scholarly journals The Luminescence Properties and Energy Transfer from Ce3+to Pr3+for YAG:Ce3+Pr3+Phosphors

2015 ◽  
Vol 2015 ◽  
pp. 1-8
Author(s):  
Rongfeng Guan ◽  
Liu Cao ◽  
Yajun You ◽  
Yuebin Cao

Y2.94−xAl5O12(YAG):Ce0.06Prxphosphors with various Pr3+concentrations (x=0, 0.006, 0.01, 0.03, 0.06, and 0.09) were synthesized by using a coprecipitation method. The phases, luminescent properties, and energy transfer phenomenon from Ce3+to Pr3+were investigated. The results indicated that the doping of Pr3+  (x≤0.09)did not produce any new phases but caused a slight lattice parameters increase. After Pr3+doping, the YAG:CePr phosphor emits red light at 610 nm, which was regarded helpful for improving the colour rendering index of the phosphor. With Pr3+concentration increase from 0.006 to 0.01 mol, the intensity of red light emission increased slightly; further increasing Pr3+concentration from 0.01 to 0.09, the red light emission intensity decreased gradually. Excitation at 340, and 460 nm could not lead to the direct electronic excitation of Pr3+ions; however, when YAG:CePr was excited at 340 nm a red light emission at 610 nm appeared, which implied the energy transfer phenomenon from Ce3+to Pr3+.

RSC Advances ◽  
2017 ◽  
Vol 7 (7) ◽  
pp. 4196-4202 ◽  
Author(s):  
Fengxian Lu ◽  
Rui Hu ◽  
Shuangqing Wang ◽  
Xudong Guo ◽  
Guoqiang Yang

A saturated white-light emission was obtained by dispersing three benzothiazole analogues into a solid PMMA matrix. This skillfully avoids the detrimental energy transfer between doped dyes providing a simple approach for fabrication of white-light emitting devices.


Nanomaterials ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 1375 ◽  
Author(s):  
Kniec ◽  
Ledwa ◽  
Marciniak

In this work the influence of the Ga3+ concentration on the luminescent properties and the abilities of the Y3Al5−xGaxO12: V nanocrystals to noncontact temperature sensing were investigated. It was shown that the increase of the Ga3+ amount enables enhancement of V4+ emission intensity in respect to the V3+ and V5+ and thus modify the color of emission. The introduction of Ga3+ ions provides the appearance of the crystallographic sites, suitable for V4+ occupation. Consequently, the increase of V4+ amount facilitates V5+ → V4+ interionic energy transfer throughout the shortening of the distance between interacting ions. The opposite thermal dependence of V4+ and V5+ emission intensities enables to create the bandshape luminescent thermometr of the highest relative sensitivity of V-based luminescent thermometers reported up to date (Smax, 2.64%/°C, for Y3Al2Ga3O12 at 0 °C). An approach of tuning the performance of Y3Al5−xGaxO12: V nanocrystals to luminescent temperature sensing, including the spectral response, maximal relative sensitivity and usable temperature range, by the Ga3+ doping was presented and discussed.


2019 ◽  
Vol 58 (12) ◽  
pp. 3097 ◽  
Author(s):  
K. Y. Tucto ◽  
W. Aponte ◽  
J. A. Dulanto ◽  
J. A. Töfflinger ◽  
J. A. Guerra ◽  
...  

1969 ◽  
Vol 15 (1) ◽  
pp. 3-14 ◽  
Author(s):  
K Van Dyke ◽  
R Stitzel ◽  
T McClellan ◽  
C Szustkiewicz

Abstract An automated procedure is described for the measurement of ATP. This method, based on the linear luminescence response of firefly extracts added to ATP, is rapid, reproducible, and allows a relatively large number of samples to be run (up to 35/hr.). A procedure is also given for the preparation of the luciferin-luciferase system from dried firefly lanterns. Sample volumes required are small, and reading error is about ± 3%. Uniform timing of the addition of reagents and reading of light emission intensity for each sample are insured. Variables investigated include dilution of firefly extract, alterations in time after mixing sample and enzyme, linearity, cation, anion, and ADP and AMP interference.


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