scholarly journals The Inhibition Effect of Sodium Glutarate towards Carbon Steel Corrosion in Neutral Aqueous Solutions

2016 ◽  
Vol 2016 ◽  
pp. 1-12
Author(s):  
G. Chan-Rosado ◽  
M. A. Pech-Canul
Keyword(s):  
Carbon Steel ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Inhibition Mechanism ◽  
Protective Film ◽  
Inhibition Effect ◽  
Low Concentrations ◽  
Defect Sites ◽  
Chemical Passivation ◽  
High Concentrations

The inhibition effect of sodium glutarate towards corrosion of carbon steel in neutral 0.02 M NaCl solution was investigated with potentiodynamic polarization and electrochemical impedance measurements. Results of electrochemical measurements revealed a poor inhibitive action for low concentrations (1 mM and 5 mM) and a significant improvement in efficiency for concentrations of 32 mM or higher. The protective film exhibited excellent stability in the temperature range 22°C–55°C. Full chemical passivation was accomplished and analysis of the impedance spectra for the high concentrations of glutarate was consistent with the inhibition mechanism which assumes that the carboxylates support the passivation of carbon steel in aerated solutions by plugging the defect sites and that the passivation process is enhanced by adsorption of the carboxylates on the oxide-covered surface. Such mechanism was confirmed by the XPS analysis.

Phenylcoumarin Glucoside as a Natural Inhibitor in the Protection of Low Carbon Steel Against Corrosion

MRS Advances ◽  
2017 ◽  
Vol 2 (62) ◽  
pp. 3909-3915
Author(s):  
Héctor M. Barbosa Cásarez ◽  
Araceli Espinoza Vázquez ◽  
Francisco J. Rodríguez-Gomez
Keyword(s):  
Carbon Steel ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Low Carbon Steel ◽  
Steel Corrosion ◽  
Low Carbon ◽  
Low Concentrations ◽  
Natural Inhibitor ◽  
Polarization Studies

AbstractPhenylcoumarin glucoside (4-PC) is a compound extracted from the plant Hintona latiflora and was studied as inhibitor for AISI 1018 steel corrosion in 3% NaCl solution using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques, which may find application as eco-friendly corrosion inhibitors. The 4-PC provides inhibitor properties that protect AISI 1018 low carbon steel against corrosion at low concentrations (5 ppm) obtained by EIS. Polarization studies showed that the inhibitor was of mixed type. The inhibition efficiency by the two electrochemical techniques shows similar results. The inhibitor adsorption was demonstrated to be a combined process (physisorption and chemisorption) according to the Langmuir isotherm.

Inhibitory Action of Persian Pyrifoliabark Extract against Corrosion of SAE 1020 Carbon Steel in Sodium Chloride Medium

2020 ◽  
Vol 1012 ◽  
pp. 390-394
Author(s):  
C. Vieira ◽  
D. Borges ◽  
D.C.S. Oliszeski ◽  
L.F.G. Larsson ◽  
E.P. Banczek
Keyword(s):  
Sodium Chloride ◽  
Carbon Steel ◽  
Electrochemical Impedance ◽  
Low Cost ◽  
Steel Corrosion ◽  
Industrial Applications ◽  
Protective Film ◽  
Chloride Medium ◽  
Simple Extraction ◽  
Extraction Processes

Carbon steel is one of the most commonly used alloys in industrial applications due to its physicochemical properties and low cost. However, the use of this metal material may become limited due to its vulnerability to corrosion. Thus, it is necessary to use methods that inhibit corrosion. Organic compounds with heteroatoms possess the characteristic of inhibiting corrosion by forming a protective film. The corrosion protection of SAE 1020 carbon steel, promoted by the aqueous extract of Persea pyrifolia (PP) bark, was evaluated in this work at extract concentrations of 5% and 10% v/v, in order to replace an inhibitor of synthetic origin with an ecologically benign inhibitor. Plant extracts are generally inexpensive and can be obtained through simple extraction processes. The objective of this work was to study the use of PP peel extract as a carbon steel corrosion inhibitor (SAE 1020). The electrochemical response was determined by measurements including electrochemical impedance spectroscopy (EIS) and anodic potentiodynamic polarization (PPA) in a 0.5 M sodium chloride medium. The samples were characterized by optical microscopy to evaluate the type of corrosion.

scholarly journals Corrosion Inhibition of Carbon Steel in 0.5 M H2SO4 by Phtalocyanine Blue

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
J. C. Valle-Quitana ◽  
G. F. Dominguez-Patiño ◽  
J. G. Gonzalez-Rodriguez
Keyword(s):  
Sulfuric Acid ◽  
Carbon Steel ◽  
Corrosion Inhibitor ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Corrosion Process ◽  
Blue Dye ◽  
Protective Film ◽  
Film Properties ◽  
Adsorption Desorption

Phthalocyanine blue dye has been investigated as a carbon steel corrosion inhibitor in 0.5 M sulfuric acid by using polarization curves, electrochemical impedance spectroscopy, and gravimetric tests. Dye concentrations included 0, 100, 200, 400, 600, 800, and 1000 ppm, whereas testing temperatures were 25, 40, and 60°C. Results indicated that phtalocyanine blue is a good corrosion inhibitor with its efficiency increasing with the concentration up to 40°C, but it increases at 60°C. Inhibitor improves the passive film properties and it forms an adherent, compact, protective film, acting, therefore, as an anodic-type inhibitor. At 25 and 40°C the corrosion process was under charge transfer, whereas at 60°C the adsorption/desorption of some species from the metal surface controlled the corrosion process.

Inhibition effect of phosphorus-based chemicals on corrosion of carbon steel in secondary-treated municipal wastewater

2013 ◽  
Vol 67 (11) ◽  
pp. 2412-2417 ◽  
Author(s):  
Zhanhui Shen ◽  
Hongqiang Ren ◽  
Ke Xu ◽  
Jinju Geng ◽  
Lili Ding
Keyword(s):  
Carbon Steel ◽  
Municipal Wastewater ◽  
Electrochemical Impedance ◽  
Cooling Water ◽  
Water Systems ◽  
Protective Film ◽  
Steel Electrode ◽  
Inhibition Effect ◽  
Treated Municipal Wastewater ◽  
Alternative Water

Secondary-treated municipal wastewater (MWW) could supply a viable alternative water resource for cooling water systems. Inorganic salts in the concentrated cooling water pose a great challenge to corrosion control chemicals. In this study, the inhibition effect of 1-hydroxy ethylidene-1,1-diphosphonic acid (HEDP), trimethylene phosphonic acid (ATMP) and 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) on corrosion of carbon steel in secondary-treated MWW was investigated by the means of potentiodynamic polarization and electrochemical impedance spectroscopy. The inhibition effect increased with increasing concentration of inhibitors. The corrosion rates of carbon steel were 1.5, 0.8, 0.2 and 0.5 mm a–1 for blank, HEDP, ATMP and PBTCA samples at 50 mg L–1, respectively. The phosphorus-based chemicals could adsorb onto the surface of the carbon steel electrode, form a coat of protective film and then protect the carbon steel from corrosion in the test solution.

scholarly journals Synthesis of ZnO-NPs Using a Convolvulus arvensis Leaf Extract and Proving Its Efficiency as an Inhibitor of Carbon Steel Corrosion

Materials ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 890
Author(s):  
Ghadah M. Al-Senani
Keyword(s):  
Carbon Steel ◽  
Steel Surface ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Protective Film ◽  
Convolvulus Arvensis ◽  
Zno Nps ◽  
Transfer Resistance ◽  
Carbon Steel Surface ◽  
Vis Spectroscopy

This paper studies the use of zinc oxide nanoparticles (ZnO-NPs) synthesized using an extract of Convolvulus arvensis leaf and expired ZnCl2, as efficient inhibitors of carbon steel corrosion in a 1 M HCl solution. The synthesized ZnO-NPs were characterized by Fourier-transform infrared (FTIR) and UV-Vis spectroscopy analysis. The corrosion inhibition of carbon steel in 1 M HCl was also investigated through potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and the determination of weight loss. The results show that the efficiency of the prevention increased when the concentration of ZnO-NPs was increased to 91%, and that the inhibition efficiency was still high (more than 89%) despite decreasing at high temperatures, acting as a mixed-type inhibitor. A sample of carbon steel with a protective layer of inhibitor on top was observed during immersion in 1 M HCl for 20 h; an increase in the charge transfer resistance (Rct) and stability of the inhibitor could be observed after 6 h. Adsorption isotherm models demonstrated that the inhibitor adsorption mechanism on the carbon steel surface followed Langmuir rather than Freundlich and Temkin behaviors. The thermodynamic parameters showed that the adsorption process is one of mixed, spontaneous, and exothermic adsorption. The results illustrate that the ZnO-NPs were a strong inhibitor of carbon steel corrosion in acid medium. The results of scanning electron microscopy (SEM) images showed that the ZnO-NPs formed a good protective film on the carbon steel surface.

scholarly journals Synthesis of ZnO-NPs Using Convolvulus Leaf Extract and Proving Its Efficiency as an Inhibitor for Carbon Steel Corrosion in 1M HCl

2020 ◽  
Author(s):  
Ghadah Al-Senani
Keyword(s):  
Carbon Steel ◽  
Steel Surface ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Isotherm Models ◽  
Protective Film ◽  
Zno Nps ◽  
Strong Inhibitor ◽  
Transfer Resistance ◽  
Carbon Steel Surface

This paper studies the use of zinc oxide nanoparticles (ZnO-NPs) synthesized using an extract of convolvulus leaves and expired ZnCl2, as an efficient inhibitor for carbon steel corrosion in 1M HCl solution. ZnO-NPs are characterized by Fourier-transform infrared spectrophotometer (FTIR) and UV–Vis analysis. The technique of weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) has also been used to investigate the prevention of carbon steel corrosion in 1M HCl. The results showed that the efficiency of restraint increased when the concentration of ZnO-NPs was raised to 91% and that the inhibition efficiency is still high despite its decrease at high temperature, and it acts as a mixed-type inhibitor A sample of carbon steel with the protective inhibitor layer on top was immersed for 20 hours and observed; an increase in the charge transfer resistance (Rct) and stability of the inhibitor was noticed after 6 hours. Adsorption isotherm models demonstrated that the inhibitor adsorption mechanism on the carbon steel surface followed Langmuir, more than Freundlich and Temkin, behavior. The thermodynamic parameters showed that the adsorption process is a mixed adsorption, spontaneous, and exothermic. The results illustrated that the acid medium was a strong inhibitor of carbon steel corrosion. Scanning electron microscope (SEM) showed that the ZnO-NPs formed a good protective film on the carbon steel surface.

Corrosion Inhibition of N,N- diethylammonium O,O′- di (p-chlorophenyl) dithiophosphate for Carbon Steel in HCL Solution

2013 ◽  
Vol 781-784 ◽  
pp. 299-303
Author(s):  
Shu Lan Cai ◽  
Kang Quan Qiao ◽  
Fa Mei Feng
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Carbon Steel ◽  
Corrosion Inhibition ◽  
Mixed Type ◽  
Electrochemical Impedance ◽  
Equivalent Circuit Model ◽  
Inhibition Effect ◽  
Inhibition Process ◽  
Hcl Solution ◽  
Mixed Type Inhibitor

A new corrosion inhibior N,N-diethylammonium O,O-di (p-chlorophenyl) dithiophosphate (EDPDP) has been synthesized and its inhibition effect towards the corrosion of carbon steel in 1.0 molL-1 HCl solution at 25 °C has been investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. The obtained results show that EDPDP is a excellent inhibitor and the inhibition efficiencies exceed 90 %. The polarization measurements reveal that EDPDP is a mixed type inhibitor and the equivalent circuit model of the corrosion inhibition process is obtained by the analysis of EIS data.

scholarly journals Practical and Theoretical Study on the Inhibitory Influences of New Azomethine Derivatives Containing an 8-Hydroxyquinoline Moiety for the Corrosion of Carbon Steel in 1 M HCl

2018 ◽  
Vol 34 (6) ◽  
pp. 3016-3029 ◽  
Author(s):  
A. El-Yaktini ◽  
A. Lachiri ◽  
M. El-Faydy ◽  
F. Benhiba ◽  
H. Zarrok ◽  
...  
Keyword(s):  
Carbon Steel ◽  
Density Functional ◽  
Electrochemical Impedance ◽  
Density Functional Theory Method ◽  
Steel Corrosion ◽  
Experimental Results ◽  
Chemical Parameters ◽  
Functional Theory ◽  
The Density Functional Theory ◽  
Inhibition Ability

The inhibition ability of a new Azomethine derivatives containing the 8-hydroxyquinoline (BDHQ and MDHQ) towards carbon steel corrosion in HCl solution was studied at various concentrations and temperatures using weight loss, polarization curves and electrochemical impedance spectroscopy (EIS) methods. The experimental results reveal that BDHQ and MDHQ are efficient mixed type corrosion inhibitors, and their inhibition efficiencies increase with increasing concentration. The adsorption of these inhibitors on mild steel surface obeys Langmuir isotherm. Quantum chemical parameters are calculated using the Density Functional Theory method (DFT) and Monte Carlo simulations. Correlation between theoretical and experimental results is discussed.

Corrosion inhibition of some azole derivatives on carbon steel in hydrochloric acid solution

2014 ◽  
Vol 61 (5) ◽  
pp. 300-306 ◽  
Author(s):  
B.P. Markhali ◽  
R. Naderi ◽  
M. Sayebani ◽  
M. Mahdavian
Keyword(s):  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Organic Compounds ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Acid Corrosion ◽  
Molecular Structures ◽  
Inhibition Mechanism ◽  
Content Type

Purpose – The purpose of this paper is investigate the inhibition efficiency of three similar bi-cyclic organic compounds, namely, benzimidazole (BI), benzotriazole (BTAH) and benzothiazole (BTH) on carbon steel in 1 M hydrochloric acid (HCl) solution. Organic inhibitors are widely used to protect metals in acidic media. Among abundant suggestions for acid corrosion inhibitors, azole compounds have gained attention. Design/methodology/approach – The inhibition efficiency of the three organic compounds was investigated using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Findings – Superiorities of BTH and BTAH corrosion inhibitors were shown by EIS data and polarization curves. Moreover, the results revealed that BTAH and BTH can function as effective mixed-type adsorptive inhibitors, whereas no inhibition behavior was observed for BI. Both BTAH and BTH obeyed Longmuir adsorption isotherm. The results obtained from this isotherm showed that both inhibitors adsorbed on the specimen surface physically and chemically. The difference in inhibition efficiencies of BTAH, BTH and BI was related to the presence of nitrogen and sulfur hetero atoms on their molecular structures. Originality/value – This study evaluated inhibition efficiency of BI, BTAH and BTH using electrochemical methods. In addition, the study attempted to find inhibition mechanism of the inhibitors and to find modes of adsorption of the inhibitors, correlating effects of heteroatoms and inhibition efficiency.

scholarly journals Electrochemically Synthesized Poly(2-Aminobenzenesulphonic Acid) – An Efficient Protection for Carbon Steel Corrosion

2019 ◽  
Vol 35 (2) ◽  
pp. 678-683
Author(s):  
Sini Varghese Cheruvathur ◽  
Joby Thomas Kakkassery ◽  
Vinod Raphael Palayoor ◽  
Binsi M. Paulson ◽  
Ragi Kooliyat
Keyword(s):  
Carbon Steel ◽  
Steel Surface ◽  
Electrochemical Impedance ◽  
Steel Corrosion ◽  
Polymeric Coating ◽  
Spectral Studies ◽  
Protection Efficacy ◽  
Efficient Protection ◽  
Ft Ir ◽  
Hcl Medium

The corrosion protection efficacy of electrochemically synthesized poly(2-aminobenzenesulphonic acid) (P2ABSA) on carbon steel in 1.0 M HCl was investigated by electrochemical impedance spectroscopy, Tafel polarisation, scanning electron microscopy (SEM) and FT-IR spectral studies. The polymeric coating was prepared on the steel surface using cyclic voltammetry. Investigations established that P2ABSA effectively prevent the metal dissolution in HCl medium. Polarisation studies revealed that this polymer hinder both anodic and cathodic process of corrosion appreciably. The structures of the chemically and electrochemically synthesised polymers were compared using IR spectroscopy. Morphology of the steel surface confirmed the intact response of P2ABSA on steel surface treated with HCl.

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