scholarly journals Photocatalytic Based Degradation Processes of Lignin Derivatives

2015 ◽  
Vol 2015 ◽  
pp. 1-18 ◽  
Author(s):  
Colin Awungacha Lekelefac ◽  
Nadine Busse ◽  
Michael Herrenbauer ◽  
Peter Czermak

Photocatalysis, belonging to the advanced oxidation processes (AOPs), is a potential new transformation technology for lignin derivatives to value added products (e.g., phenol, benzene, toluene, and xylene). Moreover, lignin represents the only viable source to produce aromatic compounds as fossil fuel alternative. This review covers recent advancement made in the photochemical transformation of industrial lignins. It starts with the photochemical reaction principle followed by results obtained by varying process parameters. In this context, influences of photocatalysts, metal ions, additives, lignin concentration, and illumination intensity and the influence of pH are presented and discussed. Furthermore, an overview is given on several used process analytical methods describing the results obtained from the degradation of lignin derivatives. Finally, a promising concept by coupling photocatalysis with a consecutive biocatalytic process was briefly reviewed.

2019 ◽  
Vol 10 (1) ◽  
pp. 3-19 ◽  
Author(s):  
Somya Singhal ◽  
Prasad Rasane ◽  
Sawinder Kaur ◽  
Umar Garba ◽  
Jyoti Singh ◽  
...  

Background: Edible mushrooms are an abundant source of carbohydrates, proteins, and multiple antioxidants and phytonutrients. This paper presents a general overview on the edible fungus describing the inventions made in the field of its cultivation, equipment and value-added products. </P><P> Objective: To understand and review the innovations and nutraceutical benefits of mushrooms as well as to develop interest regarding the edible mushrooms. </P><P> Methods: Information provided in this review is based on the available research investigations and patents. </P><P> Result: Mushrooms are an edible source of a wide variety of antioxidants and phytonutrients with a number of nutraceutical properties including anti-tumor and anti-carcinogenic. Thus, several investigations are made for cultivation and improvement of the yield of mushrooms through improvisation of growth substrates and equipment used for mushroom processing. The mushroom has been processed into various products to increase its consumption, providing the health and nutritional benefit to mankind. </P><P> Conclusion: This paper summarizes the cultivation practices of mushroom, its processing equipment, methods of preservation, value-added based products, and its nutraceutical properties. The review also highlights the various scientific feats achieved in terms of patents and research publications promoting mushroom as a wholesome food.


2019 ◽  
Vol 48 (36) ◽  
pp. 13508-13528 ◽  
Author(s):  
Diana M. Fernandes ◽  
Andreia F. Peixoto ◽  
Cristina Freire

This review focuses on the recent developments made in the fabrication of N-doped carbon materials for enhanced CO2 conversion and electrochemical reduction into high-value-added products.


2021 ◽  
Author(s):  
Lethiwe D. Mthembu ◽  
Rishi Gupta ◽  
Nirmala Deenadayalu

Rapid industrialization has led to development of various platform chemicals and fossil fuel refinery is one of the mainstreams for their production. However continuous depletion of fossil fuels reserves has led an urge to look for alternate source of feedstocks. Among various renewable sources, biomass is found to be most sustainable as it is replaced naturally. Biomass by virtue of its nature is comprised of various recalcitrant polymers and cellulose is one of them, which can be used for the generation of various platform chemicals. This chapter gives a background of cellulose and illustrate platform chemicals that can be produced from cellulose.


2016 ◽  
Vol 2 (1) ◽  
pp. 79 ◽  
Author(s):  
Bruna Steil Boneberg ◽  
Grazielle Dias Machado ◽  
Davi Friedrich Santos ◽  
Fernando Gomes ◽  
Douglas José Faria ◽  
...  

Lignocellulosic biomass has been widely investigated as a natural renewable source of feedstocks to produce high value added products which can replace energy and materials obtained from non-renewable sources. Polymers are products largely employed in industry in many different applications, which nowadays are mostly produced from petrochemical derivatives, generating huge amounts of waste of difficult treatment prior to disposal. In order to replace these polymers derived from petroleum, efforts have been made in the development of biopolymers, in the biorefinery context, derived from biomass possessing physicochemical properties similar to those derived from petroleum so that they can successfully replace these materials. A review on the different types of biopolymers obtained from biomass, as polysaccharides, lipids, proteins, polyesters produced by plants and microorganisms, and other assorted biopolymers is accomplished. An evaluation of physicochemical properties and applications of different types of biopolymers is approached. It is also discussed about the degradability of biopolymers differentiating oxo-degradability and biodegradability. A brief historic background about biopolymers is also exposed.


2020 ◽  
Vol 21 (2) ◽  
pp. 80-95 ◽  
Author(s):  
Zeba Usmani ◽  
Minaxi Sharma ◽  
Surya Sudheer ◽  
Vijai K. Gupta ◽  
Rajeev Bhat

Agri-food waste biomass is the most abundant organic waste and has high valorisation potential for sustainable bioproducts development. These wastes are not only recyclable in nature but are also rich sources of bioactive carbohydrates, peptides, pigments, polyphenols, vitamins, natural antioxidants, etc. Bioconversion of agri-food waste to value-added products is very important towards zero waste and circular economy concepts. To reduce the environmental burden, food researchers are seeking strategies to utilize this waste for microbial pigments production and further biotechnological exploitation in functional foods or value-added products. Microbes are valuable sources for a range of bioactive molecules, including microbial pigments production through fermentation and/or utilisation of waste. Here, we have reviewed some of the recent advancements made in important bioengineering technologies to develop engineered microbial systems for enhanced pigments production using agrifood wastes biomass/by-products as substrates in a sustainable way.


2021 ◽  
Vol 12 ◽  
Author(s):  
Qingxin Li

Keratinases belong to a class of proteases that are able to degrade keratins into amino acids. Microbial keratinases play important roles in turning keratin-containing wastes into value-added products by participating in the degradation of keratin. Keratin is found in human and animal hard tissues, and its complicated structures make it resistant to degradation by common proteases. Although breaking disulfide bonds are involved in keratin degradation, keratinase is responsible for the cleavage of peptides, making it attractive in pharmaceutical and feather industries. Keratinase can serve as an important tool to convert keratin-rich wastes such as feathers from poultry industry into diverse products applicable to many fields. Despite of some progress made in isolating keratinase-producing microorganisms, structural studies of keratinases, and biochemical characterization of these enzymes, effort is still required to expand the biotechnological application of keratinase in diverse fields by identifying more keratinases, understanding the mechanism of action and constructing more active enzymes through molecular biology and protein engineering. Herein, this review covers structures, applications, biochemistry of microbial keratinases, and strategies to improve its efficiency in keratin degradation.


2021 ◽  
Vol 55 (3-4) ◽  
pp. 207-222
Author(s):  
RAMANDEEP KAUR ◽  
PUNEET KAUR

"The potential of non-edible lignocellulosic biomass paves the path to sustainable economy. A large number of valueadded products have been synthesized by the fractionation of the major components of biomass, i.e. cellulose, hemicelluloses and lignin. Cellulose, the most abundant biopolymer on earth, serves as a starting material for the synthesis of various platform chemicals, such as sorbitol, 5- hydroxylmethylfurfural (HMF), dimethylfuran and levulinic acid. Hydrogels and aerogels fabricated from cellulose, modified cellulose or nanocellulose have proved valuable in a wide range of such as biomedical, food and technological applications. Cellulose-based polymers or bioplastics also emerged as an alternative to fossil fuel-based polymers. In this review, chemical paths to valorize plant cellulose for producing various value-added products have been discussed. The major challenge for valorization is the development of novel and green synthesis methods with simultaneous focus on an integrated approach."


2021 ◽  
Vol 2 (3) ◽  
pp. 467-492
Author(s):  
Marta. E. G. Mosquera ◽  
Gerardo Jiménez ◽  
Vanessa Tabernero ◽  
Joan Vinueza-Vaca ◽  
Carlos García-Estrada ◽  
...  

Polymers are essential materials in our daily life. The synthesis of value-added polymers is mainly performed from fossil fuel-derived monomers. However, the adoption of the circular economy model based on the bioeconomy will reduce the dependence on fossil fuels. In this context, biorefineries have emerged to convert biomass into bioenergy and produce high value-added products, including molecules that can be further used as building blocks for the synthesis of biopolymers and bioplastics. The achievement of catalytic systems able to polymerize the natural monomer counterparts, such as terpenes or terpenoids, is still a challenge in the development of polymers with good mechanical, thermal, and chemical properties. This review describes the most common types of bioplastics and biopolymers and focuses specifically on the polymerization of terpenes and terpenoids, which represent a source of promising monomers to create bio-based polymers and copolymers.


2006 ◽  
Vol 56 (1) ◽  
pp. 1-43
Author(s):  
Sándor Richter

The order and modalities of cross-member state redistribution as well as the net financial position of the member states are one of the most widely discussed aspects of European integration. The paper addresses selected issues in the current debate on the EU budget for the period 2007 to 2013 and introduces four scenarios. The first is identical to the European Commission's proposal; the second is based on reducing the budget to 1% of the EU's GNI, as proposed by the six net-payer countries, while maintaining the expenditure structure of the Commission's proposal. The next two scenarios represent radical reforms: one of them also features a '1% EU GNI'; however, the expenditures for providing 'EU-wide value-added' are left unchanged and it is envisaged that the requisite cuts will be made in the expenditures earmarked for cohesion. The other reform scenario is different from the former one in that the cohesion-related expenditures are left unchanged and the expenditures for providing 'EU-wide value-added' are reduced. After the comparison of the various scenarios, the allocation of transfers to the new member states in terms of the conditions prevailing in the different scenarios is analysed.


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