scholarly journals Adsorption of Molecular Gases on Silver/Carbon Nanotube Composites at Low Temperatures and Low Pressures

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
M. Barberio ◽  
P. Barone ◽  
F. Stranges ◽  
R. A. Romano ◽  
F. Xu ◽  
...  

We present an experimental study adsorption of molecular gases (N2, H2, O2, CH4, C2H4, and C2H6) on multiwalled carbon nanotubes (MWCNTs) and MWCNT doped with Ag at low temperatures (35 K) and pressures (10−6 Torr) using the temperature programmed desorption technique. Our results show that the desorption kinetics is of the first order; furthermore comparative measurements indicate that Ag/MWCNTs have an adsorption capacity higher than that of a pure sample suggesting that these composites are good candidates as gas cryosorbers for applications in cryopumps or sensor of latest generation.

1992 ◽  
Vol 282 ◽  
Author(s):  
Yuemei L. Yang ◽  
Stephen M. Cohen ◽  
Mark P. D'Evelyn

ABSTRACTThe chemistry of coadsorbed H and X (X=C1, Br) on semiconductor surfaces is important in epitaxial growth of silicon from chlorosilanes and of SixGe1−x alloys, in hydrogenating/ halogenating cycles in atomic layer epitaxy, and also provides an interesting model system, yet has received little attention to date. We have investigated the interaction of HC1 and HBr with Ge(100) by temperature-programmed desorption, and find that H2, HCl and HBr each desorb with near-first-order kinetics near 570–590 K and that GeCl2 and GeBr2 desorb with near-second-order kinetics near 675 K and 710 K, respectively. Analysis of the desorption kinetics of H2 and HX provides evidence that adsorbed H and X atoms pair preferentially in a qualitatively similar way as H atoms adsorbed alone on Ge(100)2×1 or Si(100)2×1 and that pairing of H+X occurs in competition with pairing of H+H.


Langmuir ◽  
2010 ◽  
Vol 26 (23) ◽  
pp. 18308-18314 ◽  
Author(s):  
Anderson O. Lobo ◽  
Marcus A. F. Corat ◽  
Sandra C. Ramos ◽  
Jorge T. Matsushima ◽  
Alessandro E. C. Granato ◽  
...  

2014 ◽  
Vol 38 (10) ◽  
pp. 4799-4806 ◽  
Author(s):  
Md. Shahinul Islam ◽  
Won San Choi ◽  
Tae Sung Bae ◽  
Young Boo Lee ◽  
Ha-Jin Lee

We report a simple protocol for the fabrication of multiwalled carbon nanotubes (MWCNTs) with a neuron-like structure for loading ultra-high densities of metal nanoparticles (NPs).


2014 ◽  
Vol 64 (3) ◽  
pp. 373-382 ◽  
Author(s):  
Kung-Chin Chang ◽  
Chien-Ming Chu ◽  
Chi-Hao Chang ◽  
Hsiao-Tung Cheng ◽  
Sheng-Chieh Hsu ◽  
...  

2019 ◽  
Vol 61 (3) ◽  
pp. 323-330 ◽  
Author(s):  
F. H. El-Sweify ◽  
I. M. Abdelmonem ◽  
A. M. El-Masry ◽  
T. E. Siyam ◽  
S. F. Abo-Zahra

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