scholarly journals Morphological and Optical Characterization of High Density Au/PAA Nanoarrays

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Mohamed Shaban

Hexagonal nanoarrays of Au nanorods and nanopillar were deposited on nanoporous anodic alumina (PAA) membranes utilizing dc electrodeposition. The surface morphologies and optical properties were characterized by using field emission-scanning electron microscopy (FE-SEM) and UV-Vis spectrophotometer, respectively. The optical reflectance spectra of the as-prepared, pore widened, and 2D-Au nanorods-coated PAA membranes were studied in detail. The effects of the angle of incident, pore widening time, and electrodeposition time on the characteristic peaks positions and intensities of the fabricated nanoarrays were addressed. As the angle of incident increased, the interference peaks and transverse surface resonance are shifted to longer wavelengths, but the longitudinal surface plasmon resonance is shifted to shorter wavelengths. Also, the reflected intensities are decreased linearly for the as-prepared sample and decreased exponentially for Au/PAA samples. Using the modified Kubelka-Munk radiative transfer model, the energy gap is increased from 2.83 to 3.06 eV and the refractive index is decreased from 1.84 to 1.36 for the as-prepared and 70 min pore widened PAA membranes, respectively. Based on the advantages of the fabrication approach and the enhanced and controlled properties, this generation of Au/PAA arrays can be used as efficient building blocks for nanoelectronics and nanophotonic devices.

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Mohamed Shaban

Hexagonal nanoarrays of Au particles were deposited on nanoporous anodic alumina membrane (NAAM) utilizing r.f. magnetron sputtering. The thickness of the NAAMs is adjusted by changing the second anodization time from 5 min to 20 min. The surface morphology, composition, and optical properties are characterized by using SEM, EDX, and spectrophotometer, respectively. The effects of the NAAM thickness and state of polarization on the morphological changes and on the optical properties of the fabricated nanoarrays were addressed. According to the measured optical spectra, the rate of decrease of NAAMs refractive index was found to be 3.825 × 10−4 nm−1. Using the modified Kubelka-Munk radiative transfer model, the energy gap of NAAMs was calculated from diffused reflectance and was decreased from 1.682 to 1.376 as the anodization time increased from 5 to 20 min. Also, the saturation of interference fringes is substantially enhanced, and field enhancement can be achieved due to the excitation and constructive interference of surface plasmon waves by coating NAAMs with the hexagonal nanoarrays of Au. Based on the advantages of the fabrication approach and the enhanced and controlled properties, this new generation of samples can be used as promising building blocks for nanophotonic and nanoelectronics devices.


2012 ◽  
Vol 33 (6) ◽  
pp. 1611-1624 ◽  
Author(s):  
Iñigo Mendikoa ◽  
Santiago Pérez-Hoyos ◽  
Agustín Sánchez-Lavega

2021 ◽  
Vol 13 (2) ◽  
pp. 270
Author(s):  
Adrian Doicu ◽  
Dmitry S. Efremenko ◽  
Thomas Trautmann

An algorithm for the retrieval of total column amount of trace gases in a multi-dimensional atmosphere is designed. The algorithm uses (i) certain differential radiance models with internal and external closures as inversion models, (ii) the iteratively regularized Gauss–Newton method as a regularization tool, and (iii) the spherical harmonics discrete ordinate method (SHDOM) as linearized radiative transfer model. For efficiency reasons, SHDOM is equipped with a spectral acceleration approach that combines the correlated k-distribution method with the principal component analysis. The algorithm is used to retrieve the total column amount of nitrogen for two- and three-dimensional cloudy scenes. Although for three-dimensional geometries, the computational time is high, the main concepts of the algorithm are correct and the retrieval results are accurate.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Rehman S. Eon ◽  
Charles M. Bachmann

AbstractThe advent of remote sensing from unmanned aerial systems (UAS) has opened the door to more affordable and effective methods of imaging and mapping of surface geophysical properties with many important applications in areas such as coastal zone management, ecology, agriculture, and defense. We describe a study to validate and improve soil moisture content retrieval and mapping from hyperspectral imagery collected by a UAS system. Our approach uses a recently developed model known as the multilayer radiative transfer model of soil reflectance (MARMIT). MARMIT partitions contributions due to water and the sediment surface into equivalent but separate layers and describes these layers using an equivalent slab model formalism. The model water layer thickness along with the fraction of wet surface become parameters that must be optimized in a calibration step, with extinction due to water absorption being applied in the model based on equivalent water layer thickness, while transmission and reflection coefficients follow the Fresnel formalism. In this work, we evaluate the model in both field settings, using UAS hyperspectral imagery, and laboratory settings, using hyperspectral spectra obtained with a goniometer. Sediment samples obtained from four different field sites representing disparate environmental settings comprised the laboratory analysis while field validation used hyperspectral UAS imagery and coordinated ground truth obtained on a barrier island shore during field campaigns in 2018 and 2019. Analysis of the most significant wavelengths for retrieval indicate a number of different wavelengths in the short-wave infra-red (SWIR) that provide accurate fits to measured soil moisture content in the laboratory with normalized root mean square error (NRMSE)< 0.145, while independent evaluation from sequestered test data from the hyperspectral UAS imagery obtained during the field campaign obtained an average NRMSE = 0.169 and median NRMSE = 0.152 in a bootstrap analysis.


2020 ◽  
Vol 13 (1) ◽  
pp. 116
Author(s):  
Lucie Leonarski ◽  
Laurent C.-Labonnote ◽  
Mathieu Compiègne ◽  
Jérôme Vidot ◽  
Anthony J. Baran ◽  
...  

The present study aims to quantify the potential of hyperspectral thermal infrared sounders such as the Infrared Atmospheric Sounding Interferometer (IASI) and the future IASI next generation (IASI-NG) for retrieving the ice cloud layer altitude and thickness together with the ice water path. We employed the radiative transfer model Radiative Transfer for TOVS (RTTOV) to simulate cloudy radiances using parameterized ice cloud optical properties. The radiances have been computed from an ice cloud profile database coming from global operational short-range forecasts at the European Center for Medium-range Weather Forecasts (ECMWF) which encloses the normal conditions, typical variability, and extremes of the atmospheric properties over one year (Eresmaa and McNally (2014)). We performed an information content analysis based on Shannon’s formalism to determine the amount and spectral distribution of the information about ice cloud properties. Based on this analysis, a retrieval algorithm has been developed and tested on the profile database. We considered the signal-to-noise ratio of each specific instrument and the non-retrieved atmospheric and surface parameter errors. This study brings evidence that the observing system provides information on the ice water path (IWP) as well as on the layer altitude and thickness with a convergence rate up to 95% and expected errors that decrease with cloud opacity until the signal saturation is reached (satisfying retrievals are achieved for clouds whose IWP is between about 1 and 300 g/m2).


2021 ◽  
Vol 13 (3) ◽  
pp. 434
Author(s):  
Ana del Águila ◽  
Dmitry S. Efremenko

Fast radiative transfer models (RTMs) are required to process a great amount of satellite-based atmospheric composition data. Specifically designed acceleration techniques can be incorporated in RTMs to simulate the reflected radiances with a fine spectral resolution, avoiding time-consuming computations on a fine resolution grid. In particular, in the cluster low-streams regression (CLSR) method, the computations on a fine resolution grid are performed by using the fast two-stream RTM, and then the spectra are corrected by using regression models between the two-stream and multi-stream RTMs. The performance enhancement due to such a scheme can be of about two orders of magnitude. In this paper, we consider a modification of the CLSR method (which is referred to as the double CLSR method), in which the single-scattering approximation is used for the computations on a fine resolution grid, while the two-stream spectra are computed by using the regression model between the two-stream RTM and the single-scattering approximation. Once the two-stream spectra are known, the CLSR method is applied the second time to restore the multi-stream spectra. Through a numerical analysis, it is shown that the double CLSR method yields an acceleration factor of about three orders of magnitude as compared to the reference multi-stream fine-resolution computations. The error of such an approach is below 0.05%. In addition, it is analysed how the CLSR method can be adopted for efficient computations for atmospheric scenarios containing aerosols. In particular, it is discussed how the precomputed data for clear sky conditions can be reused for computing the aerosol spectra in the framework of the CLSR method. The simulations are performed for the Hartley–Huggins, O2 A-, water vapour and CO2 weak absorption bands and five aerosol models from the optical properties of aerosols and clouds (OPAC) database.


Author(s):  
Rukeya Sawut ◽  
Ying Li ◽  
Yu Liu ◽  
Nijat Kasim ◽  
Umut Hasan ◽  
...  

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