 3910
Author(s):  
Saba Shirin ◽  
Aarif Jamal ◽  
Christina Emmanouil ◽  
Akhilesh Kumar Yadav

Acid mine drainage (AMD) occurs naturally in abandoned coal mines, and it contains hazardous toxic elements in varying concentrations. In the present research, AMD samples collected from an abandoned mine were treated with fly ash samples from four thermal power plants in Singrauli Coalfield in the proximate area, at optimized concentrations. The AMD samples were analyzed for physicochemical parameters and metal content before and after fly ash treatment. Morphological, geochemical and mineralogical characterization of the fly ash was performed using SEM, XRF and XRD. This laboratory-scale investigation indicated that fly ash had appreciable neutralization potential, increasing AMD pH and decreasing elemental and sulfate concentrations. Therefore, fly ash may be effectively used for AMD neutralization, and its suitability for the management of coalfield AMD pits should be assessed further.


2009 ◽  
Vol 6 (2) ◽  
pp. 511-517 ◽  
Author(s):  
S. Sarojini ◽  
S. Ananthakrishnasamy ◽  
G. Manimegala ◽  
M. Prakash ◽  
G. Gunasekaran

Fly ash is an amorphous ferroalumino silicate, an important solid waste around thermal power plants. It creates problems leading to environmental degradation due to improper utilization or disposal. However, fly ash is a useful ameliorant that may improve the physical, chemical and biological properties of soils and is a source of readily available plant macro and micronutrients when it is used with biosolids. Supply of nutrients from fly ash with biosolids may enhance their agricultural use. The growth and reproduction ofEisenia fetidawas studied during vermicomposting of fly ash with cowdung and pressmud in four different proportions (T1,T2,T3& T4) and one controli.e.,cow dung and pressmud alone. The growth, cocoon and hatchlings production were observed at the interval of 15 days over a period of 60 days. The maximum worm growth and reproduction was observed in bedding material alone. Next to that the T1was observed as the best mixture for vermiculture.


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