scholarly journals Effect of Ca Concentration on Microstructure and Mechanical Properties of As-Cast and As-Extruded Quasicrystal-Strengthened Mg-7.2Zn-2.4Gd Alloy

2018 ◽  
Vol 2018 ◽  
pp. 1-7
Author(s):  
Jianchun Sun ◽  
Yilong Ma ◽  
Hongwei Miao ◽  
Kejian Li ◽  
Chunhong Li ◽  
...  

Quasicrystal-strengthened Mg-Zn-RE (RE = rare-earth element) alloys have been investigated extensively due to their excellent mechanical properties. Here, we prepare quasicrystal-strengthened Mg-7.2Zn-2.4Gd (wt.%) alloy with different concentrations of Ca addition (0, 0.16, 0.32, and 0.64 wt.%) by traditional gravity casting, followed by extrusion at 573 K with the extrusion ratio of 9 : 1. The microstructure and room temperature tensile properties of as-cast and as-extruded alloys are characterized. With the addition of the trace amount of Ca, the I-phase tends to transfer into W-phase due to the appearance of Mg2Ca and Mg6Zn3Ca2. As a consequence, the mechanical properties of the as-cast Ca containing alloys are downgraded. After extrusion, in comparison to the as-cast alloys, microstructure of the four types of alloys is refined and mechanical property is enhanced greatly. With the increasing of Ca concentration, the grain size is decreased gradually. However, the yield strength of the alloys is decreased to about 230 MPa and then up to 269 MPa, while the elongation increases first from 12.9% to 13.6% yet then decreases to 9.9%.

2021 ◽  
Author(s):  
Mohamed Gamal Mahmoud ◽  
Yasser Zedan ◽  
Agnes-Marie Samuel ◽  
Victor Songmene ◽  
Herebert W. Doty ◽  
...  

The present article reviews a large number of research publications on the effect of mischmetal (MM), rare earth metals (RE), La or Ce, and combinations of La + Ce on the performance of Al-Si cast alloys mainly 319, 356, 380, 413, and 390 alloys. Most of these articles focused on the use of rare earth metals as a substitute for strontium (Sr) as a eutectic silicon (Si) modifier if added in low percentage (< 1 wt.%) to avoid precipitation of a significant amount of insoluble intermetallics and hence poor mechanical properties. Other points that were considered were the affinity of RE to react with Sr., reducing its effectiveness as modifier, as well as the grain refining efficiency of the added RE in any form. None of these articles mentioned the exact composition of the RE used and percentage of tramp elements inherited from the parent ore. Using high purity La or Ce proved to have no effect on the Si shape, size or distribution, in particular at low solidification rates (thick sections). However, regardless the source of the RE, its addition to Sr-modified alloys reduced the modification effect. As for grain refining, apparently a high percentage of RE (> 1 wt.%) is required to achieve a noticeable reduction in grain size, however at the cost of alloy brittleness.


2011 ◽  
Vol 391-392 ◽  
pp. 638-641
Author(s):  
G.H. Su ◽  
Y. Sun ◽  
Zhan Yi Cao

Mg-1Mn-0.6Ce-xY (x=0, 1, 2 and 3, mass fraction, %) magnesium alloys were prepared by casting method. And the influences of yttrium on microstructure and mechanical properties of the Mg-1Mn-0.6Ce magnesium alloy were investigated. The results reveal that the addition of yttrium to the Mg-1Mn-0.6Ce alloy could reduce the grain size of the as-cast alloys and improve mechanical properties during the investigated temperature range. The Mg-1Mn-0.6Ce-1Y alloy exhibits maximum ultimate strength, yield strength, elongation and the values are 152 MPa, 72 MPa and 13.4% and enhanced about 23.1%, 63.6% and 38.1% compared with those of Mg-1Mn-0.6Ce alloy at room temperature, respectively. The improvement of mechanical properties are attributed to the grain refinement and the precipitation strengthening generated by the Mg12Ce phase particles and the fine Mg24Y5 precipitations.


2013 ◽  
Vol 738 ◽  
pp. 30-33
Author(s):  
Shuai Li ◽  
Yan Fu Yan ◽  
Yong Tao Jiu ◽  
Hong Na Wang

A new Bi5Sb8SnRE quaternary alloy was formed by adding 0.25wt%-0.75wt% rare earth (RE)Er into Bi5Sb8Sn solder alloy to study the effect of its mechanical property.The results show that adding micro amount of Er could refine the microstructure.Meanwhile,more uniform microstructure,improvements of the mechanical properties were obtained with Er additon.Comparing with Bi5Sb8Sn matrix, the tensile strength and shear strength increased by 41.8% and 83.0% respectively when Er adds up to 0.5wt.%; However,the Microstructure coarsened and the mechanical properties were decreased when the addition of Er more than 0.5wt.%.


2013 ◽  
Vol 845 ◽  
pp. 27-30 ◽  
Author(s):  
S.L. Joy-Yii ◽  
Denni Kurniawan

This paper reviews the effect of rare earth addition on aluminium-silicon (Al-Si) alloys of hypoeutectic, eutectic, and hypereutectic types. The effects of rare earth on metallurgy, tensile strength, tensile fracture surface and wear behaviour of Al-Si alloys are highlighted and discussed in this paper. It was concluded that adding rare earth element to Al-Si alloys reduces the grain size of primary Si, increases the tensile strength and decreases the friction coefficient decreases. These indicate enhanced mechanical properties for rare earth modified Al-Si alloys are likely.


2021 ◽  
Vol 5 (4) ◽  
pp. 110
Author(s):  
Flaminio Sales ◽  
Andrews Souza ◽  
Ronaldo Ariati ◽  
Verônica Noronha ◽  
Elder Giovanetti ◽  
...  

Polydimethylsiloxane (PDMS) is a polymer that has attracted the attention of researchers due to its unique properties such as transparency, biocompatibility, high flexibility, and physical and chemical stability. In addition, PDMS modification and combination with other materials can expand its range of applications. For instance, the ability to perform superhydrophobic coating allows for the manufacture of lenses. However, many of these processes are complex and expensive. One of the most promising modifications, which consists of the development of an interchangeable coating, capable of changing its optical characteristics according to some stimuli, has been underexplored. Thus, we report an experimental study of the mechanical and optical properties and wettability of pure PDMS and of two PDMS composites with the addition of 1% paraffin or beeswax using a gravity casting process. The composites’ tensile strength and hardness were lower when compared with pure PDMS. However, the contact angle was increased, reaching the highest values when using the paraffin additive. Additionally, these composites have shown interesting results for the spectrophotometry tests, i.e., the material changed its optical characteristics when heated, going from opaque at room temperature to transparent, with transmittance around 75%, at 70 °C. As a result, these materials have great potential for use in smart devices, such as sensors, due to its ability to change its transparency at high temperatures.


Author(s):  
Bo Chi ◽  
Zhiming Shi ◽  
Cunquan Wang ◽  
Liming Wang ◽  
Hao Lian ◽  
...  

Abstract Near-eutectic Al-Si alloys have low strength and high brittleness because of the presence of many eutectic b-Si flakes, needle-like Al-Fe-Si intermetallics, and coarse α-Al grains. This study disclosed the effects of cerium-rich RE (rare earth) element modification on orientation characters of crystals, formation of Al-Ce compounds, and microstructural refinement to improve the microstructure and mechanical properties of the alloys. The RE addition depressed preferential growth along the close-packed and/or sub-closepacked planes and promoted growth along the non-closepacked planes, in which La and other elements were dissolved into needle-like Al11Ce3 phase. When the temperature decreased, Al11Ce3 was preferentially crystallized from the melts and then devitrified by attaching to the surface of β-Al5FeSi needles. Moreover, many small Al11Ce3 particles were precipitated in the matrix and on the Si surface by a T6 heat treatment. Eutectic β-Si phases were constructed into discontinuous networks, short rods, and even particles by RE additions, which were further transformed into fine nodules following the T6 treatment. α-Al grains and primary β-Al5FeSi needles were simultaneously refined. The addition of 1.0 wt.% REs and subsequent T6 treatment yielded the highest tensile strength, elongation, and hardness of the alloy.


1990 ◽  
Vol 196 ◽  
Author(s):  
R. W. Siegel

ABSTRACTThe ultrafine grain sizes and high diffusivities in nanophase materials assembled from atomic clusters suggest that these materials may have a strong tendency toward superplastic mechanical behavior. Both small grain size and enhanced diffusivity can be expected to lead to increased diffusional creep rates as well as to a significantly greater propensity for grain boundary sliding. Recent mechanical properties measurements at room temperature on nanophase Cu, Pd, and TiO2, however, give no indications of superplasticity. Nonetheless, significant ductility has been clearly demonstrated in these studies of both nanophase ceramics and metals. The synthesis of cluster-assembled nanophase materials is described and the salient features of what is known of their structure and mechanical properties is reviewed. Finally, the answer to the question posed in the title is addressed.


2012 ◽  
Vol 736 ◽  
pp. 307-315 ◽  
Author(s):  
Murugavel Suresh ◽  
Satyam Suwas

Mg alloys show limited room temperature formability compared to its lightweight counterpart aluminium alloys, which is a main obstacle in using this metal for most of the structural applications. However, it is known that grain refinement and texture control are the two possibilities for the improvement of formability of magnesium alloys. Amongst the approaches attempted for the texture weakening, additions through of rare-earth (RE) elements have been found most effective. The relationship between the texture and ductility is well established. In this paper, the effect of rare earth addition on texture weakening has been summarized for various magnesium alloys under the two most common modes of deformation methods.


2014 ◽  
Vol 875-877 ◽  
pp. 63-67 ◽  
Author(s):  
Dinh van Hai ◽  
Nguyen Trong Giang

In this work, ECAP technique was combined with cold rolling process in order to enhance mechanical properties and microstructure of pure Titanium. Coarse grain (CG) Titanium with original grain size of 150 μm had been pressed by ECAP at 425oC by 4, 8 and 12 passes, respectively. This process then was followed by rolling at room temperature with 35%, 55%, and 75% rolling strains. After two steps, mechanical properties such as strength, hardness and microstructure of processed Titanium have been measured. The result indicated significant effect of cold rolling on tensile strength, hardness and microstructure of ECAP-Titanium.


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