scholarly journals Effect of Nanosilica Particle Size on the Water Permeability, Abrasion Resistance, Drying Shrinkage, and Repair Work Properties of Cement Mortar Containing Nano-SiO2

2017 ◽  
Vol 2017 ◽  
pp. 1-11 ◽  
Author(s):  
Sattawat Haruehansapong ◽  
Tawich Pulngern ◽  
Somchai Chucheepsakul

This work presents the effect of nanosilica particle sizes on durability properties and repair work properties of cement mortar containing nanosilica (NS). Three different NS particle sizes of 12, 20, and 40 nm were used and compared with those of cement mortar without NS and cement mortar with silica fume (SF). Interesting results were obtained in which the particle size of NS affected directly the abrasion resistance and water permeability. NS with particle size of 40 nm is the optimum size and gave the highest abrasion resistance and water permeability. For repair work properties, cement mortars containing NS (12 and 20 nm) and SF experienced higher drying shrinkage than that of cement mortar without NS and then presented cracking behavior and debonding between the cement mortars and concrete substrate. Cement mortar containing 40 nm of NS gave the lowest drying shrinkage, the lowest crack number, and the highest adhesive strength. These results indicate that the particle size of NS affected not only the durability properties but also the repair work properties of cement mortar.

2014 ◽  
Vol 629-630 ◽  
pp. 443-448 ◽  
Author(s):  
Hong Jian Du ◽  
Sze Dai Pang

s. The mechanical and durability properties of cement mortars with colloidal nanosilica (CNS) were investigated experimentally. Reference mortar with a low water-to-cement ratio of 0.30 was used in this study. The influence of CNS was evaluated by adding 0.5, 1.0, 1.5 and 2.0% of CNS by weight of cement. CNS was first stirred in the mixing water for 2 minutes before added to cement and sand. Superplasticizer was used to maintain the same flowability. Results showed that the compressive strength consistently increases with higher dosage of CNS at all the curing ages, due to both hydration acceleration and pozzolanic reaction. With the increase in CNS, the migration coefficient and water sorptivity consistently decreased; with 2% of CNS, the migration coefficient and water sorptivity were reduced by 45% and 30% respectively in comparison with the reference mortar. The improved durability could be explained by the reduction and refinement in the porosity, which can be attributed to nanofiller effect and pozzolanic reaction of nanosilica. Furthermore, the addition of CNS could reduce the drying shrinkage by densifying the microstructure in the cement paste, which has not been reported previously.


Materials ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 3465 ◽  
Author(s):  
Szymanowski ◽  
Sadowski

This article focuses on the development of nanoalumina-based cement mortars for overlay applications in concrete floors. It focuses on the effect of applying aluminum oxide (Al2O3) nanopowder to the cement mortar used to make the overlay, on the adhesion of this overlay to concrete substrate and on its functional properties. It was claimed that the addition of 0.5% of Al2O3 nanopowder has a positive effect on the adhesion of the cement mortar used to make the overlay to the substrate made of concrete. The prior studies performed using scanning electron microscopy (SEM) confirmed that the reason for the improvement in adhesion is the fact that cement mortar used to make the overlay with the addition of 0.5% of Al2O3 nanopowder is less porous than the reference mortar within the interphase. The article concurs that the most favorable results, in terms of lower abrasion resistance and higher subsurface tensile strength of the cement mortar used to make the overlay, are mainly brought about by adding 0.5% of Al2O3 nanopowder.


2013 ◽  
Vol 687 ◽  
pp. 311-315 ◽  
Author(s):  
Teresa María Piqué ◽  
Luis Fernandez Luco ◽  
Analía Vázquez

The development of new materials for specific applications is an increasing field in the construction industry, so is the employment of nanotechnology for this goal. When poly(vinyl alcohol) (PVA) is added to a Portland cement mortar, a film is formed in between the hydration products. This film has low elasticity modulus and high tensile strength and it enhances the mortar’s mechanical properties in the fresh and hardened states. The addition of nano montmorillonites (MMT) gives the polymer a better compatibility with the cement matrix. In this work, the changes in the microstructure of Portland cement mortars modified with PVA and PVA with MMT are assessed by means of transport of fluids capacity as an indicator. The reference is a standard mortar according to EN 196-1. The parameters measured are: weight loss under drying and air permeability. Complementary measures, such as compressive and flexural strengths and drying shrinkage have also been performed. From the obtained results, it can be concluded that the inclusion PVA + MMT to Portland cement mortar doesn’t affect the microstructure, when compared with Portland cement mortar with PVA, and even increase its tensile strength.


TAPPI Journal ◽  
2015 ◽  
Vol 14 (9) ◽  
pp. 565-576 ◽  
Author(s):  
YUCHENG PENG ◽  
DOUGLAS J. GARDNER

Understanding the surface properties of cellulose materials is important for proper commercial applications. The effect of particle size, particle morphology, and hydroxyl number on the surface energy of three microcrystalline cellulose (MCC) preparations and one nanofibrillated cellulose (NFC) preparation were investigated using inverse gas chromatography at column temperatures ranging from 30ºC to 60ºC. The mean particle sizes for the three MCC samples and the NFC sample were 120.1, 62.3, 13.9, and 9.3 μm. The corresponding dispersion components of surface energy at 30°C were 55.7 ± 0.1, 59.7 ± 1.3, 71.7 ± 1.0, and 57.4 ± 0.3 mJ/m2. MCC samples are agglomerates of small individual cellulose particles. The different particle sizes and morphologies of the three MCC samples resulted in various hydroxyl numbers, which in turn affected their dispersion component of surface energy. Cellulose samples exhibiting a higher hydroxyl number have a higher dispersion component of surface energy. The dispersion component of surface energy of all the cellulose samples decreased linearly with increasing temperature. MCC samples with larger agglomerates had a lower temperature coefficient of dispersion component of surface energy.


2020 ◽  
Vol 38 (10A) ◽  
pp. 1522-1530
Author(s):  
Rawnaq S. Mahdi ◽  
Aseel B. AL-Zubidi ◽  
Hassan N. Hashim

This work reports on the incorporation of Flint and Kaolin rocks powders in the cement mortar in an attempt to improve its mechanical properties and produce an eco-friendly mortar. Flint and Kaolin powders are prepared by dry mechanical milling. The two powders are added separately to the mortars substituting cement partially. The two powders are found to improve the mechanical properties of the mortars. Hardness and compressive strength are found to increase with the increase of powders constituents in the cement mortars. In addition, the two powders affect water absorption and thermal conductivity of the mortar specimens which are desirable for construction applications. Kaolin is found to have a greater effect on the mechanical properties, water absorption, and thermal conductivity of the mortars than Flint. This behavior is discussed and analyzed based on the compositional and structural properties of the rocks powders.


2018 ◽  
Vol 69 (8) ◽  
pp. 2040-2044
Author(s):  
Georgeta Velciu ◽  
Virgil Marinescu ◽  
Adriana Moanta ◽  
Ladislau Radermacher ◽  
Adriana Mariana Bors

The influence of fly ash adittion (90 % fraction [ 100 mm) on the cement mortar characteristics was studied. The XRD, XRF, SEM and FTIR determinations indicated that fly ash used has a hollow microstructure of microsphere and cenosphere whose total content in SiO2, Al2O3 and Fe2O3 is 88.63 % and that of CaO and MgO of 8.55 %. The mechanical, thermal and dielectric determinations made on mortar samples with content of fly ash in the 0-40 % range have highlighted fact that the mechanical strength of cement mortars is maximal at 20 %, the increase in fly ash content leads to a decrease in relative density and thermal conductivity as well as and to increased dielectric losses tgd.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
E. S. Prasedya ◽  
A. Frediansyah ◽  
N. W. R. Martyasari ◽  
B. K. Ilhami ◽  
A. S. Abidin ◽  
...  

AbstractSample particle size is an important parameter in the solid–liquid extraction system of natural products for obtaining their bioactive compounds. This study evaluates the effect of sample particle size on the phytochemical composition and antioxidant activity of brown macroalgae Sargassum cristaefolium. The crude ethanol extract was extracted from dried powders of S.cristeafolium with various particle sizes (> 4000 µm, > 250 µm, > 125 µm, > 45 µm, and < 45 µm). The ethanolic extracts of S.cristaefolium were analysed for Total Phenolic Content (TPC), Total Flavonoid Content (TFC), phenolic compound concentration and antioxidant activities. The extract yield and phytochemical composition were more abundant in smaller particle sizes. Furthermore, the TPC (14.19 ± 2.08 mg GAE/g extract to 43.27 ± 2.56 mg GAE/g extract) and TFC (9.6 ± 1.8 mg QE/g extract to 70.27 ± 3.59 mg QE/g extract) values also significantly increased as particle sizes decreased. In addition, phenolic compounds epicatechin (EC), epicatechin gallate (ECG), epigallocatechin (EGC), and Epigallocatechin gallate (EGCG) concentration were frequently increased in samples of smaller particle sizes based on two-way ANOVA and Tukey’s multiple comparison analysis. These results correlate with the significantly stronger antioxidant activity in samples with smaller particle sizes. The smallest particle size (< 45 µm) demonstrated the strongest antioxidant activity based on DPPH, ABTS, hydroxyl assay and FRAP. In addition, ramp function graph evaluates the desired particle size for maximum phytochemical composition and antioxidant activity is 44 µm. In conclusion, current results show the importance of particle size reduction of macroalgae samples to increase the effectivity of its biological activity.


Energies ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2303
Author(s):  
Congyu Zhong ◽  
Liwen Cao ◽  
Jishi Geng ◽  
Zhihao Jiang ◽  
Shuai Zhang

Because of its weak cementation and abundant pores and cracks, it is difficult to obtain suitable samples of tectonic coal to test its mechanical properties. Therefore, the research and development of coalbed methane drilling and mining technology are restricted. In this study, tectonic coal samples are remodeled with different particle sizes to test the mechanical parameters and loading resistivity. The research results show that the particle size and gradation of tectonic coal significantly impact its uniaxial compressive strength and elastic modulus and affect changes in resistivity. As the converted particle size increases, the uniaxial compressive strength and elastic modulus decrease first and then tend to remain unchanged. The strength of the single-particle gradation coal sample decreases from 0.867 to 0.433 MPa and the elastic modulus decreases from 59.28 to 41.63 MPa with increasing particle size. The change in resistivity of the coal sample increases with increasing particle size, and the degree of resistivity variation decreases during the coal sample failure stage. In composite-particle gradation, the proportion of fine particles in the tectonic coal sample increases from 33% to 80%. Its strength and elastic modulus increase from 0.996 to 1.31 MPa and 83.96 to 125.4 MPa, respectively, and the resistivity change degree decreases. The proportion of medium particles or coarse particles increases, and the sample strength, elastic modulus, and resistivity changes all decrease.


Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2136
Author(s):  
Shaokang Zhang ◽  
Ru Wang ◽  
Linglin Xu ◽  
Andreas Hecker ◽  
Horst-Michael Ludwig ◽  
...  

This paper studies the influence of hydroxyethyl methyl cellulose (HEMC) on the properties of calcium sulfoaluminate (CSA) cement mortar. In order to explore the applicability of different HEMCs in CSA cement mortars, HEMCs with higher and lower molar substitution (MS)/degree of substitution (DS) and polyacrylamide (PAAm) modification were used. At the same time, two kinds of CSA cements with different contents of ye’elimite were selected. Properties of cement mortar in fresh and hardened states were investigated, including the fluidity, consistency and water-retention rate of fresh mortar and the compressive strength, flexural strength, tensile bond strength and dry shrinkage rate of hardened mortar. The porosity and pore size distribution were also analyzed by mercury intrusion porosimetry (MIP). Results show that HEMCs improve the fresh state properties and tensile bond strength of both types of CSA cement mortars. However, the compressive strength of CSA cement mortars is greatly decreased by the addition of HEMCs, and the flexural strength is decreased slightly. The MIP measurement shows that HEMCs increase the amount of micron-level pores and the porosity. The HEMCs with different MS/DS have different effects on the improvement of tensile bond strength in different CSA cement mortars. PAAm modification can improve the tensile bond strength of HEMC-modified CSA cement mortar.


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