scholarly journals Preparation of Miscible PVA/PEG Blends and Effect of Graphene Concentration on Thermal, Crystallization, Morphological, and Mechanical Properties of PVA/PEG (10 wt%) Blend

2018 ◽  
Vol 2018 ◽  
pp. 1-10 ◽  
Author(s):  
Fahad H. Falqi ◽  
Osamah A. Bin-Dahman ◽  
M. Hussain ◽  
Mamdouh A. Al-Harthi
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Testing Machine ◽  
Water Soluble ◽  
Poly Vinyl Alcohol ◽  
Scanning Calorimetry ◽  
Tensile Testing Machine ◽  
Elongation At Break ◽  
Casting Technique ◽  
Dsc Studies

Water-soluble polymers such as poly(vinyl alcohol) (PVA) and poly(ethylene glycol) (PEG) and their nanocomposites with graphene were prepared by using a solution mixing and casting technique. The effect of different PEG loadings was investigated to determine the optimum blend ratio. The films were characterized using Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and thermogravimetric analyzer (TGA) methods. Also, the mechanical properties including tensile strength and elongation at break were measured using a universal tensile testing machine. FTIR results confirmed the formation of the H-bond between PEG and PVA. DSC studies revealed that PEG has a significant plasticization effect on PVA as seen by the drop in the glass transition temperature (Tg). The blend with 10 wt% PEG loading was found to be the optimum blend because of good compatibility as shown by FTIR and SEM results and improved thermal properties. PVA/PEG (10%) nanocomposites were prepared using graphene as a nanofiller. It was found that the elongation at break increased by 62% from 147% for the PVA/PEG (10%) blend to 209% for the nanocomposite with graphene loading of 0.2 wt%. The experimental values of tensile strength were compared using the predictive model of Nicolais and Narkis.

Preparation and Properties of Biocomposite Film with Gelatin and Poly(Vinyl Alcohol)

2011 ◽  
Vol 287-290 ◽  
pp. 302-305
Author(s):  
Xi Ping Gao ◽  
Ke Yong Tang ◽  
Yu Qing Zhang
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Optical Properties ◽  
Vinyl Alcohol ◽  
Composite Films ◽  
Poly Vinyl Alcohol ◽  
Elongation At Break ◽  
Biocomposite Film

The mechanical properties, swelling, solubility, and optical properties of composite films with poly(vinyl alcohol) (PVA) and gelatin were studied. With increasing the PVA content in the composite films, the tensile strength (TS) and elongation at break (EB) of the films increase. The swelling and solubility are different with different gelatin/PVA ratios, with the lowest at 1:5.

scholarly journals FTIR spectroscopy characterization and critical comparison of poly(vinyl)alcohol and natural hydroxyapatite derived from fish bone composite for bone-scaffold

2021 ◽  
Vol 2120 (1) ◽  
pp. 012004
Author(s):  
May Teng Hooi ◽  
Siew Wei Phang ◽  
Hui Ying Yow ◽  
Edmund David ◽  
Ning Xin Kim ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Vinyl Alcohol ◽  
Fish Bone ◽  
Poly Vinyl Alcohol ◽  
Solution Casting ◽  
Casting Method ◽  
Elongation At Break ◽  
Solution Casting Method ◽  
Extrusion Method

Abstract This paper presents the interaction comparison of poly(vinyl) alcohol (PVA) with hydroxyapatite derived from Spanish Mackerel (SM) and Whitefin Wolf Herring (WWH) bones, in different processing method. PVA filament and solution casting method illustrated higher crystallinity in the FTIR graph as compared to the PVA pellet and filament extrusion method. Besides, minimal interactions between PVA with glycerol and HAp was observed as well. PVA pellet and solution casting method portrait higher interaction as compared to the PVA filament and extrusion method. As for the HAp of SM and WWH, WWH had higher crystallinity and better cell adhesion with a higher Ca/P ratio while SM had relatively better mechanical strength with Ca/P ratio near to stoichiometric value. The loading of HAp (0, 2.5, 5, 10, 20, 30%) does not affect interactions of PVA/HAp composite in FTIR, and thermal properties in TGA. However, it caused an increase in crystallinity at low HAp loading and decreased at higher loading of HAp above 10%. Upon addition of HAp, tensile strength increased and elongation at break decreased. As the loading of HAp increased, both mechanical properties decreased. Scaffold with WWH composite possessed lower tensile strength and higher elongation at break than SM composite. The result of mechanical properties corresponded to the SEM result. ANOVA analysis justified the effect of HAp variations and loading on the mechanical properties of the composite was prominent.

scholarly journals PREPARATION AND CHARACTERIZATIONS OF LATEX/FILLER NANOCOMPOSITES

2020 ◽  
Vol 21 (2) ◽  
pp. 230-238
Author(s):  
Mohamad Firdaus Omar ◽  
NURIAH MOHAMAD ◽  
Fathilah Ali
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Coupling Agent ◽  
Morphological Properties ◽  
Rubber Matrix ◽  
Silane Coupling Agents ◽  
Scanning Calorimetry ◽  
Elongation At Break ◽  
Silane Coupling ◽  
Latex Compounding

Latex compounding which incorporates various types of clays as filler to the rubber can significantly give reinforcement in the rubber matrix when rubber/clay nanocomposites are formed, but the filler agglomerates. Thus, study was conducted by using Kaolin clay as the filler in the rubber nanocomposites with silane coupling agent to functionalize the surface of the filler. This study was done in order to investigate the mechanical properties of various functionalized Kaolin in latex nanocomposites, to prepare various ratios of Kaolin to rubber, and to characterize mechanical, thermal and morphological properties of the Kaolin in latex nanocomposites. To achieve these, six types of silane coupling agents was used for Kaolin filler surface functionalization purpose during the filler’s incorporation in latex compounding. The optimized coupling agent, USi-7301 (?-chloropropyltrimetoxysilane) – with tensile strength value of 32.77 MPa, elongation at break value of 632.589 % and force at break value of 6.737 N – was used to further functionalize Kaolin filler in different ratios so as to achieve the optimum mechanical, thermal and morphological properties of the filler in the polymer matrix. Universal tensile machine was used to analyze the mechanical properties of the nanocomposites, while the Scanning Electron Microscopy (SEM) and Differential Scanning Calorimetry (DSC) were used to observe the morphological and thermal properties of the nanocomposites, respectively. The results showed that reducing the Total Solids Content (TSC) of Kaolin filler to 26 % somehow showed the optimized properties of the nanocomposites, giving 34.00 MPa tensile strength, 576.494 % elongation at break and 6.564 N force at break. Rough surface morphology was observed under SEM suggesting the occurrence of phase separation between the hydrophilic filler and the hydrophobic rubber matrix. In the DSC plot, sample with USi-7301 and with functionalized Kaolin filler 26 % TSC showed glass transition temperature shifted to lower region compared to normal nitrile rubber. The reinforcement of nanocomposites formed will not only enhance the properties of the nanocomposites, but is also economically feasible thus brings advantages to the industry. ABSTRAK: Penyebatian lateks yang menggabungkan pelbagai jenis tanah liat sebagai pengisi dalam getah dapat memberi pengukuhan dalam matriks getah dengan ketara apabila nanokomposit getah / tanah liat terbentuk, tetapi pengisi mengagregat. Oleh itu, kajian dijalankan dengan menggunakan tanah liat Kaolin sebagai pengisi dalam nanokomposit getah dengan ejen gandingan silan untuk menambah-fungsi permukaan pengisi tersebut. Kajian ini dilakukan untuk mengenalpasti sifat mekanik pelbagai Kaolin (yang berfungsi) dalam nanokomposit lateks, untuk menyediakan pelbagai nisbah Kaolin terhadap getah, dan untuk mencirikan sifat mekanik, haba dan morfologi Kaolin dalam nanokomposit lateks. Untuk mencapainya, enam jenis ejen gandingan silan digunakan untuk tujuan menambah-fungsi permukaan pengisi Kaolin semasa penggabungan pengisi dalam penyebatian lateks. Ejen gandingan silan yang paling optimum, USi-7301 (?-silan kloropropiltrimetoksi) - dengan nilai kekuatan tegangan 32.77 MPa, nilai pemanjangan ketika pemutusan 632.589% dan kekuatan daya ketika pemutusan 6.737 N - digunakan dengan lebih lanjut untuk menambah-fungsi pengisi Kaolin dalam nisbah yang berbeza untuk lebih mencapai sifat mekanikal, haba dan morfologi optimum pengisi dalam matriks polimer lateks. Mesin tegangan universal digunakan untuk menganalisis sifat mekanik nanokomposit, sementara Mikroskopi Elektron Pengimbasan (SEM) dan Kalorimetri Pengimbasan Berbeza (DSC) digunakan untuk menganalisa sifat morfologi dan haba nanokomposit tersebut. Hasil kajian menunjukkan bahawa pengurangan Jumlah Kandungan Pepejal (TSC) pengisi Kaolin kepada 26% menunjukkan sifat optimum nanokomposit, dengan kekuatan tegangan 34.00 MPa, pemanjangan ketika pemutusan sebanyak 576.494% dan daya ketika pemutusan sebanyak 6.564 N. Morfologi permukaan kasar diperhatikan di bawah SEM dan ia menunjukkan berlakunya pemisahan fasa antara pengisi hidrofilik dan matriks getah hidrofobik. Dalam plot DSC, sampel dengan USi-7301 dan dengan pengisi Kaolin yang difungsikan dengan 26% TSC menunjukkan suhu peralihan kaca beralih ke kawasan yang lebih rendah berbanding getah nitril biasa. Pengukuhan nanokomposit yang terbentuk bukan sahaja akan meningkatkan sifat nanokomposit, tetapi juga dapat dilaksanakan secara ekonomi sehingga memberi banyak kelebihan kepada industri.

Effect of silver nanoparticle (AgNp) mixed with calcium carbonate on impact, hardness and tensile strength properties of aluminium 6063

2020 ◽  
pp. 002199832092314
Author(s):  
Adefemi Adeodu ◽  
Lateef Mudashiru ◽  
Ilesanmi Daniyan ◽  
Abdulmalik Awodoyin
Keyword(s):  
Tensile Strength ◽  
Calcium Carbonate ◽  
Aluminium Alloy ◽  
Testing Machine ◽  
Charpy Impact ◽  
Stir Casting ◽  
Optical Microscope ◽  
Tensile Testing Machine ◽  
Casting Technique ◽  
The Impact

Mechanical properties (impact, hardness and tensile strength) characterization of samples containing homogenous mixtures of Al 6063 matrix and varying amount of silver nanoparticles mixed with calcium carbonate at 2, 4, 6% weight fractions, respectively, produced by method of stir casting were carried out. Measurement of impact energy, hardness and tensile strength of the produced samples at 24℃ (ambient) temperature was done by Charpy impact, Brinell hardness and universal tensile testing machine in accordance to ASTM E23, E384 and E8/E8M-13M, respectively. The magnitude of impact and hardness increased evidently with increase in percentage weight fraction of the AgNPs. The refined samples were examined under an optical microscope. The fracture surfaces of the impact test samples were further examined by scanning electron microscopy. There is an increase in tensile strength, elongation and modulus of elasticity of Al-AgNP composites compared to as-cast aluminium alloy. The use of stir-casting technique influences the homogeneity and microstructure of the composites positively. It is concluded that Al-silver nanocomposites possess better qualities in hardness and strength and can replace conventional aluminium alloy in terms of performance and longer life in industrial application.

scholarly journals Preparation and Characterization of PVA/PDDA/Nano-Zirconia Composite Anion Exchange Membranes for Fuel Cells

Polymers ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1399 ◽  
Author(s):  
Asep Muhamad Samsudin ◽  
Viktor Hacker
Keyword(s):  
Mechanical Properties ◽  
Fuel Cells ◽  
Anion Exchange ◽  
Testing Machine ◽  
Conductivity Measurement ◽  
Poly Vinyl Alcohol ◽  
Anion Exchange Membranes ◽  
Potential Candidate ◽  
Casting Technique ◽  
Chemical Structures

Anion exchange membranes (AEMs) contribute significantly to enhance the performance and efficiency of alkaline polymer electrolyte fuel cells (APEFCs). A sequence of composite anion exchange membranes (AEMs) consisting of poly(vinyl alcohol) (PVA), poly(diallyldimethylammonium chloride) (PDDA), and nano-zirconia (NZ) has been prepared by a solution casting technique. The effect of zirconia mass ratio on attribute and performance of composite AEMs was investigated. The chemical structures, morphology, thermal, and mechanical properties of AEMs were characterized by FTIR, SEM, thermogravimetric analysis, and universal testing machine, respectively. The performance of composite AEMs was verified using water uptake, swelling degree, ion-exchange capacity, and OH− conductivity measurement. The nano-zirconia was homogeneously dispersed in the PVA/PDDA AEMs matrix. The mechanical properties of the composite AEMs were considerably enhanced with the addition of NZ. Through the introduction of 1.5 wt.% NZ, PVA/PDDA/NZ composite AEMs acquired the highest hydroxide conductivity of 31.57 mS·cm−1 at ambient condition. This study demonstrates that the PVA/PDDA/NZ AEMs are a potential candidate for APEFCs application.

Preparation and Characterization of Poly(Vinyl Alcohol)(PVA)/Hydroxyapatite (HA) Nanofibrous Scaffolds

2011 ◽  
Vol 284-286 ◽  
pp. 459-463 ◽  
Author(s):  
Yuan Yuan Qi ◽  
Bin Liu ◽  
Xing Bin Yan
Keyword(s):  
Mechanical Properties ◽  
Drug Delivery ◽  
Tissue Engineering ◽  
Tensile Strength ◽  
Drug Delivery Systems ◽  
Poly Vinyl Alcohol ◽  
Elongation At Break ◽  
Nanofibrous Scaffolds ◽  
Potential Applications

Nanofibrous scaffolds of PVA and HA were prepared by electrospinning. SEM showed the scaffolds had porous nanofibrous morphology, and the diameter of the fibers was in the range of 200-1000 nm. FTIR and XRD showed the presence of HA in the scaffolds. The mechanical properties of the scaffolds changed by the adding content of HA. For the nanoscaffolds with 2wt % HA, the ultimate tensile strength and the elongation at break was 7.5 MPa and 17%. The PVA/HA nanoscaffolds prepared by electrospinning indicated good properties, and had a potential applications in bone tissue engineering and drug delivery systems.

Effect of Coarse-Grained Ring on Mechanical Properties and Cutting Performance of 2011 Aluminum Alloy Extruded Bar

2021 ◽  
Vol 1035 ◽  
pp. 114-118
Author(s):  
Chang Liang Shi ◽  
Yan Ping Niu ◽  
Yi Min Lin ◽  
Quan Hu ◽  
Xin Zhang
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Aluminum Alloy ◽  
Tensile Testing ◽  
High Speed ◽  
Testing Machine ◽  
Eutectic Phase ◽  
Cutting Performance ◽  
Coarse Grained ◽  
Tensile Testing Machine

The effects of coarse-grained ring on the mechanical properties and cutting performance of 2011 aluminum alloy extruded bars were studied by metallographic microscope, scanning electron microscope, tensile testing machine and high-speed lathe. The results show that the microstructure of aluminum alloy extruded bar was composed of α-Al phase, Al7Cu2Fe phase, CuAl2 phase and SnBi eutectic phase. There was a coarse-grained ring in the aluminum alloy extruded bar. The coarse-grained ring reduced the mechanical properties and cutting performance of the aluminum alloy extruded bar. The aluminum alloy extruded bar with a diameter of 30 mm had a coarse-grained ring depth of 9 mm and lower mechanical properties, whose the tensile strength was 287.9 MPa, the elongation was 17%, the cutting performance was poor and the chips were long. The aluminum alloy extruded bar with a diameter of 40 mm had a coarse-grained ring depth of 1 mm, higher mechanical properties and better cutting performance, whose the tensile strength was 394.5 MPa, the elongation was 23.5%, the chips were fine and uniform.

Influence of PNA012 on Crystallization and Mechanical Properties of Polybutylene Terephthalate

2012 ◽  
Vol 624 ◽  
pp. 264-268 ◽  
Author(s):  
Duo You Zhang ◽  
Peng Liu ◽  
Chun Fa Ouyoung ◽  
Qun Gao ◽  
Kang Sheng Zheng ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Differential Scanning Calorimetry ◽  
Tensile Strength ◽  
Bending Strength ◽  
Testing Machine ◽  
Nucleating Agent ◽  
Polybutylene Terephthalate ◽  
Scanning Calorimetry ◽  
Universal Testing ◽  
Crystallization Degree

PNA012 is a new nucleating agent on polybutylene terephthalate. The effect of different dosage of PNA012 on crystallization and mechanical properties were investigated by means of differential scanning calorimetry, universal testing machine, melt flow indexer and vicat softening testing machine. It was revealed that the PNA012 could substantially accelerate the crystallization of PBT. Compared with the pure PBT,the crystallization temperature of PBT/PNA012 rises from 196.3 °C to 199.7 °C and crystallization degree from 34.2% to 39.9%. The tensile Strength of PBT/PNA012 is increased 9.7%. The Bending Strength has a rise of 9.3% and the heat distortion temperatures of PBT/PNA012 is increased from 115.07°C to 125.94°C.

Preparation and Characterization of Chitosan/poly( Vinyl Alcohol) Composite Packaging Films

2011 ◽  
Vol 332-334 ◽  
pp. 1739-1742 ◽  
Author(s):  
Ling Li ◽  
Zheng Wei Jin ◽  
Jian Qing Wang
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Water Vapor ◽  
Vinyl Alcohol ◽  
Permeability Coefficient ◽  
Composite Films ◽  
Weight Ratio ◽  
Poly Vinyl Alcohol ◽  
Elongation At Break ◽  
Packaging Films

A novel chitosan/poly(vinyl alcohol) composite packaging films were prepared by the casting method, and the effects of chitosan concentration on the structures, mechanical properties, permeability for oxygen and water vapor were discussed in this study. Mechanical properties of these films, which were evaluated by the tensile test and the barrier properties showed that the elongation at break (E) of the composite films decreased rapidly with the addition of chitosan, whereas, the tensile strength (TS) presented an almost opposite trend. Both the water vapour and oxygen transmission rate values were increased with the increasing amount of the chitosan in the composite films. Based on the obtained results, the better property of the composites films would be prepared chitosan/poly(vinyl alcohol) blends at a weight ratio of 3/5, and the tensile strength and elongation at break of the packaging films were 34.12 MPa, 40.24 % respectively. It was also observed that the water vapor permeability coefficient (Pv) and the oxygen permeability coefficient (P) of chitosan/poly(vinyl alcohol) composite packaging films prepared with weight ratio of 3/5 were 1.99×10-15 g•cm/cm2•s•Pa and 7.98×10-16 cm3•cm/cm2•s•Pa respectively. The composite films in this paper can be used in fresh-keeping or other fields as a kind of green packaging material.

scholarly journals Effect of cooling rates after annealing on the microstructure and properties of 1000MPa grade automobile steel for cold forming

2021 ◽  
Author(s):  
Ruifeng Dong ◽  
Qingbo Zhao ◽  
Xiaohong Bi ◽  
Deng Xiangtao ◽  
Wentian Shen ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Cooling Rate ◽  
Testing Machine ◽  
Phase Region ◽  
Two Phase ◽  
Tensile Testing Machine ◽  
Cooling Rates ◽  
Cold Forming ◽  
Automobile Steel

Abstract The effects of different cooling rates ( 0.05℃/s, 0.1℃/s, and 0.2℃/s ) on the microstructure and mechanical properties of 1000 MPa grade automobile steel for cold forming after two-phase annealing were studied. The microstructure of the experimental steel was observed by SEM and TEM, and its mechanical properties were tested by a universal tensile testing machine. The results showed that by increasing the cooling rate of two-phase annealing, more massive retained austenite, more uniform and fine ferrite, better elongation and higher ultimate tensile strength of steel can be obtained, so as to obtain better production of tensile strength and total elongation ( product of tensile strength and elongation, PSE ). The final result shows that after the test steel is quenched at 800℃ + 10 minutes and annealed in the two-phase region at 690℃ + 10 minutes, the faster the cooling rate, the better the mechanical properties. The mechanical properties of the steel plate are the best when the cooling rate reaches 0.2℃/s, and PSE can reach 27.44 GPa·%.

Sign in / Sign up

Export Citation Format

Share Document