scholarly journals Competitive Adsorption of Cadmium(II) and Mercury(II) Ions from Aqueous Solutions by Activated Carbon from Xanthoceras sorbifolia Bunge Hull

2016 ◽  
Vol 2016 ◽  
pp. 1-10 ◽  
Author(s):  
Xiaotao Zhang ◽  
Yinan Hao ◽  
Ximing Wang ◽  
Zhangjing Chen ◽  
Chun Li
Keyword(s):  
Activated Carbon ◽  
High Efficiency ◽  
Metal Removal ◽  
Chemical Interaction ◽  
Low Cost ◽  
Heavy Metal Removal ◽  
Metal System ◽  
Experimental Conditions ◽  
Equilibrium Data ◽  
Adsorption Equilibrium Data

This paper presents low-cost and recyclable activated carbon (XLAC) derived from Xanthoceras sorbifolia Bunge hull for high-efficiency adsorption of Cd(II) and Hg(II) ions in industrial wastewater. XLAC was prepared through H3PO4 activation and was characterized using N2 adsorption-desorption, scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDX), and Fourier transform infrared (FTIR) spectroscopy. In single-metal-system adsorption experiments, the maximum adsorption capacities for Cd(II) and Hg(II) obtained under different experimental conditions were 388.7 and 235.6 mg·g−1, respectively. All adsorption equilibrium data fit perfectly with the Langmuir isotherm model. In a binary metal system, competitive studies demonstrated that the presence of Cd(II) significantly decreased the adsorption of Hg(II), but the adsorption of Cd(II) showed a little change in the presence of Hg(II). In addition, XLAC can be regenerated with a 0.01 mol·L−1 HNO3 solution and reused at least four times. The FTIR spectra revealed that a chemical interaction occurs between functional groups containing lone electron pairs in XLAC and metal ions. Overall, these results suggest that XLAC may be suitable as an adsorbent for heavy metal removal from wastewater streams.

Effective Removal of Lead from Solution by Sulfate Reducing Bacteria Cultured with Sugar Byproducts

2020 ◽  
Vol 14 (3) ◽  
pp. 384-395
Author(s):  
Juan Yin ◽  
Chao-Bing Deng ◽  
Hongxiang Zhu ◽  
Jianhua Xiong ◽  
Zhuo Sun
Keyword(s):  
High Efficiency ◽  
Metal Removal ◽  
Low Cost ◽  
Heavy Metal Removal ◽  
Carbon Sources ◽  
Sulfate Reducing Bacteria ◽  
Lead Removal ◽  
Sulfate Reducing ◽  
Reducing Bacteria ◽  
Filter Mud

Sulfate reducing bacteria (SRB) are widely used to remove heavy metals because of their high efficiency. However, the metabolic processes of SRB require additional carbon sources, and the development of low-cost carbon sources has gradually attracted attention. The utilization of sugar byproduct resources, as the low-cost carbon sources, has great practical significance for environmentally sustainable development in Guangxi, China. This study aims to cultivate SRB with low-cost sugar byproducts, apply them to controlling a lead-polluted environment, and study the effects and mechanisms of controlling lead pollution. The research results show that the best culture effect of SBR can be obtained by mixing the filter mud and vinasse in a ratio of 1:1 to 3:1. SRB have average lead removal rates of more than 96.97% in solutions with different lead concentration of 10∼100 mg/L, and SRB have a higher tolerance to high concentrations of lead due to factors such as the organic substance composition of sugar byproducts and the porosity of filter mud. Scanning electron microscopy combined with energy dispersive spectrometry and X-ray diffraction analysis show that SRB mainly cause Pb2+ to form PbS precipitate through redox reactions to remove lead from the solution. Therefore, low-cost filters of a mud and vinasse mixture can be used as a medium for SRB and exhibit high heavy metal removal efficiency, thus providing a new utilization of filter mud and vinasse.

Removal of Pb(II) by adsorption onto Chinese walnut shell activated carbon

2015 ◽  
Vol 72 (6) ◽  
pp. 983-989 ◽  
Author(s):  
Zheng-ji Yi ◽  
Jun Yao ◽  
Yun-fei Kuang ◽  
Hui-lun Chen ◽  
Fei Wang ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Metal Removal ◽  
Heavy Metal Removal ◽  
Walnut Shell ◽  
Maximum Adsorption Capacity ◽  
Equilibrium Data ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order ◽  
Chinese Walnut ◽  
Maximum Removal

The excessive discharge of Pb(II) into the environment has increasingly aroused great concern. Adsorption is considered as the most effective method for heavy metal removal. Chinese walnut shell activated carbon (CWSAC) was used as an adsorbent for the removal of Pb(II) from aqueous solution. Batch experiments were conducted by varying contact time, temperature, pH, adsorbent dose and initial Pb(II) concentration. Adsorption equilibrium was established within 150 min. Although temperature effect was insignificant, the Pb(II) adsorption was strongly pH dependent and the maximum removal was observed at pH 5.5. The Pb(II) removal efficiency increased with increasing CWSAC dosage up to 2.0 g/L and reached a maximum of 94.12%. Langmuir and Freundlich adsorption isotherms were employed to fit the adsorption data. The results suggested that the equilibrium data could be well described by the Langmuir isotherm model, with a maximum adsorption capacity of 81.96 mg/g. Adsorption kinetics data were fitted by pseudo-first- and pseudo-second-order models. The result indicated that the pseudo-first-order model best describes the adsorption kinetic data. In summary, CWSAC could be a promising material for the removal of Pb(II) from wastewater.

Effect of Particle Size on Cadmium Removal by Banana Peels

2015 ◽  
Vol 72 (4) ◽  
Author(s):  
Mohd Ismid Mohd Said ◽  
Shaikhah Sabri ◽  
Shamila Azman
Keyword(s):  
Particle Size ◽  
Metal Removal ◽  
Low Cost ◽  
Polluted Water ◽  
Banana Peel ◽  
Cadmium Removal ◽  
Musa Balbisiana ◽  
Equilibrium Data ◽  
Langmuir Isotherm Model ◽  
Adsorption Equilibrium Data

Contamination of metals in aquatic environment is a worldwide problem because of its toxicity and capability to accumulate in biological chain, as well as persistence in the natural environment. Therefore various expensive technologies have been applied to treat metal-polluted water. In Malaysia there are abundance of banana species available which could provide cheap, low cost and environmental friendly bio-materials. Preliminary study was conducted on two species of banana i.e. Musa balbisiana (Nipah) and Musa acuminata (Kapas). The banana peels were washed, dried and grounded into various range of particle sizes (0.20–1.18 mm). The ability of the adsorbents were determined by agitation of 1.0 g banana peel and 100 ml of cadmium standard solution at the concentration of 100 mg/L. Musa balbisiana showed the highest removal of cadmium at 89.58% from the initial concentration compared to Musa acuminate with the particle size of 0.30-0.60 mm. Adsorption equilibrium data are well described by Langmuir isotherm model. The result also shows that different species have different capabilities to adsorb metal. Hence, their potential as bio-adsorbent could be further be examined for metal removal from wastewater.

scholarly journals A Review on Promising Membrane Technology Approaches for Heavy Metal Removal from Water and Wastewater to Solve Water Crisis

Water ◽  
2021 ◽  
Vol 13 (22) ◽  
pp. 3241
Author(s):  
Mervette El Batouti ◽  
Nouf F. Al-Harby ◽  
Mahmoud M. Elewa
Keyword(s):  
Heavy Metal ◽  
Wastewater Treatment ◽  
High Efficiency ◽  
Metal Removal ◽  
Low Cost ◽  
Heavy Metal Removal ◽  
Membrane Technology ◽  
Treated Wastewater ◽  
Treatment Techniques ◽  
Water And Wastewater

Due to the impacts of water scarcity, the world is looking at all possible solutions for decreasing the over-exploitation of finite freshwater resources. Wastewater is one of the most reliable and accessible water supplies. As the population expands, so do industrial, agricultural, and household operations in order to meet man’s enormous demands. These operations generate huge amounts of wastewater, which may be recovered and used for a variety of reasons. Conventional wastewater treatment techniques have had some success in treating effluents for discharge throughout the years. However, advances in wastewater treatment techniques are required to make treated wastewater suitable for industrial, agricultural, and household use. Diverse techniques for removing heavy metal ions from various water and wastewater sources have been described. These treatments can be categorized as adsorption, membrane, chemical, or electric. Membrane technology has been developed as a popular alternative for recovering and reusing water from various water and wastewater sources. This study integrates useful membrane technology techniques for water and wastewater treatment containing heavy metals, with the objective of establishing a low-cost, high-efficiency method as well as ideal production conditions: low-cost, high-efficiency selective membranes, and maximum flexibility and selectivity. Future studies should concentrate on eco-friendly, cost-effective, and long-term materials and procedures.

Mechanisms of heavy metal removal using microorganisms as biosorbent

2013 ◽  
Vol 69 (9) ◽  
pp. 1775-1787 ◽  
Author(s):  
Vahid Javanbakht ◽  
Seyed Amir Alavi ◽  
Hamid Zilouei
Keyword(s):  
Heavy Metals ◽  
Functional Groups ◽  
Metal Binding ◽  
High Efficiency ◽  
Metal Removal ◽  
Physical Adsorption ◽  
Low Cost ◽  
Heavy Metal Removal ◽  
Functional Sites ◽  
Biosorption Process

Release and distribution of heavy metals through industrial wastewaters has adverse affects on the environment via contamination of surface- and ground-water resources. Biosorption of heavy metals from aqueous solutions has been proved to be very promising, offering significant advantages such as low cost, availability, profitability, ease of operation, and high efficiency, especially when dealing with low concentrations. Residual biomasses of industrial microorganisms including bacteria, algae, fungi, and yeast have been found to be capable of efficiently accumulating heavy metals as biosorbent. This paper presents and investigates major mechanisms of biosorption and most of the functional groups involved. The biosorption process includes the following mechanisms: transport across cell membrane, complexation, ion exchange, precipitation, and physical adsorption. In order to understand how metals bind to the biomass, it is essential to identify the functional groups responsible for metal binding. Most of these groups have been characterized on the cell walls. The biosorbent contains a variety of functional sites including carboxyl, imidazole, sulfydryl, amino, phosphate, sulfate, thioether, phenol, carbonyl, amide, and hydroxyl moieties that are responsible for metal adsorption. These could be helpful to improve biosorbents through modification of surface reactive sites via surface grafting and/or exchange of functional groups.

Biochar as a Low-Cost Adsorbent for Aqueous Heavy Metal Removal: A Review

2021 ◽  
pp. 105081
Author(s):  
Bingbing Qiu ◽  
Xuedong Tao ◽  
Hao Wang ◽  
Wenke Li ◽  
Xiang Ding ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Metal Removal ◽  
Low Cost ◽  
Heavy Metal Removal

scholarly journals Adsorption of Hexavalent Chromium and Divalent Lead Ions on the Nitrogen-Enriched Chitosan-Based Activated Carbon

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1907
Author(s):  
Fatma Hussain Emamy ◽  
Ali Bumajdad ◽  
Jerzy P. Lukaszewicz
Keyword(s):  
Heavy Metal ◽  
Activated Carbon ◽  
Metal Ions ◽  
Metal Removal ◽  
High Surface ◽  
Heavy Metal Removal ◽  
High Surface Area ◽  
Kinetics Of Adsorption ◽  
Removal Of Heavy Metals ◽  
Pseudo Second Order

Optimizing the physicochemical properties of the chitosan-based activated carbon (Ch-ACs) can greatly enhance its performance toward heavy metal removal from contaminated water. Herein, Ch was converted into a high surface area (1556 m2/g) and porous (0.69 cm3/g) ACs with large content of nitrogen (~16 wt%) using K2CO3 activator and urea as nitrogen-enrichment agents. The prepared Ch-ACs were tested for the removal of Cr(VI) and Pb(II) at different pH, initial metal ions concentration, time, activated carbon dosage, and temperature. For Cr(VI), the best removal was at pH = 2, while for Pb(II) the best pH for its removal was in the range of 4–6. At 25 °C, the Temkin model gives the best fit for the adsorption of Cr(VI), while the Langmuir model was found to be better for Pb(II) ions. The kinetics of adsorption of both heavy metal ions were found to be well-fitted by a pseudo-second-order model. The findings show that the efficiency and the green properties (availability, recyclability, and cost effectiveness) of the developed adsorbent made it a good candidate for wastewaters treatment. As preliminary work, the prepared sorbent was also tested regarding the removal of heavy metals and other contaminations from real wastewater and the obtained results were found to be promising.

Heavy Metal Removal by Oil Palm Empty Fruit Bunches (OPEFB) Biosorbent

2014 ◽  
Vol 625 ◽  
pp. 889-892 ◽  
Author(s):  
Safoura Daneshfozoun ◽  
Bawadi Abdullah ◽  
Mohd Azmuddin Abdullah
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Metal Removal ◽  
Low Cost ◽  
Ph Dependence ◽  
Heavy Metal Removal ◽  
Absorption Spectrometry ◽  
Adsorption Efficiency ◽  
Empty Fruit Bunches ◽  
Initial Ph

This study developed an effective and economical physical pretreatment of OPEFB to be used as biosorbent for the removal of heavy metal ions such as Cu+2, Zn+2and Pb2+. The effects of fibres sizes, metal ions concentration (100-1000 ppm), initial pH (4-10) and contact time (20-150 min) were investigated in batch system. Samples were characterized with Atomic Absorption Spectrometry (AAS), Transmission Electron Microscopy (TEM) and Fourier Transmission Infra-red Spectroscopy (FTIR). Results showed pH-dependence adsorption efficiency and increased adsorption with initial metal concentrations where more than 92% adsorption efficiency achieved. We have successfully developed an eco-friendly, low cost adsorbent without any chemical modification or excessive energy disposal.

Application of Immobilized Fungi Phanerochaete chrysosporium in Removal of Heavy-Metals from Wastewater

2013 ◽  
Vol 779-780 ◽  
pp. 1674-1677 ◽  
Author(s):  
Dan Lian Huang ◽  
Guang Ming Zeng ◽  
Piao Xu ◽  
Cui Lai ◽  
Mei Hua Zhao ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Iron Oxide ◽  
Magnetic Nanoparticles ◽  
Phanerochaete Chrysosporium ◽  
High Efficiency ◽  
Metal Removal ◽  
Heavy Metal Removal ◽  
Removal Of Heavy Metals ◽  
Iron Oxide Magnetic Nanoparticles ◽  
Ca Alginate

Immobilized microbe technologies are expected to be effectively used in wastewater treatment. Removal of heavy-metals from wastewater by immobilized Phanerochaete chrysosporium (Pc) with Ca-alginate and iron oxide magnetic nanoparticles (MNPs) was studied. The results showed that a biosorbent as Pc immobilized by Ca-alginate and iron oxide magnetic nanoparticles was successfully developed. And the iron oxide magnetic nanoparticles played an important role in the increase of biosorption capacity of Pc. Energy dispersive spectrometer (EDS) analysis confirmed that metal ions adsorbed to the surface of the biosorbents were partly transmitted to the interior of biosorbents, mainly embedded with iron oxide nanoparticles and Ca-alginate. Moreover, it was found that MNPs-Ca-alginate immobilized Pc showed a good affinity to various heavy metals, such as Pb(II), Zn(II), Cd(II) or Mg(II) and so on. The results proved the high efficiency of the biosorbents for heavy-metal removal and its potential application in the treatment of metal-containing wastewater.

scholarly journals Removal of Orange G Dye from Aqueous Solution by Adsorption: A Short Review

2020 ◽  
Vol 9 (1) ◽  
pp. 318-327
Keyword(s):  
Aqueous Solution ◽  
Activated Carbon ◽  
Low Cost ◽  
Short Review ◽  
Industrial Wastes ◽  
Present Review ◽  
Wastewater Remediation ◽  
Experimental Conditions ◽  
Adsorption Capacities ◽  
Orange G

Adsorption is a widely used technique for wastewater remediation. The process is effective and economical for the removal of various pollutants from wastewater, including dyes. Moreover, Besides commercial activated carbon, different low-cost materials such as agricultural and industrial wastes are now used as adsorbents. The present review focused on the removal of a teratogenic and carcinogenic dye, orange G (OG) via adsorption using several adsorbents, together with the experimental conditions and their adsorption capacities. Based on the information compiled, various adsorbents have shown promising potential for OG removal.

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