scholarly journals Safety of Potato Consumption in Slovak Region Contaminated by Heavy Metals due to Previous Mining Activity

2017 ◽  
Vol 2017 ◽  
pp. 1-11 ◽  
Author(s):  
Janette Musilova ◽  
Judita Bystricka ◽  
Alena Vollmannova ◽  
Beata Janotova ◽  
Matyas Orsak ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Slovak Republic ◽  
Daily Intake ◽  
Chemical Properties ◽  
Total Content ◽  
Vegetation Period ◽  
Soil Samples ◽  
The European Union ◽  
Limit Values ◽  
Tolerable Weekly Intake

Heavy metals are among the most serious environmental contaminants in mining districts. Soil, as one of the main components of the environment, is the place of heavy metal entry into plants and consequently into the food chain, too. Potatoes grown in the region of Middle Spis (Slovakia) may be a source of increased content of heavy metals and pose a health risk to the consumer. The contents of heavy metals (Cd, Pb, and Ni) in potato and soil samples were determined using the AAS method and compared with limit values set by the Slovak Republic and the European Union. The content of heavy metals was determined in 12 potato cultivars with different length of vegetation period (mid-early, very early, and early, resp.), which were grown in three localities with a highly disturbed environment. Total contents and mobile forms of heavy metals as well as physical and chemical properties were determined in soil samples which were collected from the same sampling sites. Only Pb content in potato tubers was higher than the hygienic limit value (0.1 mg kg−1 FM) in 15 sampling sites (interval was n.d. –0.2298 mg kg−1 FM). The contents of exchangeable forms (total content) of heavy metals in soil were ranged between the intervals: Cd 0.004–0.055 (0.94–1 56), Pb 0.023–0.295 (17.00–26.80), and Ni 0.019–0.475 (30.80–71.00) mg kg−1. At current average consumption levels of potatoes, tolerable weekly intake (TWI) or tolerable daily intake (TDI) for observed heavy metals was not exceeded.

scholarly journals Chemical Properties of Heavy Metal-Contaminated Soils from a Korean Military Shooting Range: Evaluation of Pb Sources Using Pb Isotope Ratios

2021 ◽  
Vol 11 (15) ◽  
pp. 7099
Author(s):  
Inkyeong Moon ◽  
Honghyun Kim ◽  
Sangjo Jeong ◽  
Hyungjin Choi ◽  
Jungtae Park ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Contaminated Soils ◽  
Management Strategies ◽  
Chemical Properties ◽  
Heavy Metal Concentration ◽  
Soil Samples ◽  
Shooting Range ◽  
Geochemical Properties ◽  
Mineral Phases

In this study, the geochemical properties of heavy metal-contaminated soils from a Korean military shooting range were analyzed. The chemical behavior of heavy metals was determined by analyzing the soil pH, heavy metal concentration, mineral composition, and Pb isotopes. In total, 24 soil samples were collected from a Korean military shooting range. The soil samples consist of quartz, albite, microcline, muscovite/illite, kaolinite, chlorite, and calcite. Lead minerals, such as hydrocerussite and anglesite, which are indicative of a transformation into secondary mineral phases, were not observed. All soils were strongly contaminated with Pb with minor concentrations of Cu, Ni, Cd, and Zn. Arsenic was rarely detected. The obtained results are indicated that the soils from the shooting range are contaminated with heavy metals and have evidences of different degree of anthropogenic Pb sources. This study is crucial for the evaluation of heavy metal-contaminated soils in shooting ranges and their environmental effect as well as for the establishment of management strategies for the mitigation of environmental risks.

Organic and metallic pollutants in water treatment and natural wetlands: a review

2012 ◽  
Vol 65 (1) ◽  
pp. 76-99 ◽  
Author(s):  
K. Haarstad ◽  
H. J. Bavor ◽  
T. Mæhlum
Keyword(s):  
Heavy Metals ◽  
Aquatic Plants ◽  
Metal Uptake ◽  
High Capacity ◽  
Treatment Wetlands ◽  
The European Union ◽  
Toxic Heavy Metals ◽  
Limit Values ◽  
Fish Samples ◽  
Other Substances

A literature review shows that more than 500 compounds occur in wetlands, and also that wetlands are suitable for removing these compounds. There are, however, obvious pitfalls for treatment wetlands, the most important being the maintenance of the hydraulic capacity and the detention time. Treatment wetlands should have an adapted design to target specific compounds. Aquatic plants and soils are suitable for wastewater treatment with a high capacity of removing nutrients and other substances through uptake, sorption and microbiological degradation. The heavy metals Cd, Cu, Fe, Ni and Pb were found to exceed limit values. The studies revealed high values of phenol and SO4. No samples showed concentrations in sediments exceeding limit values, but fish samples showed concentrations of Hg exceeding the limit for fish sold in the European Union (EU). The main route of metal uptake in aquatic plants was through the roots in emergent and surface floating plants, whereas in submerged plants roots and leaves take part in removing heavy metals and nutrients. Submerged rooted plants have metal uptake potential from water as well as sediments, whereas rootless plants extracted metals rapidly only from water. Caution is needed about the use of SSF CWs (subsurface flow constructed wetlands) for the treatment of metal-contaminated industrial wastewater as metals are shifted to another environmental compartment, and stable redox conditions are required to ensure long-term efficiency. Mercury is one of the most toxic heavy metals and wetlands have been shown to be a source of methylmercury. Methyl Hg concentrations are typically approximately 15% of Hgt (total mercury). In wetlands polycyclic aromatic hydrocarbons (PAH), bisphenol A, BTEX, hydrocarbons including diesel range organics, glycol, dichlorodiphenyltrichloroethane (DDT), polychlorinated biphenyls (PCB), cyanide, benzene, chlorophenols and formaldehyde were found to exceed limit values. In sediments only PAH and PCB were found exceeding limit values. The pesticides found above limit values were atrazine, simazine, terbutylazine, metolachlor, mecoprop, endosulfan, chlorfenvinphos and diuron. There are few water quality limit values of these compounds, except for some well-known endocrine disrupters such as nonylphenol, phtalates, etc.

scholarly journals Arsenic and heavy metal concentrations in agricultural soils in South Savo province

2002 ◽  
Vol 11 (4) ◽  
pp. 285-300 ◽  
Author(s):  
V. MÄNTYLAHTI ◽  
P. LAAKSO
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Agricultural Soils ◽  
Mineral Soil ◽  
Soil Samples ◽  
Potential Hazard ◽  
Metal Concentrations ◽  
Limit Values ◽  
Heavy Metal Concentrations ◽  
Target Values

Increasing concentrations of arsenic and heavy metals in agricultural soils are becoming a growing problem in industrialized countries. These harmful elements represent the basis of a range of problems in the food chain, and are a potential hazard for animal and human health. It is therefore important to gauge their absolute and relative concentrations in soils that are used for crop production. In this study the arsenic and heavy metal concentrations in 274 mineral soil samples and 38 organogenic soil samples taken from South Savo province in 2000 were determined using the aqua regia extraction technique. The soil samples were collected from 23 farms.The elements analyzed were arsenic, cadmium, chromium, copper, mercury, nickel, lead and zinc. The median concentrations in the mineral soils were:As 2.90 mg kg –1, Cd 0.084 mg kg –1, Cr 17.0 mg kg –1, Cu 13.0 mg kg –1, Hg 0.060 mg kg –1, Ni 5.4 mg kg –1, Pb 7.7 mg kg –1, Zn 36.5 mg kg –1. The corresponding values in the organogenic soils were:As 2.80 mg kg –1, Cd 0.265 mg kg –1, Cr 15.0 mg kg –1, Cu 29.0 mg kg –1, Hg 0.200 mg kg –1, Ni 5.9 mg kg –1, Pb 11.0 mg kg –1, Zn 25.5 mg kg –1. The results indicated that cadmium and mercury concentrations in the mineral and organogenic soils differed. Some of the arsenic, cadmium and mercury concentrations exceeded the normative values but did not exceed limit values. Most of the agricultural fields in South Savo province contained only small amounts of arsenic and heavy metals and could be classified as “Clean Soil”. A draft for the target values of arsenic and heavy metal concentrations in “Clean Soil” is presented.;

scholarly journals State of Heavy Metals Pollution of Flooded Agricultural Land in the North Part of Republic of Srpska

2017 ◽  
Vol 17 (1) ◽  
pp. 19
Author(s):  
Tihomir Predić ◽  
Petra Nikić Nauth ◽  
Bojana Radanović ◽  
Alen Predić
Keyword(s):  
Heavy Metals ◽  
Soil Contamination ◽  
Agricultural Land ◽  
Total Content ◽  
Soil Samples ◽  
Available Phosphorus ◽  
The North ◽  
North Part ◽  
Grid Points ◽  
Phosphorus And Potassium

This paper presents the results of the research of soil contamination in flooded area located at the confluence of Bosna and Sava rivers. The sampling was performed according to a network of points Etrs89 reference European Network based on grid points of 500 m x 500 m. The total number of soil samples was 31 and 13 samples of sediment-mud. In the soil samples and sediment-mud samples various parameters were analyzed: pH H2O and 1 M KCl, humus (method by Tjurin), and the readily available phosphorus and potassium (AL method). The interpretation of total content of heavy metals in the soil was conducted according to Dutch Soil Remediation Circular (2009). The samples were analyzed for the total content of heavy metals: Pb, Cd, Cr, Ni, Zn, Cu (aqua regia digestion, AAS) and the elevated concentrations of Ni. However, Ni content in mud was from 240.5 mg/kg to 294.5 mg/kg, in soil it was from 128.9 mg/kg to 452.1 mg/kg. All mud samples were alkaline, and 79% of soil samples were alkaline and of neutral reaction. The analysis indicated that the flood in May 2014 was not caused by soil contamination with heavy metals, which however contributed to the increase of the overall content of these elements in the soil.

scholarly journals Seasonal content of heavy metals in the "soil–feed–milk–manure" system in horse husbandry in Kazakhstan

2021 ◽  
pp. 2947-2956
Author(s):  
Nazym Kozhanova ◽  
Nurzhan Sarsembayeva ◽  
Bozena Lozowicka ◽  
Zhassulan Kozhanov
Keyword(s):  
Heavy Metals ◽  
Adverse Effects ◽  
Soil Samples ◽  
Mixed Feed ◽  
Animal Products ◽  
Limit Values ◽  
Horse Manure ◽  
Environmentally Safe ◽  
Living Organisms

Background and Aim: The quality of food, especially animal-based food, is crucial for human health. However, the quality of milk and other animal products has become an acute cause for concern in Kazakhstan . Technogenic dispersion of heavy metals (HMs) causes adverse effects on living organisms and creates unfavorable conditions for the existence of humans, animals, and plants. The purpose of this study was to analyze the content of several HMs in samples of soil, horse feed (hay, mixed feed, and bran), mare's milk, and manure to assess bioaccumulation and possible adverse effects on the bodies of horses. An additional purpose was to identify areas with acceptable conditions for obtaining environmentally safe horse breeding products in the agricultural zones of the Almaty region, Kazakhstan. Materials and Methods: Samples were obtained from two farms in the Almaty region in 2020 (spring, summer, and autumn). In total, 72 soil samples were analyzed, which were taken from the upper humus horizon to the depth of the arable layer. Eighty-six samples were taken from the feed of horses. Green feed was represented by perennial and annual grasses (alsike clover, Medicago sativa, sweet yellow clover, as well as pea and oat mix). Barley and wheat bran stored in the warehouses of the farm were sampled for the research as feed supplements. The mixed feed comprised components such as maize and sunflower. In addition, 46 samples of mare's milk and 28 samples of horse manure were collected. The HM analysis was performed in the laboratory of the Kazakh-Japanese Innovation Center. The residual amounts of HMs were determined using an absorption spectrometer with a voltammetric analyzer. The content of cadmium (Cd), lead (Pb), mercury (Hg), and arsenic (As) in all the studied samples of soil, feed, mare's milk, and manure did not exceed the threshold limit values (TLVs), suggesting that the intake of these toxic elements into the human body with food was low. Results: The average Cd concentration was in the range of 0.29-0.31 mg/kg in soil samples and in the range of 0.20-0.27 mg/kg in feed samples. In milk, the Cd concentration varied from 0.01 to 0.02 mg/L and was lower in summer and higher in fall. The total average Cd content in horse manure was 0.1844 mg/kg. The concentration of Pb in soil samples ranged from 1.09 to 1.30 mg/kg with the lowest value in spring and the highest in fall. In the feed, the concentration of Pb varied from 0.14 to 0.76 mg/kg and in milk from 0.03 to 0.15 mg/L. The average concentrations of Hg and As in soil samples averaged 0.022 and 0.019 mg/kg, respectively, and were within the TLVs. Conclusion: In the study areas, the calculated transition rates in the soil–feed–milk–manure system revealed that the greatest transition of HMs was observed for Pb and Cd, and a smaller migration was observed for Hg and As. The tendency of accumulation of trace elements continued in the feed.

scholarly journals Status of soil heavy metals contamination using contamination indices in shallot fields

2021 ◽  
Vol 306 ◽  
pp. 04013
Author(s):  
Triyani Dewi ◽  
Edhi Martono ◽  
Eko Hanudin ◽  
Rika Harini
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Heavy Metal Contamination ◽  
Contamination Factor ◽  
Soil Samples ◽  
Limit Values ◽  
Central Java ◽  
Contamination Indices ◽  
Heavy Metals Contamination ◽  
The Status

Monitoring and assessment of heavy metal concentrations in shallot fields are needed to evaluate the potential risk of contamination due to heavy metals. This study aims to define the status of heavy metal contamination in shallot fields using contamination indices. A total of 184 soil samples (0-20 cm) were taken from shallot fields in Brebes Regency, Central Java. The soil samples were analyzed for the concentration of five heavy metals (Cd, Pb, Ni, Cr, and Co) with HNO3 and HClO4 extracts and measured using AAS. Assessment of the status of heavy metals contamination in the soil using contaminant factor (CF), geo-accumulation index (I-geo), and pollution load index (PLI). The mean concentration in shallot fields showed the following order Cr > Ni > Pb > Co > Cd and the concentration were still below critical limit values. Four metals are Pb, Cr, Co, and Ni are low contamination (CF<1), while Cd is considerable until very high contamination factor. Based on I-geo values, shallot fields are practically uncontaminated of Pb, Co, Ni, and Cr (I-geo<1), meanwhile the status of Cd is uncontaminated to moderately contaminated (0<I-geo<1). Generally, the shallot fields in Brebes Regency, Central Java is unpolluted with five metals (PLI<1).

scholarly journals Assessment of Heavy Metal Pollution in Soils from Farms in the Vicinity of Durumi Quarry Site in Mpape, Abuja Nigeria

2018 ◽  
Vol 13 (3) ◽  
pp. 360-373
Author(s):  
FATIMAH OYENIKE OJO ◽  
TUKURA BITRUS WOKHE ◽  
MADU PASCAL CHIMA
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Pollution ◽  
Heavy Metal Pollution ◽  
Rainy Season ◽  
Soil Depth ◽  
Chemical Properties ◽  
Dry Season ◽  
Soil Samples ◽  
World Health

Seasonal concentrations of eight total and bioavailable heavy metals (Cr, Cu, Cd, Zn, Mn, Ni, Pb an Fe), along with some physico chemical properties of soil in vegetable farms around the rock quarry in Durumi, Abuja was assessed to know the level of heavy metal pollution of the soil. Control and actual soil samples were collected from depths of 0.0 -5.0cm and 5.0 - 10.0cm during dry and rainy seasons. Heavy metal concentrations varied inconsistently in samples and control. Dry season levels of Zn(5.20mg/kg), Mn(19.44mg/kg), Ni(1.69mg/kg) and Pb(4.56mg/kg) and rainy season levels of Zn (0.26mg/kg), Pb(22.53mg/kg) at soil depth of 0.0 - 5.0cm, and dry season levels of Zn(1.19mgkg) and Ni(1.62mg/kg) along with rainy season levels of Cr (0.44mg/kg), Cd (0.06mg/kg), Zn(0.09mg/kg) and Fe(6.74mg/kg) at soil depth of 5.0 -10.0cm were all higher in samples than controls. However, seasonal mean total heavy metals in the soil samples were lower than the Maximum Allowable Limits (mg/Kg) for World Health Organization (WHO) and Food and Agriculture Organization (FAO). During dry season, heavy metals that indicated anthropogenic content, had anthropogenic levels that ranged in the order: Cd(16.67%) < Cu(54.17%)

scholarly journals Physicochemical Parameters and Heavy Metals Content of Soil Samples from Farms in Minna

2015 ◽  
Vol 58 ◽  
pp. 154-163
Author(s):  
Z. Abdulhamid ◽  
E.B. Agbaji ◽  
C.E. Gimba ◽  
A.S. Agbaji
Keyword(s):  
Heavy Metals ◽  
Cation Exchange Capacity ◽  
Physicochemical Parameters ◽  
Chemical Properties ◽  
Absorption Spectrometry ◽  
Exchange Capacity ◽  
Average Concentration ◽  
Soil Samples ◽  
Ph Values ◽  
Physico Chemical

Physico-chemical properties and heavy metals content of soils were determined from seven farms in Minna, central Nigeria. Conventional analytical methods were employed to determine the physico-chemical properties and the heavy metals were analysed by atomic absorption spectrometry. The result showed that pH values ranged from 6.64 - 7.70 indicating slight acidity to slight alkalinity of the soils. The total organic carbon values ranged from 0.95-2.25 % resulting in the presence of organic matter (1.63-3.87). The electrical conductivity values ranged from 17-37 μS/cm. The cation exchange capacity of the soil samples ranged from 3.68-5.15 cmol/kg. The heavy metals levels were in the following range: Cd (0.00018-0.00134 mg/g), Cu (0.0069-0.0476 mg/g), Fe (1.942-2.2059 mg/g), Mn (0.1825-0.3696 mg/g), Ni (0.0065-0.0069 mg/g) and Zn (0.0157-0.2252 mg/g). The concentration of the metals in the soil samples varied according to the following trend: Fe>Mn>Zn> Cu>Ni>Cd. The average concentration of all the metals in each farm also gave the trend Farm B>Farm G>Farm E>Farm C>Farm F>Farm D>Farm A. The findings indicate the presence of heavy metals in all the farms but only Fe was above the FAO/WHO standards.

Status of accumulated heavy metals in soils from organic and conventional farms in Akinyele Local Government, Ibadan, Oyo State, Nigeria

2021 ◽  
Vol 20 (1) ◽  
pp. 29-40
Author(s):  
T.E. Odunjo ◽  
E.Y. Thomas
Keyword(s):  
Heavy Metals ◽  
Local Government ◽  
Chemical Properties ◽  
Soil Samples ◽  
Residual Fraction ◽  
Organic Farm ◽  
Conventional Farms ◽  
Sequential Extraction Method ◽  
Different Depths ◽  
Conventional Farm

The risk associated with the presence of heavy metals in soil is their potential toxicity and ability to enter the ecosystem through the food chain. Total heavy metal content of a soil is inadequate for predicting the toxicity of heavy metals in soil. Therefore, the current study was designed to determine the various forms in which the selected heavy metals: Chromium (Cr), Lead (Pb), Nickel (Ni), and Cadmium (Cd) exist in the soil to ascertain the available forms for plant uptake. Soils samples were randomly collected from selected organic and conventional farms in Akinyele local government, Ibadan, Oyo State, Nigeria, at different depths (0-15, 15-30 and 30-45 cm) using random sampling method. Routine analysis was carried out to determine the textural classes and chemical properties of soil samples. The total heavy metals of the soil samples were determined and their fractions were analysed using sequential extraction method. Cadmium was not detected in most of the soil samples. Residual fraction was predominant in all the analysed heavy metals. In addition, Cr was more associated with the oxidizable fraction having a range of 0.1 mg/kg from Ajibode organic farm (AO) at 30-45 cm depth. Pb and Ni were both more associated with reducible fraction with Pb having a range of 2.7 mg/kg in Ajibode conventional farm (AI) at 0-15 cm depth and 0.1 mg/kg in (AI) at 30-45 cm depth. Reducible values of Ni ranges from 4.3 mg/kg in AI at 0-15 cm to 1.4 mg/kg in AO at 30-45 cm. The apparent mobility and bioavailability for these heavy metals in the studied soils were in the order: Pb>Cr>Ni. The result showed that uptake of heavy metals by the plants would be low as the concentration of the exchangeable form of the heavy metals in the analysed soil sample has the least concentration when compared with the other forms.

scholarly journals Concentration of some metals in the muscles of fish from selected lakes of Warmia and Mazury region (Poland)

2013 ◽  
Vol 82 (1) ◽  
pp. 67-71 ◽  
Author(s):  
Anna Spodniewska ◽  
Dariusz Barski
Keyword(s):  
Heavy Metals ◽  
Muscle Tissue ◽  
Absorption Spectrometry ◽  
Limited Information ◽  
The European Union ◽  
Fish Muscles ◽  
Tolerable Weekly Intake ◽  
North Eastern ◽  
The Mean ◽  
Mean Concentration

In view of very scarce and limited information concerning the content of heavy metals in tissues of fish from the lakes in north-eastern Poland, the aim of the study was to determine the content of some heavy metals in the muscle tissue of two fish species: bream (Abramis brama) (n = 60) and pikeperch (Sander lucioperca) (n = 60) caught in selected lakes of Warmia and Mazury region (Poland) in 2010 as well as to asses human health safety. The concentration of lead (Pb), mercury (Hg), copper (Cu), iron (Fe) and zinc (Zn) in the muscle tissue of bream and pikeperch was determined by atomic absorption spectrometry. The mean concentration of toxic metals (Pb and Hg) in muscles of bream was 0.07 mg/kg and 0.03 mg/kg, respectively, and 0.10 mg/kg and 0.13 mg/kg in muscles of pikeperch, respectively. The mean concentration of Cu, Fe and Zn found in the muscles of bream was 0.33 mg/kg, 7.27 mg/kg and 6.12 mg/kg in muscles of pikeperch it was 0.21 mg/kg, 5.56 mg/kg and 6.02 mg/kg, respectively. It was found that the content of the analysed metals in fish muscles was low and did not exceed the values of limits admissible in the European Union. At the assumed mean and maximum concentration of Pb and Hg, the values of PTWI (provisional tolerable weekly intake) were not exceeded (i.e. 0.56% PTWI for Pb and 3.01% PTWI for Hg), therefore the consumption of fish originating from selected lakes of Warmia and Mazury does not constitute a threat to consumer health.

Sign in / Sign up

Export Citation Format

Share Document