scholarly journals Is Superplasticity in the Future of Nanophase Materials?

1990 ◽  
Vol 196 ◽  
Author(s):  
R. W. Siegel

ABSTRACTThe ultrafine grain sizes and high diffusivities in nanophase materials assembled from atomic clusters suggest that these materials may have a strong tendency toward superplastic mechanical behavior. Both small grain size and enhanced diffusivity can be expected to lead to increased diffusional creep rates as well as to a significantly greater propensity for grain boundary sliding. Recent mechanical properties measurements at room temperature on nanophase Cu, Pd, and TiO2, however, give no indications of superplasticity. Nonetheless, significant ductility has been clearly demonstrated in these studies of both nanophase ceramics and metals. The synthesis of cluster-assembled nanophase materials is described and the salient features of what is known of their structure and mechanical properties is reviewed. Finally, the answer to the question posed in the title is addressed.

2018 ◽  
Vol 385 ◽  
pp. 39-44 ◽  
Author(s):  
Fernando Carreño ◽  
Oscar A. Ruano

The 7075 (Al-Zn-Mg-Cu) aluminium alloy is the reference alloy for aerospace applications due to its specific mechanical properties at room temperature, showing excellent tensile strength and sufficient ductility. Formability at high temperature can be improved by obtaining superplasticity as a result of fine, equiaxed and highly misoriented grains prone to deform by grain boundary sliding (GBS). Different severe plastic deformation (SPD) processing routes such as ECAP, ARB, HPT and FSP have been considered and their effect on mechanical properties, especially at intermediate to high temperatures, are studied. Refined grains as fine as 100 nm and average misorientations as high as 39o allow attainment of high strain rate superplasticity (HSRSP) at lower than usual temperatures (250-300oC). It is shown that increasing misorientations are obtained with increasing applied strain, and increasing grain refinement is obtained with increasing processing stress. Thus, increasing superplastic strains at higher strain rates, lower stresses and lower temperatures are obtained with increasing processing strain and, specially, processing stress.


1990 ◽  
Vol 206 ◽  
Author(s):  
G. W. Nieman ◽  
J. R. Weertman ◽  
R. W. Siegel

ABSTRACTMeasurements of tensile strength and creep resistance have been made on bulk samples of nanocrystalline Cu, Pd and Ag consolidated from powders by cold compaction. Samples of Cu-Cu2O have also been tested. Yield strength for samples with mean grain sizes of 5–80 nm and bulk densities on the order of 95% of theoretical density are increased 2–5 times over that measured in pure, annealed samples of the same composition with micrometer grain sizes. Ductility in the nanocrystalline Cu has exceeded 6% true strain, however, nanocrystalline Pd samples were much less ductile. Constant load creep tests performed at room temperature at stresses of >100 MPa indicate logarithmic creep. The mechanical properties results are interpreted to be due to grain size-related strengthening and processing flaw-related weakening.


2007 ◽  
Vol 345-346 ◽  
pp. 565-568
Author(s):  
Byung Nam Kim ◽  
Keijiro Hiraga ◽  
Koji Morita ◽  
Hidehiro Yoshida

For steady-state deformation caused by grain-boundary diffusion and viscous grain-boundary sliding, the creep rate of regular polyhedral grains is analyzed by the energy-balance method. For the microstructure, the grain-grain interaction increases the degree of symmetry of diffusional field, resulting in a decrease of the effective diffusion distance. Meanwhile, the viscous grain-boundary sliding is found to decrease the creep rate. The present analysis reveals that the grain-size exponent is dependent on the grain size and the grain-boundary viscosity: the exponent becomes unity for small grain sizes and/or high viscosity, while it is three for large grain sizes and/or low viscosity.


2020 ◽  
Vol 402 ◽  
pp. 67-72
Author(s):  
Rahmawaty ◽  
Surya Dharma ◽  
Abdul Razak ◽  
Sarjianto ◽  
Nisfan Bahri ◽  
...  

Equal-channel angular pressing (ECAP) is an effective fabrication process to modify ultrafine grain size. It is believed that the smaller grain size could improve the mechanical properties. In the present work, the solution treatment applied to Al-Si-Cu-Mg-Mn alloy. Furthermore, two models of ECAP have been done through one-to-three pass at room temperature. The microstructures were observed by optical microscope (OM) and scanning electron microscope (SEM). The micro-hardness of longitudinal plane was analyzed by vickers hardness test. The strength of ECAP materials at room temperature was obtained by using tensile test. The results show that the ECAP process has improved mechanical properties of alloys, which were the hardness and ultimate tensile strength tend to increase since single pass stage.


2008 ◽  
Vol 584-586 ◽  
pp. 35-40 ◽  
Author(s):  
Eduard Kozlov ◽  
Nina Koneva ◽  
L.I. Trishkina ◽  
A.N. Zhdanov ◽  
M.V. Fedorischeva

The present work is devoted to the investigation of the influence of the grain size on the main mechanical characteristics of nanopolycrystals of different metals. The Hall-Petch parameter behaviour for Al, Cu, Ni, Ti and Fe was examined in the wide grain size interval. The stages of plastic deformation and the parameters of work hardening for nanocrystalline copper were analysed in detail. The deformation mechanisms and critical grain sizes accounting for the transition from the dislocation slip to the grain boundary sliding were described.


2019 ◽  
Vol 55 (7) ◽  
pp. 2661-2681 ◽  
Author(s):  
Sneha N. Naik ◽  
Stephen M. Walley

AbstractWe review some of the factors that influence the hardness of polycrystalline materials with grain sizes less than 1 µm. The fundamental physical mechanisms that govern the hardness of nanocrystalline materials are discussed. The recently proposed dislocation curvature model for grain size-dependent strengthening and the 60-year-old Hall–Petch relationship are compared. For grains less than 30 nm in size, there is evidence for a transition from dislocation-based plasticity to grain boundary sliding, rotation, or diffusion as the main mechanism responsible for hardness. The evidence surrounding the inverse Hall–Petch phenomenon is found to be inconclusive due to processing artefacts, grain growth effects, and errors associated with the conversion of hardness to yield strength in nanocrystalline materials.


2008 ◽  
Vol 22 (18n19) ◽  
pp. 2823-2832 ◽  
Author(s):  
REZA MAHMUDI ◽  
H. MHJOUBI ◽  
P. MEHRARAM

Creep and superplasticity of the fine-grained Sn -1wt.% Bi alloy, processed by conventional rolling (CNR), cryorolling (CRR) and equal channel angular pressing (ECAP) routes, were investigated by indentation testing at room temperature (T > 0.6T m ). Based on the steady-state power law creep relationship, the stress exponents of 4.1, 2.8 and 2.5 were obtained for the CNR, CRR and ECAP routes, respectively. The corresponding strain rate sensitivity (SRS) indices of 0.24, 0.36 and 0.40, corresponding respectively to the grain sizes of 2.8, 2.1 and 1.2 μm, indicate that the materials processed by ECAP and CRR exhibit superplastic deformation behavior for which, grain boundary sliding is the possible creep mechanism.


2004 ◽  
Vol 449-452 ◽  
pp. 665-668 ◽  
Author(s):  
Junichi Koike

Deformation mechanisms of Mg-Al-Zn (AZ31) alloys were investigated by performing tensile test at room temperature. In fine grain Mg alloys deformed at room temperature, nonbasal slip systems were found to be active as well as basal slip systems because of grain-boundary compatibility effect. Slip-induced grain-boundary sliding occurred as a complementary deformation mechanism to give rise to c-axis component of strain. With increasing grain size, the activation of the nonbasal slip systems was limited near grain boundaries. Instead of grain-boundary sliding, twinning occurred as a complementary deformation mechanism in large grained samples. Orientation analysis of twins indicated that twinning is induced by stress concentration due to the pile up of basal dislocations. The grain-size dependence on deformation mechanism was found to affect yielding behavior both microscopically and macroscopically which can influence various mechanical properties such as fatigue and creep.


2011 ◽  
Vol 683 ◽  
pp. 149-160 ◽  
Author(s):  
De Liang Zhang ◽  
Hong Bao Yu ◽  
Yuong Chen

Bulk nanostructured (grain sizes in the range of 50-200nm) and ultrafine structured (grain sizes in the range of 100-500nm) -TiAl based alloys with compositions Ti-47Al (in at%) and Ti–45Al–2Cr–2Nb–1B–0.5Ta (in at%), respectively, have been produced using a combination of high energy mechanical milling of mixtures of elemental powders and hot isostatic pressing at 800 and 1000oC respectively, and the microstructures of the samples have been characterised. At room temperature, the HIPed samples fractured prematurely at tensile stresses in the range of 200-300MPa and showed no ductility, very likely due to the relative high oxygen content (0.6wt%) in the samples and very low tolerance of TiAl based alloys on dissolved oxygen. At 800oC, the HIPed samples showed a yield strength in the range of 55-70MPa, a tensile strength in the range of 60-80MPa, a large amount of elongation to fracturing around 100% and clear strain softening. Examination of the fractured tensile test specimens at room temperature and 800oC showed that the level of the consolidation was fairly high, but the HIPed samples do contain a small fraction of interparticle boundaries with weak atomic bonding. The fracture of the HIPed samples in tensile testing at room temperature and 800oC, respectively, is predominately intergranular, and the large amount of plastic deformation prior to fracture at 800oC is achieved mainly through grain boundary sliding in conjunction with dislocation gliding, in agreement with the deformation mechanisms of nanostructured and ultrafine structured alloys generally agreed by researchers.


2007 ◽  
Vol 44 (11) ◽  
pp. 1587-1602 ◽  
Author(s):  
S Vitale ◽  
J C White ◽  
A Iannace ◽  
S Mazzoli

The Apennine Pollino–Ciagola limestone unit in northern Calabria is characterized by subgreenschist, heterogeneous ductile strain localized along narrow deformation zones at several stratigraphic levels. Paleogene conglomerates and Jurassic calcareous breccias and ooidal packstones have been analyzed with the aim of characterizing the deformation of limestone as a function of the strain recorded by sedimentary markers. Reference sections parallel to principal finite strain planes were prepared at each locality for the study of specific parameters. Image analysis of polished sections by scanning electron microscopy (SEM) was used to obtain the finite strain of calcite grains by Rf/ϕ, harmonic mean and normalized Fry methods. For the range of grain sizes analyzed (1–10 µm), the ellipticity of calcite grains varies as a function of grain size according to a power-law relationship, from which the size of isometric grains is empirically predicted. The finite strain (ellipticity) determined from single calcite grains shows consistently lower values than the corresponding rock strain. For a fixed grain size, grain ellipticity initially increases with rock strain; however for larger strain, scattered ellipticity values are recorded, probably because of dynamic recrystallization. Comparison of bulk strain with grain strain suggests that intercrystalline deformation involving grain boundary sliding contributes 50%–80% of the total strain, for grain sizes in the range of 2–10 µm, increasing to 90% or more for smaller grain sizes. Microstructures (optical, SEM, transmission electron microscopy) are consistent with dominant grain boundary sliding accommodated by dislocation processes. The weakly deformed samples (Rs <4) exhibit straight and subsidiary curved mechanical twins in large grains (d >10 µm), with well-developed glide dislocation substructures in both coarse and micrite grains. In the moderately to highly deformed samples (Rs >4), large grains show curved, thick, and patchy twins, with the development of undulose extinction and subgrains. Subwalls are formed from dislocation networks and relate to subgrain rotation recrystallization in the coarsest grains. Both large and small grains exhibit complex dislocation substructures comprising dislocation networks indicative of concurrent intercrystalline and intracrystalline deformation, whereby grain boundary sliding is accommodated by dislocation processes. Integration of tectonic constraints, field observations, finite strain data, microstructures, and experimental data is consistent with natural deformation at 250 °C, 15–50 MPa, and bulk shear strain rates on the order of 10–13 s–1 to 10–12 s–1.


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