scholarly journals A Facile Low-Temperature Hydrothermal Method to Prepare Anatase Titania/Cellulose Aerogels with Strong Photocatalytic Activities for Rhodamine B and Methyl Orange Degradations

2015 ◽  
Vol 2015 ◽  
pp. 1-8
Author(s):  
Caichao Wan ◽  
Yun Lu ◽  
Chunde Jin ◽  
Qingfeng Sun ◽  
Jian Li

A facile low-temperature hydrothermal method for in situ preparation of anatase titania (TiO2) homogeneously dispersed in cellulose aerogels substrates was described. The formed anatase TiO2aggregations composed of a mass of evenly dispersed TiO2nanoparticles with sizes of 2−5 nm were embedded in the interconnected three-dimensional (3D) architecture of the cellulose aerogels matrixes without large-scale reunion phenomenon; meanwhile, the obtained anatase titania/cellulose (ATC) aerogels also had a high loading amount of TiO2(ca. 35.7%). Furthermore, compared with commercially available Degussa P25, ATC aerogels displayed comparable photocatalytic activities for Rhodamine B and methyl orange degradations under UV radiation, which might be useful in the fields of catalysts, wastewater treatment, and organic pollutant degradation. Meanwhile, the photocatalytic reaction behaviors of ATC aerogels under UV irradiation were also illuminated.

2021 ◽  
Vol 10 (2) ◽  
pp. 59-63
Author(s):  
Hai Pham Viet ◽  
Anh Dao Thi Ngoc ◽  
Viet Nguyen Minh ◽  
Ha Tran Thi Viet ◽  
Dang Do Van ◽  
...  

In this study, direct Z–scheme heterostructure CoWO4/g-C3N4 was synthesized by a facile hydrothermal method. The structural, morphological properties of the prepared samples were characterised by XRD, SEM, UV–Vis and PL measurements. The as-obtained heterostructure CoWO4/g-C3N4 exhibited enhanced photocatalytic activities toward the degradation of Rhodamine B under visible light irradiation with 92% Rhodamine B removal after 80 minutes irritation, which exceeded pristine g-C3N4 and CoWO4. The enhanced photocatalytic performance ascribed to interfacial contact between g-C3N4 and CoWO4, thus further inhibiting the recombination of photogenerated electron/hole pairs. It is anticipated that the construction of Z–scheme heterostructure CoWO4/g-C3N4 is an effective strategy to develop high-performance photocatalysts for the degradation of organic pollutants in water.


2013 ◽  
Vol 423-426 ◽  
pp. 163-166 ◽  
Author(s):  
Bao Wei Cao ◽  
Yun Hua Xu

Bi2WO6 doped with iodine ions were synthesized using hydrothermal method and their photocatalytic activities to degrade Rhodamine B (RhB) under visible-light was investigated. The successful incorporation of I ions in Bi2WO6 was proved by XRD and XPS. UV-vis absorption spectra results show that I ion was successfully doped into Bi2WO6 and a red shift for I-doped Bi2WO6 appeared when compared to pure Bi2WO6. The photocatalytic activities of the photocatalysts were evaluated by the decolorization of RhB under visible-light irradiation. The results showed that the photocatalytic activity of I-doped Bi2WO6 was much higher than the undoped Bi2WO6.


2018 ◽  
Vol 140 (1) ◽  
Author(s):  
Asisa Kumar Panigrahy ◽  
Kuan-Neng Chen

Arguably, the integrated circuit (IC) industry has received robust scientific and technological attention due to the ultra-small and extremely fast transistors since past four decades that consents to Moore's law. The introduction of new interconnect materials as well as innovative architectures has aided for large-scale miniaturization of devices, but their contributions were limited. Thus, the focus has shifted toward the development of new integration approaches that reduce the interconnect delays which has been achieved successfully by three-dimensional integrated circuit (3D IC). At this juncture, semiconductor industries utilize Cu–Cu bonding as a key technique for 3D IC integration. This review paper focuses on the key role of low temperature Cu–Cu bonding, renaissance of the low temperature bonding, and current research trends to achieve low temperature Cu–Cu bonding for 3D IC and heterogeneous integration applications.


RSC Advances ◽  
2015 ◽  
Vol 5 (42) ◽  
pp. 33001-33007 ◽  
Author(s):  
Deqing Zhang ◽  
Junye Cheng ◽  
Feng Shi ◽  
Zhangjie Cheng ◽  
Xiuying Yang ◽  
...  

Ribbon-like orthorhombic NaNbO3 fibers were successfully prepared by combining a traditional hydrothermal method with post-heat treatment at a low annealing temperature.


2017 ◽  
Vol 24 (3) ◽  
pp. 307-328 ◽  
Author(s):  
Elisa Johanna Spreitzer ◽  
Manuel Patrik Marschalik ◽  
Peter Spichtinger

Abstract. Ice clouds, so-called cirrus clouds, occur very frequently in the tropopause region. A special class are subvisible cirrus clouds with an optical depth lower than 0.03, associated with very low ice crystal number concentrations. The dominant pathway for the formation of these clouds is not known well. It is often assumed that heterogeneous nucleation on solid aerosol particles is the preferred mechanism although homogeneous freezing of aqueous solution droplets might be possible, since these clouds occur in the low-temperature regime T < 235 K. For investigating subvisible cirrus clouds as formed by homogeneous freezing we develop a reduced cloud model from first principles, which is close enough to complex models but is also simple enough for mathematical analysis. The model consists of a three-dimensional set of ordinary differential equations, and includes the relevant processes as ice nucleation, diffusional growth and sedimentation. We study the formation and evolution of subvisible cirrus clouds in the low-temperature regime as driven by slow vertical updraughts (0 < w ≤ 0. 05 m s−1). The model is integrated numerically and also investigated by means of theory of dynamical systems. We found two qualitatively different states for the long-term behaviour of subvisible cirrus clouds. The first state is a stable focus; i.e. the solution of the differential equations performs damped oscillations and asymptotically reaches a constant value as an equilibrium state. The second state is a limit cycle in phase space; i.e. the solution asymptotically approaches a one-dimensional attractor with purely oscillatory behaviour. The transition between the states is characterised by a Hopf bifurcation and is determined by two parameters – vertical updraught velocity and temperature. In both cases, the properties of the simulated clouds agree reasonably well with simulations from a more detailed model, with former analytical studies, and with observations of subvisible cirrus, respectively. The reduced model can also provide qualitative interpretations of simulations with a complex and more detailed model at states close to bifurcation qualitatively. The results indicate that homogeneous nucleation is a possible formation pathway for subvisible cirrus clouds. The results motivate a minimal model for subvisible cirrus clouds (SVCs), which might be used in future work for the development of parameterisations for coarse large-scale models, representing structures of clouds.


2009 ◽  
Vol 610-613 ◽  
pp. 225-228
Author(s):  
Xiang Ping Huang ◽  
Zhao Wang ◽  
Feng Mao ◽  
Hui Li Wei ◽  
Chang Yuan Zhang

Pure rutile TiO2 nanorod-assembled microspheres were synthesized on a large scale without templates or surfactants by hydrolysis of TiCl3 in ethanol and HCl mixed solution at 180°C.The spheres exhibit unique three-dimensional hierarchical architectures with significantly improved photocatalytic activities in visible light.


2013 ◽  
Vol 853 ◽  
pp. 111-115
Author(s):  
Wei Wang ◽  
Ya Ru Ni ◽  
Chun Hua Lu ◽  
Zhong Zi Xu

High-reactive {001} facets dominated anatase TiO2 nanosheets were synthesized successfully by a simple hydrothermal method. CNTs were used to couple with as-prepared TiO2 nanosheets to further improve the photocatalytic activity of TiO2. Photocatalytic activities of the photocatalysts were tested by the degradation of Rhodamine B (RhB) aqueous solution under the xenon lamp irradiation. The results indicate that the introduction of CNTs will improve the photocatalytic activities of TiO2 which can be ascribed to the enhanced light absorption and separation efficiency of photogenerated holes and electrons. There was also an optimal content of CNTs to modify TiO2, and a possible mechanism for this idea was also proposed.


2020 ◽  
Author(s):  
Raghavendra K. Sali ◽  
Malatesh S. Pujar ◽  
Aishwarya Nadgir ◽  
Ashok H. Sidarai

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