scholarly journals Stability of Fluorosurfactant Adsorption on Mineral Surface for Water Removal in Tight Gas Reservoirs

2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Lijun You ◽  
Wanchun Zhang ◽  
Yili Kang ◽  
Zhangxin Chen ◽  
Xuefen Liu
Keyword(s):  
Photoelectron Spectroscopy ◽  
Single Layer ◽  
Sample Surface ◽  
Gas Production ◽  
Wettability Alteration ◽  
Water Removal ◽  
Pore Surface ◽  
Mineral Surface ◽  
Gas Reservoirs ◽  
Rock Mineral

Long-term effectiveness of rock wettability alteration for water removal during gas production from tight reservoir depends on the surfactant adsorption on the pore surface of a reservoir. This paper selected typical cationic fluorosurfactant FW-134 as an example and took advantage of Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and atomic force microscope (AFM) to investigate its adsorption stability on the rock mineral surface under the oscillation condition at high temperature for a long time. The experimental results indicate that the F element content on the sample surface increases obviously, the surface structure of fluorine-carbonization also undergoes a significant change, and the fluorine surfactant exhibits a good interfacial modification and wettability alteration ability due to its adsorption on the pore surface transforming the chemical structure of the original surface. The adsorption increases indistinctly with the concentration of over 0.05% due to a single layer adsorption structure and is mainly electrostatic adsorption because the chemical bonding between the fluorosurfactant and the rock mineral surface, the hydrogen bonding, is weak and inconspicuous.

Mitigation of Gas Condensate Banking Using an Integrated Chemical Approach

2021 ◽  
Author(s):  
Amjed Mohammed Hassan ◽  
Mohamed Ahmed Mahmoud ◽  
Ayman Raja Al-Nakhli
Keyword(s):  
Zeta Potential ◽  
Hydraulic Fracturing ◽  
Thermochemical Treatment ◽  
Chelating Agent ◽  
Integrated Approach ◽  
Gas Production ◽  
Wettability Alteration ◽  
Gas Reservoirs ◽  
Multiple Fractures ◽  
Well Production

Abstract In gas reservoirs, the well production can be reduced due to the development and accumulation of condensate in the near-wellbore zone. Various techniques are used to minimize the condensate damage and maintain hydrocarbon production. Hydraulic fracturing and wettability alteration techniques are the most effective methods. However, these techniques are expensive, especially in deep gas reservoirs. This paper introduces a new approach for mitigating condensate accumulation by integrating the hydraulic fracturing and wettability alteration treatments. The efficiency of two chemicals that can generate multiple fractures and alter the fracture surfaces to less condensate status is investigated in this work. Thermochemical fluids and chelating agent solutions are used to mitigate the condensate damage and improve gas production for the long term. Several laboratory measurements were carried out to study the performance of the proposed approach; coreflooding, zeta potential, and nuclear magnetic resonance (NMR) experiments were conducted. The chemicals were injected into the tight rocks to recover the condensate and improve the flow conductivity. Zeta potential was performed to assess the rock wettability before and after the chemical injection. Moreover, the changes in pores network due to the chemical treatments as analyzed using the NMR technique. Thermochemical treatment removed around 66% of the condensate liquid, while the chelating agent reduced the condensate saturation by around 80%. The main mechanism for condensate removal during thermochemical flooding is the generation of micro-fractures that increase the rock permeability and improve the condensate flow. On the other hand, chelating agents can alter the rock wettability toward less oil-state, leading to considerable recovery of the condensate liquid utilizing a wettability alteration mechanism. Finally, an integrated approach is suggested to injecting thermochemical fluids followed by chelating agent solutions. The proposed technique can lead to generating micro-fractures of less oil-wet surfaces, consequently, the condensate bank can be removed by more than 90%.

Preventive Treatment for Enhancing Water Removal from Gas Reservoirs by Wettability Alteration

2007 ◽  
Author(s):  
Mohan K.R. Panga ◽  
Suzylawati Ismail ◽  
Pascal Cheneviere ◽  
Mathew Samuel
Keyword(s):  
Preventive Treatment ◽  
Wettability Alteration ◽  
Water Removal ◽  
Gas Reservoirs

scholarly journals Performance Evaluation and Mechanism Study of a Silicone Hydrophobic Polymer for Improving Gas Reservoir Permeability

2020 ◽  
Author(s):  
Jie Zhang ◽  
Xu-Yang Yao ◽  
Bao-Jun Bai ◽  
Wang Ren
Keyword(s):  
Surface Tension ◽  
Water Saturation ◽  
Gas Production ◽  
Spontaneous Imbibition ◽  
Wettability Alteration ◽  
Mechanism Study ◽  
Gas Reservoirs ◽  
Tension Reduction ◽  
Surface Tension Reduction ◽  
Reservoir Permeability

The permeability of tight gas reservoirs is usually lower than 1 md. When the external fluids from drilling and completion processes invade such reservoirs, formation damage occurs and causes serious damage to oil and gas production. Fluorocarbon surfactants are most often recommended for removing such damage because they have extremely low surface tension, which means that they can change the reservoir wettability from water wet to gas or oil wet. However, they are not normally applied in the field because they are not cost-effective. Besides, some environmental concerns also restrict their application. In this work, we studied the effects of an oligomeric organosilicon surfactant (OSSF) on wettability modification, surface tension reduction, invasion of different fluids, and fluid flow back. It was found that the amount of spontaneous imbibition and remaining water could be reduced by the surfactant as a result of surface tension reduction and wettability alteration. Compared to the distilled water, the concentration of 0.20 wt% OSSF could decrease water saturation of cores by about 4%. At a flow-back pressure of 0.06 and 0.03 MPa after 20 PV displacement, permeability recovery could increase from 8 to 7–93% and 86%, respectively. We also found that the mechanism of OSSF includes the physical obstruction effect, surface tension reduction of external fluids, and wettability alteration of the reservoir generated. Meanwhile, quantum chemical calculations indicated that adsorbent layer of polydimethylsiloxane could decrease the affinity and adhesion of CH4 and H2O on the pore surface.

The Method of Dynamic Reserves Prediction for a Constant Volume Gas Reservoir

2013 ◽  
Vol 275-277 ◽  
pp. 456-461
Author(s):  
Lei Zhang ◽  
Lai Bing Zhang ◽  
Bin Quan Jiang ◽  
Huan Liu
Keyword(s):  
Pressure Drop ◽  
Material Balance ◽  
Production Method ◽  
Gas Production ◽  
Constant Volume ◽  
Phase Method ◽  
Gas Reservoirs ◽  
Two Phase ◽  
Material Balance Method ◽  
Unit Pressure

The accurate prediction of the dynamic reserves of gas reservoirs is the important research content of the development of dynamic analysis of gas reservoirs. It is of great significance to the stable and safe production and the formulation of scientific and rational development programs of gas reservoirs. The production methods of dynamic reserves of gas reservoirs mainly include material balance method, unit pressure drop of gas production method and elastic two-phase method. To clarify the characteristics of these methods better, in this paper, we took two typeⅠwells of a constant volume gas reservoir as an example, the dynamic reserves of single well controlled were respectively calculated, and the results show that the order of the calculated volume of the dynamic reserves by using different methods is material balance method> unit pressure drop of gas production method >elastic two-phase method. Because the material balance method is a static method, unit pressure drop of gas production method and elastic two-phase method are dynamic methods, therefore, for typeⅠwells of constant volume gas reservoirs, when the gas wells reached the quasi-steady state, the elastic two-phase method is used to calculate the dynamic reserves, and when the gas wells didn’t reach the quasi-steady state, unit pressure drop of gas production method is used to calculate the dynamic reserves. The conclusion has some certain theoretical value for the prediction of dynamic reserves for constant volume gas reservoirs.

Wettability Alteration to Intermediate Gas-Wetting in Gas-Condensate Reservoirs at High Temperatures

SPE Journal ◽  
2007 ◽  
Vol 12 (04) ◽  
pp. 397-407 ◽  
Author(s):  
Mashhad Mousa Fahes ◽  
Abbas Firoozabadi
Keyword(s):  
Hydraulic Fracturing ◽  
Production Rate ◽  
High Temperatures ◽  
Gas Production ◽  
Reservoir Rock ◽  
Wettability Alteration ◽  
Absolute Permeability ◽  
Low Permeability ◽  
Gas Well ◽  
Water Blocking

Summary Wettability of two types of sandstone cores, Berea (permeability on the order of 600 md), and a reservoir rock (permeability on the order of 10 md), is altered from liquid-wetting to intermediate gas-wetting at a high temperature of 140C. Previous work on wettability alteration to intermediate gas-wetting has been limited to 90C. In this work, chemicals previously used at 90C for wettability alteration are found to be ineffective at 140C. New chemicals are used which alter wettability at high temperatures. The results show that:wettability could be permanently altered from liquid-wetting to intermediate gas-wetting at high reservoir temperatures,wettability alteration has a substantial effect on increasing liquid mobility at reservoir conditions,wettability alteration results in improved gas productivity, andwettability alteration does not have a measurable effect on the absolute permeability of the rock for some chemicals. We also find the reservoir rock, unlike Berea, is not strongly water-wet in the gas/water/rock system. Introduction A sharp reduction in gas well deliverability is often observed in many low-permeability gas-condensate reservoirs even at very high reservoir pressure. The decrease in well deliverability is attributed to condensate accumulation (Hinchman and Barree 1985; Afidick et al. 1994) and water blocking (Engineer 1985; Cimolai et al. 1983). As the pressure drops below the dewpoint, liquid accumulates around the wellbore in high saturations, reducing gas relative permeability (Barnum et al. 1995; El-Banbi et al. 2000); the result is a decrease in the gas production rate. Several techniques have been used to increase gas well deliverability after the initial decline. Hydraulic fracturing is used to increase absolute permeability (Haimson and Fairhurst 1969). Solvent injection is implemented in order to remove the accumulated liquid (Al-Anazi et al. 2005). Gas deliverability often increases after the reduction of the condensate saturation around the wellbore. In a successful methanol treatment in Hatter's Pond field in Alabama (Al-Anazi et al. 2005), after the initial decline in well deliverability by a factor of three to five owing to condensate blocking, gas deliverability increased by a factor of two after the removal of water and condensate liquids from the near-wellbore region. The increased rates were, however, sustained for a period of 4 months only. The approach is not a permanent solution to the problem, because the condensate bank will form again. On the other hand, when hydraulic fracturing is used by injecting aqueous fluids, the cleanup of water accumulation from the formation after fracturing is essential to obtain an increased productivity. Water is removed in two phases: immiscible displacement by gas, followed by vaporization by the expanding gas flow (Mahadevan and Sharma 2003). Because of the low permeability and the wettability characteristics, it may take a long time to perform the cleanup; in some cases, as little as 10 to 15% of the water load could be recovered (Mahadevan and Sharma 2003; Penny et al. 1983). Even when the problem of water blocking is not significant, the accumulation of condensate around the fracture face when the pressure falls below dewpoint pressure could result in a reduction in the gas production rate (Economides et al. 1989; Sognesand 1991; Baig et al. 2005).

A Dynamic Workflow of Well Health Issue Prediction – Sulfur Deposition

2021 ◽  
Author(s):  
Bashirul Haq
Keyword(s):  
Material Balance ◽  
Gas Production ◽  
Health Issue ◽  
Sulfur Deposition ◽  
Gas Reservoirs ◽  
Gas Field ◽  
Actual Performance ◽  
Sulphur Deposition ◽  
Balance Analysis ◽  
Sour Gas

Abstract Sour gas reservoirs are vital sources for natural gas production. Sulphur deposition in the reservoir reduces a considerable amount of gas production due to permeability reduction. Consequently, well health monitoring and early prediction of Sulphur deposition are crucial for effective gas production from a sour gas reservoir. Dynamic gas material balance analysis is a useful technique in calculating gas initially in place utilizing the flowing wellhead or bottom hole pressures and rates during the well's lifetime. The approach did not apply to monitor a producing gas's health well and detect Sulphur deposition. This work aims to (i) modify dynamic gas material balance equation by adding the Sulphur deposition term, (ii) build a model to predict and validate the issue utilizing the modified equation. A unique form of the flowing material balance is developed by including Sulphur residue term. The curve fitting tool and modified flowing gas material balance are applied to predict well-expected behaviour. The variation between expected and actual performance indicates the health issue of a well. Initial, individual components of the model are tested. Then the model is validated with the known values. The workflow is applied to active gas field and correctly detected the health issue. The novel workflow can accurately predict Sulphur evidence. Besides,the workflow can notify the production engineers to take corrective measures about the subject. Keywords: Sulfur deposition, Dynamic gas material balance analysis, Workflow

scholarly journals Investigation of the Main Factors During Shale-gas Production Using Grey Relational Analysis

2016 ◽  
Vol 9 (1) ◽  
pp. 207-215 ◽  
Author(s):  
Hongling Zhang ◽  
Jing Wang ◽  
Haiyong Zhang
Keyword(s):  
Shale Gas ◽  
Gas Production ◽  
Gas Reservoirs ◽  
Fracture Conductivity ◽  
Matrix Permeability ◽  
Shale Gas Reservoirs ◽  
Main Factors ◽  
Grey Relational ◽  
The Impact ◽  
Half Length

Shale gas is one of the primary types of unconventional reservoirs to be exploited in search for long-lasting resources. Production from shale gas reservoirs requires horizontal drilling with hydraulic fracturing to achieve the most economic production. However, plenty of parameters (e.g., fracture conductivity, fracture spacing, half-length, matrix permeability, and porosity,etc) have high uncertainty that may cause unexpected high cost. Therefore, to develop an efficient and practical method for quantifying uncertainty and optimizing shale-gas production is highly desirable. This paper focuses on analyzing the main factors during gas production, including petro-physical parameters, hydraulic fracture parameters, and work conditions on shale-gas production performances. Firstly, numerous key parameters of shale-gas production from the fourteen best-known shale gas reservoirs in the United States are selected through the correlation analysis. Secondly, a grey relational grade method is used to quantitatively estimate the potential of developing target shale gas reservoirs as well as the impact ranking of these factors. Analyses on production data of many shale-gas reservoirs indicate that the recovery efficiencies are highly correlated with the major parameters predicted by the new method. Among all main factors, the impact ranking of major factors, from more important to less important, is matrix permeability, fracture conductivity, fracture density of hydraulic fracturing, reservoir pressure, total organic content (TOC), fracture half-length, adsorbed gas, reservoir thickness, reservoir depth, and clay content. This work can provide significant insights into quantifying the evaluation of the development potential of shale gas reservoirs, the influence degree of main factors, and optimization of shale gas production.

scholarly journals Unconventional Gas Production from Hydraulically Fractured Well-An Application of Direct Search Based Optimization Algorithm

2019 ◽  
Vol 8 (2S11) ◽  
pp. 2726-2737
Keyword(s):  
Objective Function ◽  
Fracture Propagation ◽  
Gas Production ◽  
Production Model ◽  
Tight Gas ◽  
Gas Reservoirs ◽  
Unconventional Gas ◽  
Fracture Geometry ◽  
Propagation Behavior ◽  
Fractured Well

Unconventional gas reservoirs are now the targets for meeting the demand for gas. These reservoirs are at the depth of more than 10,000 ft (even over 15000 depth as well) and are difficult to be exploited by conventional methods. For the last decades hydraulic fracturing has become the tool to develop these resources. Mathematical models (2D and pseudo-3D) have been developed for fracture geometry, which should be realistically created at the depth by surface controllable treatment parameters. If the reservoir rock is sandstone, then proppant fracturing is suitable and if the rock is carbonates, then acid fracturing is applicable. In both cases, proper design of controllable treatment parameters within constraints is essential. This needs proper optimization model which gives real controllable parametric vales. The model needs the most important analyses from geomechanical study and linear elastic fracture mechanics of rock containing unconventional gas so that fracture geometry makes maximum contact with the reservoirs for maximum recovery. Currently available software may lack proper optimization scheme containing geomechanical stress model, fracture geometry, natural fracture interactions, real field constraints and proper reservoir engineering model of unconventional gas resources, that is, production model from hydraulically fractured well (vertical and horizontal). An optimization algorithm has been developed to integrate all the modules, as mentioned above, controllable parameters, field constraints and production model with an objective function of maximum production (with or without minimization of treatment cost). Optimization is basically developed based on Direct Search Genetic and Polytope algorithm, which can handle dual objective function, non-differentiable equations, discontinuity and non-linearity. A dual objective function will meet operator’s economic requirements and investigate conflict between two objectives. The integrated model can be applied to a vertical or horizontal well in tight gas or ultra-tight shale gas deeper than over 10,000 ft. A simulation (with industrial simulators) was conducted to investigate and analyse fracture propagation behavior, under varying parameters with respect to the fracture design process, for tight gas reservoirs. Results indicate that hydraulic fracture propagation behavior is not uninhibited in deep reservoirs as some may believe that minor variations of variables such as in-situ stress, fluid properties etc. are often detrimental to fracture propagation in some conditions. Application of this model to a hypothetical tight and ultra-tight unconventional gas formations indicates a significant gas production at lower treatment cost; whereas the resources do not flow without any stimulation (hydraulic fracturing).

scholarly journals An Analytical Method for Parameter Interpretation of Fracture Networks in Shale Gas Reservoirs considering Uneven Support of Fractures

Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-15
Author(s):  
Shijun Huang ◽  
Jiaojiao Zhang ◽  
Sidong Fang ◽  
Xifeng Wang
Keyword(s):  
Data Analysis ◽  
Shale Gas ◽  
Analytical Method ◽  
Material Balance ◽  
Gas Production ◽  
Production Data ◽  
Analysis Method ◽  
Gas Reservoirs ◽  
Data Analysis Method ◽  
Parameter Interpretation

In shale gas reservoirs, the production data analysis method is widely used to invert reservoir and fracture parameter, and productivity prediction. Compared with numerical models and semianalytical models, which have high computational cost, the analytical model is mostly used in the production data analysis method to characterize the complex fracture network formed after fracturing. However, most of the current calculation models ignore the uneven support of fractures, and most of them use a single supported fracture model to describe the flow characteristics, which magnifies the role of supported fracture to a certain extent. Therefore, in this study, firstly, the fractures are divided into supported fractures and unsupported fractures. According to the near-well supported fractures and far-well unsupported fractures, the SRV zone is divided into outer SRV and inner SRV. The four areas are characterized by different seepage models, and the analytical solutions of the models are obtained by Laplace transform and inverse transform. Secondly, the material balance pseudotime is introduced to process the production data under the conditions of variable production and variable pressure. The double logarithmic curves of normalized production rate, rate integration, the derivative of the integration, and material balance pseudotime are established, and the parameters are interpreted by fitting the theoretical curve to the measured data. Then, the accuracy of the method is verified by comparison the parameter interpretation results with well test results, and the influence of parameters such as the half-length and permeability of supported and unsupported fractures on gas production is analyzed. Finally, the proposed method is applied to four field cases in southwest China. This paper mainly establishes an analytical method for parameter interpretation after hydraulic fracturing based on the production data analysis method considering the uneven support of fractures, which is of great significance for understanding the mechanism of fracturing stimulation, optimization of fracturing parameters, and gas production forecast.

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