scholarly journals Deterioration and Microstructural Evolution of the Fly Ash Geopolymer Concrete against MgSO4Solution

2017 ◽  
Vol 2017 ◽  
pp. 1-11 ◽  
Author(s):  
Tao Long ◽  
Qingyuan Wang ◽  
Zhongwei Guan ◽  
Yu Chen ◽  
Xiaoshuang Shi
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Magnesium Sulfate ◽  
Strength Loss ◽  
Sulfate Attack ◽  
Aluminum Silicate ◽  
Geopolymer Concrete ◽  
Portland Cement Concrete ◽  
Sodium Aluminum Silicate ◽  
Magnesium Aluminum Silicate

Fly ash geopolymer concrete (FAGC) and ordinary Portland cement concrete (OPCC) specimens were immersed in 5% MgSO4solution undergoing 32 wetting-drying and heating-cooling cycles. Their compressive behavior was investigated after every 8 cycles. Several microstructure analysis techniques were applied on the samples to identify the materials formed due to magnesium sulfate attack, including XRD, FTIR, SEM, and EDS. Experimental results elucidated that the compressive strength loss ratio in the heating group of FAGC was 12.7%, while that of OPCC was 17.8%, which means that FAGC had better magnesium sulfate resistance than OPCC. The compressive strength loss of OPCC was due to the formation of gypsum under the magnesium sulfate attack exposed to wetting-drying and heating-cooling cycles. The deterioration mechanisms of FAGC against MgSO4solution were discovered to be that sodium aluminum silicate hydrate (N-A-S-H) gels reacted with MgSO4, leading to the creation of low strength magnesium aluminum silicate hydrate (M-A-S-H) gels.

Fly Ash Slag Geopolymer Concrete: Resistance to Sodium and Magnesium Sulfate Attack

2016 ◽  
Vol 28 (12) ◽  
pp. 04016148 ◽  
Author(s):  
William Gustavo Valencia Saavedra ◽  
Daniela Eugenia Angulo ◽  
Ruby Mejía de Gutiérrez
Keyword(s):  
Fly Ash ◽  
Magnesium Sulfate ◽  
Sulfate Attack ◽  
Geopolymer Concrete

Development of sustainable construction material from fly ash class C

2020 ◽  
Vol 18 (6) ◽  
pp. 1615-1640
Author(s):  
Eric Asa ◽  
Monisha Shrestha ◽  
Edmund Baffoe-Twum ◽  
Bright Awuku
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Portland Cement ◽  
Alkaline Solution ◽  
Sustainable Construction ◽  
Geopolymer Concrete ◽  
Curing Time ◽  
Portland Cement Concrete ◽  
Cement Concrete ◽  
Content Type

Purpose Environmental issues caused by the production of Portland cement have led to it being replaced by waste materials such as fly ash, which is more economical and safer for the environment. Also, fly ash is a material with sustainable properties. Therefore, this paper aims to focus on the development of sustainable construction materials using 100% high-calcium fly ash and potassium hydroxide (KOH)-based alkaline solution and study the engineering properties of the resulting fly ash-based geopolymer concrete. Laboratory tests were conducted to determine the mechanical properties of the geopolymer concrete such as compressive strength, flexural strength, curing time and slump. In phase I of the study, carbon nanotubes (CNTs) were added to determine their effect on the strength of the geopolymer mortar. The results derived from the experiments indicate that mortar and concrete made with 100% fly ash C require an alkaline solution to produce similar (comparable) strength characteristics as Portland cement concrete. However, it was determined that increasing the amount of KOH generates a considerable amount of heat causing the concrete to cure too quickly; therefore, it is notable to forming a proper bond was unable to form a stronger bond. This study also determined that the addition of CNTs to the mix makes the geopolymer concrete tougher than the traditional concrete without CNT. Design/methodology/approach Tests were conducted to determine properties of the geopolymer concrete such as compressive strength, flexural strength, curing time and slump. In Phase I of the study, CNTs were studied to determine their effect on the strength of the geopolymer mortar. Findings The results derived from the experiments indicate that mortar and concrete made with 100% fly ash C require an alkaline solution to produce the same strength characteristics as Portland cement concrete. However, it was determined that increasing the amount of KOH generates too much heat causing the concrete to cure too quickly; therefore, it is notable to forming a proper bond. This study also determined that the addition of CNTs to the mix makes the concrete tougher than concrete without CNT. Originality/value This study was conducted at the construction engineering and management concrete laboratory at North Dakota State University in Fargo, North Dakota. All the experiments were conducted and analyzed by the authors.

scholarly journals Comparative Study Involving Effect of Curing Regime on Elastic Modulus of Geopolymer Concrete

Buildings ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 101 ◽  
Author(s):  
Peiman Azarsa ◽  
Rishi Gupta
Keyword(s):  
Compressive Strength ◽  
Elastic Modulus ◽  
Fly Ash ◽  
Resonant Frequency ◽  
Construction Material ◽  
Bottom Ash ◽  
Geopolymer Concrete ◽  
Portland Cement Concrete ◽  
Steam Curing ◽  
Curing Regime

Geopolymer Concrete (GPC) as a cement-less construction material has attracted worldwide attention due to its lower carbon footprint. There are numerous studies reported on GPC made using different by-products including fly-ash. However, since the use of bottom-ash is comparatively limited, making potassium-based GPC using this waste can be an alternative to Portland Cement Concrete (PCC). In this study, two methods of accelerated curing were used to determine the influence of elevated temperature on the compressive strength of GPC, composed of 50% bottom-ash and 50% fly-ash. GPC specimens were cured using various temperatures including ambient, 30 °C, 45 °C, 60 °C, and 80 °C for 24 h, all followed by 28 days of ambient curing. The highest compressive strength was obtained with steam curing at a temperature of 80 °C for a duration of 24 h. It is of great significance to evaluate elastic modulus of the concrete mixture so that the short-term rigidity of structures subjected to elongation, bending, or compression can be predicted. In this study, a longitudinal Resonant Frequency Test (RFT) as a non-destructive test (NDT) was used to calculate the elastic modulus of both GPC and a comparative PCC mix. Based on the results, PCC had higher resonant frequency (by about 1000 Hz) compared to GPC. A review of empirical models for predicting GPC’s elastic modulus showed that all of the predicted elastic modulus values were lower than experimental values.

scholarly journals Practical Prediction Models of Tensile Strength and Reinforcement-Concrete Bond Strength of Low-Calcium Fly Ash Geopolymer Concrete

Polymers ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 875
Author(s):  
Chenchen Luan ◽  
Qingyuan Wang ◽  
Fuhua Yang ◽  
Kuanyu Zhang ◽  
Nodir Utashev ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Fly Ash ◽  
Bond Strength ◽  
Prediction Models ◽  
Splitting Tensile Strength ◽  
Geopolymer Concrete ◽  
Structural Factors ◽  
Test Results ◽  
Portland Cement Concrete ◽  
Low Calcium

There have been a few attempts to develop prediction models of splitting tensile strength and reinforcement-concrete bond strength of FAGC (low-calcium fly ash geopolymer concrete), however, no model can be used as a design equation. Therefore, this paper aimed to provide practical prediction models. Using 115 test results for splitting tensile strength and 147 test results for bond strength from experiments and previous literature, considering the effect of size and shape on strength and structural factors on bond strength, this paper developed and verified updated prediction models and the 90% prediction intervals by regression analysis. The models can be used as design equations and applied for estimating the cracking behaviors and calculating the design anchorage length of reinforced FAGC beams. The strength models of PCC (Portland cement concrete) overestimate the splitting tensile strength and reinforcement-concrete bond strength of FAGC, so PCC’s models are not recommended as the design equations.

scholarly journals Assessment of the Rheological and Mechanical Properties of Geopolymer Concrete Comprising Fly Ash and Fluid Catalytic Cracking Residue as Aluminosilicate Precursor

2021 ◽  
Vol 11 (7) ◽  
pp. 3032
Author(s):  
Tuan Anh Le ◽  
Sinh Hoang Le ◽  
Thuy Ninh Nguyen ◽  
Khoa Tan Nguyen
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Elastic Modulus ◽  
Fly Ash ◽  
Flexural Strength ◽  
Catalytic Cracking ◽  
Fluid Catalytic Cracking ◽  
High Alumina ◽  
Geopolymer Concrete ◽  
Sem Images

The use of fluid catalytic cracking (FCC) by-products as aluminosilicate precursors in geopolymer binders has attracted significant interest from researchers in recent years owing to their high alumina and silica contents. Introduced in this study is the use of geopolymer concrete comprising FCC residue combined with fly ash as the requisite source of aluminosilicate. Fly ash was replaced with various FCC residue contents ranging from 0–100% by mass of binder. Results from standard testing methods showed that geopolymer concrete rheological properties such as yield stress and plastic viscosity as well as mechanical properties including compressive strength, flexural strength, and elastic modulus were affected significantly by the FCC residue content. With alkali liquid to geopolymer solid ratios (AL:GS) of 0.4 and 0.5, a reduction in compressive and flexural strength was observed in the case of geopolymer concrete with increasing FCC residue content. On the contrary, geopolymer concrete with increasing FCC residue content exhibited improved strength with an AL:GS ratio of 0.65. Relationships enabling estimation of geopolymer elastic modulus based on compressive strength were investigated. Scanning electron microscope (SEM) images and X-ray diffraction (XRD) patterns revealed that the final product from the geopolymerization process consisting of FCC residue was similar to fly ash-based geopolymer concrete. These observations highlight the potential of FCC residue as an aluminosilicate source for geopolymer products.

Microstructure and Mechanical Properties of Ambiently-Cured Blended Coal Ash-Based Geopolymer Concrete

2016 ◽  
Vol 857 ◽  
pp. 400-404
Author(s):  
Tian Yu Xie ◽  
Togay Ozbakkaloglu
Keyword(s):  
Mechanical Properties ◽  
Experimental Study ◽  
Compressive Strength ◽  
Fly Ash ◽  
Bottom Ash ◽  
Coal Ash ◽  
Geopolymer Concrete ◽  
Mass Ratio ◽  
Blended Coal ◽  
Microstructure And Mechanical Properties

This paper presents the results of an experimental study on the behavior of fly ash-, bottom ash-, and blended fly and bottom ash-based geopolymer concrete (GPC) cured at ambient temperature. Four bathes of GPC were manufactured to investigate the influence of the fly ash-to-bottom ash mass ratio on the microstructure, compressive strength and elastic modulus of GPC. All the results indicate that the mass ratio of fly ash-to-bottom ash significantly affects the microstructure and mechanical properties of GPCs

scholarly journals Novel Analytical Method for Mix Design and Performance Prediction of High Calcium Fly Ash Geopolymer Concrete

Polymers ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 900
Author(s):  
Chamila Gunasekara ◽  
Peter Atzarakis ◽  
Weena Lokuge ◽  
David W. Law ◽  
Sujeeva Setunge
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Gradient Algorithm ◽  
Geopolymer Concrete ◽  
Statistical Regression ◽  
Solid Ratio ◽  
Marquardt Algorithm ◽  
High Calcium ◽  
High Calcium Fly Ash ◽  
Matlab Programming

Despite extensive in-depth research into high calcium fly ash geopolymer concretes and a number of proposed methods to calculate the mix proportions, no universally applicable method to determine the mix proportions has been developed. This paper uses an artificial neural network (ANN) machine learning toolbox in a MATLAB programming environment together with a Bayesian regularization algorithm, the Levenberg-Marquardt algorithm and a scaled conjugate gradient algorithm to attain a specified target compressive strength at 28 days. The relationship between the four key parameters, namely water/solid ratio, alkaline activator/binder ratio, Na2SiO3/NaOH ratio and NaOH molarity, and the compressive strength of geopolymer concrete is determined. The geopolymer concrete mix proportions based on the ANN algorithm model and contour plots developed were experimentally validated. Thus, the proposed method can be used to determine mix designs for high calcium fly ash geopolymer concrete in the range 25–45 MPa at 28 days. In addition, the design equations developed using the statistical regression model provide an insight to predict tensile strength and elastic modulus for a given compressive strength.

scholarly journals Strength and Durability Performance of Alkali-Activated Rice Husk Ash Geopolymer Mortar

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Yun Yong Kim ◽  
Byung-Jae Lee ◽  
Velu Saraswathy ◽  
Seung-Jun Kwon
Keyword(s):  
Compressive Strength ◽  
Rice Husk ◽  
Rice Husk Ash ◽  
Polymerization Reaction ◽  
Strength Development ◽  
Geopolymer Concrete ◽  
Portland Cement Concrete ◽  
Mix Proportion ◽  
Strength And Durability ◽  
Alkali Activated

This paper describes the experimental investigation carried out to develop the geopolymer concrete based on alkali-activated rice husk ash (RHA) by sodium hydroxide with sodium silicate. Effect on method of curing and concentration of NaOH on compressive strength as well as the optimum mix proportion of geopolymer mortar was investigated. It is possible to achieve compressive strengths of 31 N/mm2and 45 N/mm2, respectively for the 10 M alkali-activated geopolymer mortar after 7 and 28 days of casting when cured for 24 hours at 60°C. Results indicated that the increase in curing period and concentration of alkali activator increased the compressive strength. Durability studies were carried out in acid and sulfate media such as H2SO4, HCl, Na2SO4, and MgSO4environments and found that geopolymer concrete showed very less weight loss when compared to steam-cured mortar specimens. In addition, fluorescent optical microscopy and X-ray diffraction (XRD) studies have shown the formation of new peaks and enhanced the polymerization reaction which is responsible for strength development and hence RHA has great potential as a substitute for ordinary Portland cement concrete.

The Effect of Substituting Rdf on the Physical and Environmental Properties of Coal Fly Ash

1988 ◽  
Vol 136 ◽  
Author(s):  
Ashaari B. Mohamad ◽  
David L. Gress
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Physical Properties ◽  
Activity Index ◽  
Coal Fly Ash ◽  
Pozzolanic Activity ◽  
Portland Cement Concrete ◽  
Fly Ash Concrete ◽  
Refuse Derived Fuel ◽  
Cadmium And Lead

ABSTRACTRefuse-derived-fuel (RDF) consisting mainly of waste paper and plastics is a viable fuel source for the production of power. An experimental test burn partially substituting coal with RDF was undertaken by the Public Service of New Hampshire at the Merrimack Power Station.Five percent and ten percent RDF were substituted, on a BTU basis, for coal in the test bums. The chemical and physical properties of the resulting fly ash were determined. Twelve test burn days were run with 4 days of 5% RDF and 8 days of 10% RDF. Emphasis was placed on investigating the effect of the RDF fly ash on Portland cement concrete.Most of the chemical and physical properties of the coal-RDF fly ash were found to be comparable with ordinary coal fly ash except for the amount of cadmium and lead, the pozzolanic activity index and the compressive strength of fly ash concrete. Cadmium and lead were at average levels of 5.1 ppm and 102.6 ppm for the 5% RDF, and 7.8 ppm and 198.3 ppm for the 10% RDF, respectively. Although the pozzolanic activity index of coal-RDF fly ash increases over normal coal fly ash, preliminary results show that the 28-day compressive strength of concrete with direct replacement of cement and sand decreases by up to 30%. Leaching tests on crushed concrete were conducted to evaluate the environmental effect of acid rain.

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