scholarly journals Separation of CO2 from Small Gas Molecules Using Deca-Dodecasil 3 Rhombohedral (DDR3) Membrane Synthesized via Ultrasonically Assisted Hydrothermal Growth Method

2020 ◽  
Vol 2020 ◽  
pp. 1-8
Author(s):  
Muhammad Mubashir ◽  
Yeong Yin Fong ◽  
Sidra Saqib ◽  
Ahmad Mukhtar ◽  
Sikander Rafiq ◽  
...  

Deca-dodecasil 3 rhombohedral (DDR3) membrane has received much attention in CO2 separation from small gas molecules because of its molecular sieving property and stable characteristics. Therefore, the present work is focusing on the utilization of previously fabricated membrane (synthesized in 3 days as reported in our previous work) to study the effect of hydrocarbons and its durability at the previously optimized conditions. Subsequently, gas permeation study was conducted on the DDR3 membrane in CO2 separation from small gas molecules and it was found that the permeance of H2, CO2, N2, and CH4 decreased in the order of H2 > CO2 > N2 > CH4, according to the increase in kinetic diameter of these gas molecules. Besides, it was observed that the ideal selectivities of the gas pairs decreased in the sequence of CO2/CH4 > CO2/N2 > H2/CO2. On the other hand, it was found that the presence of hydrocarbon impurities in the gas mixture containing CO2 and CH4 has directly affected the performance of DDR3 membrane and contributed to the losses of CO2 permeability, CH4 permeability, and CO2/CH4 selectivity of 39.1%, 14.8%, and 4.2%, respectively. Consequently, from the stability test, the performance of DDR3 membrane remained stable for 96 h, even after the separation testing using CO2 and CH4 gas mixture containing hydrocarbon impurities.

Membranes ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 249
Author(s):  
Yasuhisa Hasegawa ◽  
Chie Abe ◽  
Mayumi Natsui ◽  
Ayumi Ikeda

The polycrystalline CHA-type zeolite layer with Si/Al = 18 was formed on the porous α-Al2O3 tube in this study, and the gas permeation properties were determined using single-component H2, CO2, N2, CH4, n-C4H10, and SF6 at 303–473 K. The membrane showed permeation behavior, wherein the permeance reduced with the molecular size, attributed to the effect of molecular sieving. The separation performances were also determined using the equimolar mixtures of N2–SF6, CO2–N2, and CO2–CH4. As a result, the N2/SF6 and CO2/CH4 selectivities were as high as 710 and 240, respectively. However, the CO2/N2 selectivity was only 25. These results propose that the high-silica CHA-type zeolite membrane is suitable for the separation of CO2 from CH4 by the effect of molecular sieving.


Author(s):  
Hiroyuki Takahira ◽  
Daishi Ito ◽  
Tomoaki Katsuyama

To understand the stability of microbubbles, the shrinkage and growth of microbubbles under variation of a pressure field are observed with a CCD camera. The influence of gas diffusion is investigated for two kinds of microbubbles; one is Levovist which is an air microbubble coated by palmitic acid, and the other is Imavist which is a PFC gas microbubble covered by lipid and surfactant. It is shown that when the ambient liquid pressure increases, a tiny microbubble shrinks accompanied with surface depression, and does not return to the initial size even after the pressure is reduced. On the other hand, a large microbubble shrinks nearly spherically. The depression of bubble surface suggests the formation of multilayers of surfactant or lipid on bubble surface. It is also shown that air diffusion enhances the growth of the Imavist. A bubble model is also constructed by considering dynamic surface tension and gas permeation resistance of surfactant or lipid layers. The previous experimental results in which a microbubble was trapped with a laser trapping technique are compared with simulations based on the model. The results show that the rate of adsorption of surfactant is much faster than the shrinking speed of microbubbles. The decrease of surface tension due to the decrease of the surface area of a microbubble is a significant factor to determine the bubble profile. Also, the present experimental results are compared with simulations. The simulations considering the gas permeation resistance are in good agreement with the experiments for nearly spherical bubbles. The results also show that the increase of the permeation resistance during bubble shrinkage stabilizes microbubbles.


1994 ◽  
Vol 343 ◽  
Author(s):  
M. Kohyama ◽  
R. Yamamoto ◽  
Y. Watanabe

ABSTRACTThe energies and atomic structures of tilt and twist boundaries in Si have been examined by using the tight-binding electronic theory, and the reason why twist boundaries are seldom found in polycrystalline Si has been investigated. About the frequently observed {122} Σ=9 and {255} Σ=27 tilt boundaries, the configurations without any coordination defects consistent with the electron microscopy observations have relatively small interfacial energies with small bond distortions. About the <111> Σ=7, <011> Σ=3 and <001> Σ = 5 twist boundaries, the configurations contain larger bond distortions or more coordination defects, and much larger interfacial energies than those of the tilt boundaries. The <001> twist boundaries have very complex structures as compared with the other twist boundaries, which can be explained by the morphology of the ideal surfaces. The stability of the tilt boundaries in Si can be explained by the viewpoint of the stable structural units consisting of atomic rings.


Author(s):  
Godfrey C. Hoskins ◽  
V. Williams ◽  
V. Allison

The method demonstrated is an adaptation of a proven procedure for accurately determining the magnification of light photomicrographs. Because of the stability of modern electrical lenses, the method is shown to be directly applicable for providing precise reproducibility of magnification in various models of electron microscopes.A readily recognizable area of a carbon replica of a crossed-line diffraction grating is used as a standard. The same area of the standard was photographed in Phillips EM 200, Hitachi HU-11B2, and RCA EMU 3F electron microscopes at taps representative of the range of magnification of each. Negatives from one microscope were selected as guides and printed at convenient magnifications; then negatives from each of the other microscopes were projected to register with these prints. By deferring measurement to the print rather than comparing negatives, correspondence of magnification of the specimen in the three microscopes could be brought to within 2%.


Author(s):  
Milen Dimov

The present study traces the dynamics of personal characteristics in youth and the manifested neurotic symptoms in the training process. These facts are the reason for the low levels of school results in the context of the existing theoretical statements of the problem and the empirical research conducted among the trained teenagers. We suggest that the indicators of neurotic symptomatology in youth – aggression, anxiety, and neuroticism, are the most demonstrated, compared to the other studied indicators of neurotic symptomatology. Studies have proved that there is a difference in the act of neurotic symptoms when tested in different situations, both in terms of expression and content. At the beginning of the school year, neurotic symptoms, more demonstrated in some aspects of aggressiveness, while at the end of school year, psychotism is more demonstrated. The presented summarized results indicate that at the beginning of the school year, neurotic symptoms are strongly associated with aggression. There is a tendency towards a lower level of social responsiveness, both in the self-assessment of real behavior and in the ideal “I”-image of students in the last year of their studies. The neurotic symptomatology, more demonstrated due to specific conditions in the life of young people and in relation to the characteristics of age.


1970 ◽  
Vol 6 (2) ◽  
Author(s):  
Nurul Aini Musyarofah

The relationship between Islam and state raises a controversy that includes two main groups;formalists and substantialists. Both of them intend to achieve a good social condition which is inaccordance with Islamic politics. The ideal form of good society to be achieved is principallydescribed in the main source of Islamic law, Al Qur’an and As Sunnah, as follows. A form of goodsociety should supprot equality and justice, egalitarianism, and democracy in its social community.The next problem is what the needed methods and instruments to achieve the ideal Islamic politicsare. In this case, the debate on the formalization and substance of Islamic teaching is related to therunning formal political institution.Each group claims itself to be the most representative to the ideal Islam that often leads to anescalating conflict. On the other hand thr arguments of both groups does not reach the wholeMuslims. As a result, the discourse of Islam and state seems to be elitist and political. As a result,Both groups suspect each other each other and try to utilize the controversy on the relationshipbetween Islam and state to get their own benefit which has no relation with the actualization ofIslamic teaching.


2020 ◽  
Vol 12 (7) ◽  
pp. 2767 ◽  
Author(s):  
Víctor Yepes ◽  
José V. Martí ◽  
José García

The optimization of the cost and CO 2 emissions in earth-retaining walls is of relevance, since these structures are often used in civil engineering. The optimization of costs is essential for the competitiveness of the construction company, and the optimization of emissions is relevant in the environmental impact of construction. To address the optimization, black hole metaheuristics were used, along with a discretization mechanism based on min–max normalization. The stability of the algorithm was evaluated with respect to the solutions obtained; the steel and concrete values obtained in both optimizations were analyzed. Additionally, the geometric variables of the structure were compared. Finally, the results obtained were compared with another algorithm that solved the problem. The results show that there is a trade-off between the use of steel and concrete. The solutions that minimize CO 2 emissions prefer the use of concrete instead of those that optimize the cost. On the other hand, when comparing the geometric variables, it is seen that most remain similar in both optimizations except for the distance between buttresses. When comparing with another algorithm, the results show a good performance in optimization using the black hole algorithm.


2021 ◽  
Vol 5 (2) ◽  
pp. 32
Author(s):  
Esmehan Uçar ◽  
Sümeyra Uçar ◽  
Fırat Evirgen ◽  
Necati Özdemir

It is possible to produce mobile phone worms, which are computer viruses with the ability to command the running of cell phones by taking advantage of their flaws, to be transmitted from one device to the other with increasing numbers. In our day, one of the services to gain currency for circulating these malignant worms is SMS. The distinctions of computers from mobile devices render the existing propagation models of computer worms unable to start operating instantaneously in the mobile network, and this is particularly valid for the SMS framework. The susceptible–affected–infectious–suspended–recovered model with a classical derivative (abbreviated as SAIDR) was coined by Xiao et al., (2017) in order to correctly estimate the spread of worms by means of SMS. This study is the first to implement an Atangana–Baleanu (AB) derivative in association with the fractional SAIDR model, depending upon the SAIDR model. The existence and uniqueness of the drinking model solutions together with the stability analysis are shown through the Banach fixed point theorem. The special solution of the model is investigated using the Laplace transformation and then we present a set of numeric graphics by varying the fractional-order θ with the intention of showing the effectiveness of the fractional derivative.


Games ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 53
Author(s):  
Roberto Rozzi

We consider an evolutionary model of social coordination in a 2 × 2 game where two groups of players prefer to coordinate on different actions. Players can pay a cost to learn their opponent’s group: if they pay it, they can condition their actions concerning the groups. We assess the stability of outcomes in the long run using stochastic stability analysis. We find that three elements matter for the equilibrium selection: the group size, the strength of preferences, and the information’s cost. If the cost is too high, players never learn the group of their opponents in the long run. If one group is stronger in preferences for its favorite action than the other, or its size is sufficiently large compared to the other group, every player plays that group’s favorite action. If both groups are strong enough in preferences, or if none of the groups’ sizes is large enough, players play their favorite actions and miscoordinate in inter-group interactions. Lower levels of the cost favor coordination. Indeed, when the cost is low, in inside-group interactions, players always coordinate on their favorite action, while in inter-group interactions, they coordinate on the favorite action of the group that is stronger in preferences or large enough.


2019 ◽  
pp. 1-31
Author(s):  
Paul Ingram

Abstract Theodor Adorno’s philistine functions as the other of art, or as the ideal embodiment of everything that the bourgeois aesthetic subject is not. He insists on the truth-content of the derogation, while recognising its unjust social foundation, and seeking to reflect that tension in a self-critical turn. His model of advanced art is negatively delimited by the philistinism of art with a cause and the philistinism of art for enjoyment, which represent the poles of the aesthetic and the social. The philistine is also the counterpart to the connoisseur, with the interplay between them pointing to his preferred approach to aesthetics, in which an affinity for art and alienness to it are combined without compromise. However, Adorno fails to realise fully the critical potential of the philistine as the immanent negation of art and aesthetics.


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