scholarly journals Influence of Cement Type and Water-to-Cement Ratio on the Formation of Thaumasite

2017 ◽  
Vol 2017 ◽  
pp. 1-6 ◽  
Author(s):  
Ailian Zhang ◽  
Linchun Zhang
Keyword(s):  
Portland Cement ◽  
Cement Mortar ◽  
Sulfate Solution ◽  
Sulfate Attack ◽  
Strength Development ◽  
X Ray Diffraction ◽  
Limestone Filler ◽  
Visual Appearance ◽  
Cement Ratio ◽  
Water To Cement Ratio

Cement mortar prisms were prepared with three different cement types and different water-to-cement ratios plus 30% mass of limestone filler. After 28 days of curing in water at room temperature, these samples were submerged in 2% magnesium sulfate solution at 5°C and the visual appearance and strength development for every mortar were measured at intervals up to 1 year. Samples selected from the surface of prisms after 1-year immersion were examined by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. The results show that mortars with sulfate resisting Portland cement (SRC) or sulphoaluminate cement (SAC) underwent weaker degradation due to the thaumasite form of sulfate attack than mortars with ordinary Portland cement (OPC). A lower water-to-cement ratio leads to better resistance to the thaumasite form of sulfate attack of the cement mortar. A great deal of thaumasite or thaumasite-containing materials formed in the OPC mortar, and a trace of thaumasite can also be detected in SRC and SAC mortars. Therefore, the thaumasite form of sulfate attack can be alleviated but cannot be avoided by the use of SAC or SRC.

scholarly journals Evaluation of external sulfate attack (Na2SO4 and MgSO4): Portland cement mortars containing fillers

2020 ◽  
Vol 13 (3) ◽  
pp. 644-655 ◽  
Author(s):  
D. J. DE SOUZA ◽  
M. H. F. MEDEIROS ◽  
J. HOPPE FILHO
Keyword(s):  
Portland Cement ◽  
Linear Expansion ◽  
Sulfate Attack ◽  
Hardened Cement ◽  
X Ray Diffraction ◽  
Limestone Filler ◽  
Sulfate Ions ◽  
X Ray ◽  
Cement Mortars ◽  
Physical And Chemical

Abstract Sulfate attack is a term used to describe a series of chemical reactions between sulfate ions and hydrated compounds of the hardened cement paste. The present study aims to evaluate the physical (linear expansion, flexural and compressive strength) and mineralogical properties (X-ray diffraction) of three different mortar compositions (Portland Cement CPV-ARI with limestone filler and, with a quartz filler, in both cases with 10% replacement of the cement by weight) against sodium and magnesium sulfate attack (concentration of SO4 2- equal to 0.7 molar). The data collected indicate that the replacing the cement by the two fillers generate different results, the quartz filler presented a mitigating behaviour towards the sulfate, and the limestone filler was harmful to Portland cement mortars, in both physical and chemical characteristics.

scholarly journals Experimental Study on Effective Chloride Diffusion Coefficient of Cement Mortar by Different Electrical Accelerated Measurements

Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 240
Author(s):  
Jianlan Chen ◽  
Jiandong Wang ◽  
Rui He ◽  
Huaizhu Shu ◽  
Chuanqing Fu
Keyword(s):  
Diffusion Coefficient ◽  
Cement Mortar ◽  
Early Stage ◽  
Chloride Concentration ◽  
Chloride Diffusion ◽  
Chloride Diffusion Coefficient ◽  
Cement Ratio ◽  
Water To Cement Ratio ◽  
Good Consistency ◽  
Determination Methods

This study investigated the effective chloride diffusion coefficient of cement mortar with different water-to-cement ratio (w/c) under electrical accelerated migration measurement. The cumulative chloride concentration in anode cell solution and the cumulative chloride concentration drop in the cathode cell solution was measured by RCT measurement and the results were further used to calculate the chloride diffusion coefficient by Nordtest Build 355 method and Truc method. The influence of w/c on cement mortar’s chloride coefficient was investigated and the chloride diffusion coefficient under different determination methods were compared with other researchers’ work, a good consistency between this work’s results and literatures’ results was obtained. The results indicated that the increased w/c of cement mortar samples will have a higher chloride diffusion coefficient. The cumulative chloride concentration drop in the cathode cell solution will have deviation in early stage measurement (before 60 h) which will result in overestimation of the effective chloride diffusion coefficient.

Deterioration of concrete containing limestone powder exposed to sulfate attack at ambient temperature

2021 ◽  
Vol 11 (5) ◽  
pp. 724-731
Author(s):  
Hemin Liu ◽  
Qian Huang ◽  
Liang Zhao
Keyword(s):  
Ambient Temperature ◽  
Sulfate Solution ◽  
Sulfate Attack ◽  
Limestone Powder ◽  
X Ray Diffraction ◽  
X Ray ◽  
Mineral Phases ◽  
Adverse Influence ◽  
Powder Content ◽  
Scanning Electron

This study investigates the deterioration of concrete containing limestone powder exposed to sulfate solution under ambient temperature (20~25 °C). Microstructure and mineral phases within the attacked concrete were measured by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). It was found that the addition of limestone powder increased the initial porosity of concrete. Consequently, a larger amount of SO2–4 ions diffused into the concrete containing limestone powder, and their degree of deterioration caused by sulfate attack increased with the increase in limestone powder content. At ambient temperature, gypsum and ettringite were the major attack products, respectively within the surface and nearsurface portions of concrete containing limestone powder, which was consistent with the products of sulfate attack within concrete without limestone powder. Therefore, the type and distribution of the attack products in concrete had not been revised due to the addition of limestone powder. Nevertheless, the adverse influence of limestone powder on the sulfate resistance of concrete, even at ambient temperature, should be considered. Furthermore, effective measures should be implemented to improve the durability of concrete containing limestone powder in this environment.

EFFECT OF STYRENE-BUTADIENE COPOLYMER (SBR) LATEX ON MECHANICAL AND TRANSPORT PROPERTIES OF PORTLAND CEMENT MORTAR

2020 ◽  
Vol 15 (4) ◽  
pp. 185-197
Author(s):  
Daniel Hatungimana ◽  
Şemsi Yazici ◽  
Şevket Orhan ◽  
Ali Mardani-Aghabaglou
Keyword(s):  
Mechanical Properties ◽  
Portland Cement ◽  
Detrimental Effect ◽  
Cement Mortar ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Replacement Level ◽  
Cement Production ◽  
Cement Ratio ◽  
Styrene Butadiene

ABSTRACT Portland cement is extensively used as a binder in concrete production. However, with Portland cement production, 5% of the natural resources used in this production are consumed, constituting 5–7% of the total CO2 emission. In order to mitigate the environmental problems associated with cement production, styrene-butadiene rubber latex was used as cement replacement up to 20%. In this study, compressive strength, flexural strength, unit weight, water absorption, open porosity, water sorptivity and the chloride ion permeability of Portland cement mortar mixtures modified by styrene-butadiene rubber (SBR) polymeric latex were investigated. For this purpose, the sand/cement ratio and the water/cement ratio were kept constant as 3/1 and 0.5, respectively. In addition to the control mixture containing no polymer, 1, 2, 3, 5, 10 and 20 wt.% of cement was replaced with SBR. In this way, seven mortar mixtures were prepared. Mixed curing (wet cure and dry cure) method was applied to the mortar specimens. Results showed that up to a 5% replacement level, it is possible to improve the mechanical properties of cement mortars with SBR latex addition. However, at a 10% and 20% replacement level, SBR had a significant detrimental effect on the mechanical properties of polymer modified mortars. However, the transport properties decreased with the incorporation rate of SBR latex and the detrimental effect of SBR replacement was more pronounced in 20% SBR mortar mixtures.

scholarly journals CO2 Curing Efficiency for Cement Paste and Mortars Produced by a Low Water-to-Cement Ratio

Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3883
Author(s):  
Seong Ho Han ◽  
Yubin Jun ◽  
Tae Yong Shin ◽  
Jae Hong Kim
Keyword(s):  
Cement Paste ◽  
Pressure Vessel ◽  
Gas Pressure ◽  
Strength Development ◽  
Co2 Uptake ◽  
Cement Pastes ◽  
Co2 Gas ◽  
Cement Ratio ◽  
Mix Proportion ◽  
Water To Cement Ratio

Curing by CO2 is a way to utilize CO2 to reduce greenhouse gas emissions. Placing early-age cement paste in a CO2 chamber or pressure vessel accelerates its strength development. Cement carbonation is attributed to the quickened strength development, and CO2 uptake can be quantitatively evaluated by measuring CO2 gas pressure loss in the pressure vessel. A decrease in CO2 gas pressure is observed with all cement pastes and mortar samples regardless of the mix proportion and the casting method; one method involves compacting a low water-to-cement ratio mix, and the other method comprises a normal mix consolidated in a mold. The efficiency of the CO2 curing is superior when a 20% concentration of CO2 gas is supplied at a relative humidity of 75%. CO2 uptake in specimens with the same CO2 curing condition is different for each specimen size. As the specimen scale is larger, the depth of carbonation is smaller. Incorporating colloidal silica enhances the carbonation as well as the hydration of cement, which results in contributing to the increase in the 28-day strength.

scholarly journals Difference in Strength Development between Cement-Treated Sand and Mortar with Various Cement Types and Curing Temperatures

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4999
Author(s):  
Lanh Si Ho ◽  
Kenichiro Nakarai ◽  
Kenta Eguchi ◽  
Yuko Ogawa
Keyword(s):  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Bound Water ◽  
Curing Temperature ◽  
Strength Development ◽  
Early Age ◽  
Cement Type ◽  
A Value ◽  
Water To Cement Ratio ◽  
Novel Method

To improve the strength of cement-treated sand effectively, the use of various cement types was investigated at different curing temperatures and compared with the results obtained from similar mortars at higher cement contents. The compressive strengths of cement-treated sand specimens that contained high early-strength Portland cement (HPC) cured at elevated and normal temperatures were found to be higher than those of specimens that contained ordinary Portland cement (OPC) and moderate heat Portland cement at both early and later ages. At 3 days, the compressive strength of the HPC-treated sand specimen, normalized with respect to that of the OPC under normal conditions, is nearly twice the corresponding value for the HPC mortar specimens with water-to-cement ratio of 50%. At 28 days, the normalized value for HPC-treated sand is approximately 1.5 times higher than that of mortar, with a value of 50%. This indicates that the use of HPC contributed more to the strength development of the cement-treated sand than to that of the mortar, and the effects of HPC at an early age were higher than those at a later age. These trends were explained by the larger quantity of chemically bound water observed in the specimens that contained HPC, as a result of their greater alite contents and porosities, in cement-treated sand. The findings of this study can be used to ensure the desired strength development of cement-treated soils by considering both the curing temperature and cement type. Furthermore, they suggested a novel method for producing a high internal temperature for promoting the strength development of cement-treated soils.

scholarly journals Evaluation the effect of lime on the plastic and hardened properties of cement mortar and quantified using Vipulanandan model

2019 ◽  
Vol 9 (1) ◽  
pp. 468-480 ◽  
Author(s):  
Warzer Qadir ◽  
Kawan Ghafor ◽  
Ahmed Mohammed
Keyword(s):  
Cement Mortar ◽  
Plastic Properties ◽  
Cement Ratio ◽  
Lime Content ◽  
Setting Times ◽  
Water To Cement Ratio ◽  
Bond Strengths ◽  
Hardened Properties ◽  
Compressive And Flexural Strengths ◽  
The Relationship

AbstractIn this study, the effect of lime content (L %) on the plastic properties such as water-cement ratio (w/c), setting times, flowability, compressive, flexural and bond strengths of cement mortar were investigated. Based on the information in the literature the amount of lime varied between 0 to 45% (by weight of cement). The experimental results were compared with the data collected from different research studies and quantified using two different models. The plastic and hardened properties of the cement mortar modified with different percentage of lime were conducted according to the ASTM and BS standards. Based on the literature data the water to cement ratio (w/c) ranged between 0.3-0.74 percent, the w/c of 0.5 was selected in this study. The compressive and flexural strengths of cement mortar modified with lime up to 28 days of curing were ranged between 3 MPa to 65 MPa and 2 MPa to 12 MPa respectively. The compressive, flexural and bond strengths of the cement mortar decreased with increasing lime content. Vipulanandan correlation model was used to correlate the relationship between lime with consistency, setting times, flowability and compressive strength of cement mortar. Compressive and flexural strengths of cement mortar modified with lime were quantified very well as a function of w/c, lime content and curing time using nonlinear relationship.

scholarly journals Influence of cement replacement with limestone filler on the properties of concrete

2021 ◽  
Vol 64 (3) ◽  
pp. 165-170
Author(s):  
Ksenija Tešić ◽  
Snežana Marinković ◽  
Aleksandar Savić
Keyword(s):  
Particle Size ◽  
Compressive Strength ◽  
Mineralogical Composition ◽  
Limestone Filler ◽  
Green Concrete ◽  
Cement Ratio ◽  
Cement Replacement ◽  
Concrete Mixtures ◽  
Water To Cement Ratio ◽  
Compressive Strength Of Concrete

This paper presents an experimental research of one type of green concrete in which Portland cement was replaced with two types of limestone filler of the same origin and mineralogical composition, but with a different fineness of particles. Ten concrete mixtures were designed in which 0%, 15%, 30% and 45% (by mass) of cement were replaced with filler. The water to cement ratio for each mixture was constant (w/c=0.54), and the water to powder ratio was decreasing with increasing cement replacement. Particle size distribution was selected using Funk and Dinger, as well as using Fuller's model. The results showed that it is possible to increase the compressive strength of concrete by reducing 45% of cement, but further research should be focused on improving the workability.

THE EFFECT OF ADDITION NANOPARTICLES ON SHRINKAGE PROPERTY OF ORDINARY PORTLAND CEMENT

2021 ◽  
Vol 25 (Special) ◽  
pp. 2-78-2-82
Author(s):  
Haider K. Ahmed ◽  
◽  
Mohammed A. Abdulrehman ◽  
Keyword(s):  
Compressive Strength ◽  
Carbon Black ◽  
Portland Cement ◽  
Cement Mortar ◽  
Cement Ratio ◽  
Water Cement Ratio ◽  
Carbon Black Nanoparticles ◽  
Flow Table ◽  
Compressive Strength Test ◽  
Negative Effect

Two types of nanomaterial: Tio2 nanoparticles (NPs) and carbon black NPs have used in this research to study their effect on compressive strength, shrinkage and flow table tests Cement mortar. The mixing ratio was 1:2.7:0.485 (cement, sand, water/cement ratio) for compressive strength test and 1:2 (cement, sand) with the water/cement ratio was a variable value for dry shrinkage test. The two nanoparticles’ ratios are (0.25%, 0.75%, 1.25 % and 1.75%) by weight of the Portland cement. The test results show that the highest value of compressive strength was obtained when using Tio2 at 1.25% wt. of cement. But when using carbon black nanoparticles, the greatest value was obtained when adding it with a ratio of 1.75 % wt. of cement. Using two NPs when added to cement mortar has a negative effect on the shrinkage value.

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