scholarly journals Electrochemical Impedance Spectroscopy Investigation on the Clinical Lifetime of ProTaper Rotary File System

2014 ◽  
Vol 2014 ◽  
pp. 1-10
Author(s):  
Virgil Penta ◽  
Cristian Pirvu ◽  
Ioana Demetrescu
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Oxide Layer ◽  
File System ◽  
Electrochemical Impedance ◽  
Protective Layer ◽  
Electrochemical Technique ◽  
Clinical Aspects ◽  
Surface Oxide Layer

The main objective of the current paper is to show that electrochemical impedance spectroscopy (EIS) could be a method for evaluating and predicting of ProTaper rotary file system clinical lifespan. This particular aspect of everyday use of the endodontic files is of great importance in each dental practice and has profound clinical implications. The method used for quantification resides in the electrochemical impedance spectroscopy theory and has in its main focus the characteristics of the surface titanium oxide layer. This electrochemical technique has been adapted successfully to identify the quality of the Ni-Ti files oxide layer. The modification of this protective layer induces changes in corrosion behavior of the alloy modifying the impedance value of the file. In order to assess the method, 14 ProTaper sets utilized on different patients in a dental clinic have been submitted for testing using EIS. The information obtained in regard to the surface oxide layer has offered an indication of use and proves that the said layer evolves with each clinical application. The novelty of this research is related to an electrochemical technique successfully adapted for Ni-Ti file investigation and correlation with surface and clinical aspects.

scholarly journals Efficiency of Organic Corrosion Inhibitors Derived from Thai-Bael Fruit Extract for Preventing Corrosion in Carbon Steels

2020 ◽  
Vol 32 (8) ◽  
pp. 2043-2050
Author(s):  
Phattarasuda Manantapong ◽  
Nattanon Chaipunya ◽  
Suttipong Wannapaiboon ◽  
Prae Chirawatkul ◽  
Worawat Wattanathana ◽  
...  
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Steel Surface ◽  
Electrochemical Impedance ◽  
Protective Layer ◽  
Corrosion Current ◽  
Carbon Steels ◽  
Fruit Extract ◽  
Polarization Measurements ◽  
Hcl Solution

The inhibiting action of Thai-bael fruit extract at room temperature on hot-rolled steel in 1M HCl solution was studied. The chemical functional groups of the green inhibitors were characterized by Fourier-transformed infrared spectroscopy. The electrochemical activities of steel surface were investigated through linear polarization measurements, electrochemical impedance spectroscopy, surface assessment techniques based on optical microscopy and X-ray absorption spectroscopy. Electrochemical testing samples have been prepared in the form of square plates with the size 1 × 1 cm2. The organic corrosion inhibitor extract from Thai-bael fruit has shown the smallest corrosion current density (Icorr) of 114.8 μA cm-2 and corrosion potential (Ecorr) of -424.6 mV, compared with standard Ag/AgCl electrode potential. In comparison, similar tests in the bare HCl solutions yielded Icorr = 882.4 mA cm-2 and Ecorr = -445.8 mV. The mixed-type corrosion inhibiting behaviour was evidenced in the results of the polarization measurements. Electrochemical impedance spectroscopy reveals that the resistance to charge transfer due to the presence of the extracts has been increased by about four times that of the same test on the bare HCl solution, indicating the formation of a protective layer. The adsorption of the organic molecules near the steel-electrolyte interface is evident in the decreasing double-layer capacitance with the enhancing concentration levels of the extract. This latter finding supports the displacement of the water molecules by means of the adsorption of the inhibitors on the steel surface. The optical images of steel surface before and after being immersed in HCl solution also showed pieces of evidence of corrosion retardation. XANES study as well as the linear combination fitting revealed that the samples immersed in HCl solutions with Thai-bael fruit extract possess less Fe3+ compositions. All tendencies across the four examinations indicate that Thai-bael fruit extract could potentially inhibit the corrosion reaction of steel electrodes in the acidic solution.

scholarly journals Modelling of an equivalent circuit for Cu2ZnSnS4- and Cu2ZnSnSe4-based thin film solar cells

RSC Advances ◽  
2017 ◽  
Vol 7 (41) ◽  
pp. 25347-25352 ◽  
Author(s):  
Naoyuki Shibayama ◽  
Yiwen Zhang ◽  
Tetsuo Satake ◽  
Mutsumi Sugiyama
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Equivalent Circuit ◽  
Electrochemical Impedance ◽  
Internal Resistance ◽  
Thin Film Solar Cells

The internal resistance and quality of the interface in CZTS solar cells were investigated using electrochemical impedance spectroscopy.

Evaluation of N,N-Dimethylformamide as Corrosion Inhibitor on API 5L X70 using 3% NaCl

MRS Advances ◽  
2019 ◽  
Vol 4 (44-45) ◽  
pp. 2391-2399
Author(s):  
Pablo Martínez Jiménez ◽  
Araceli Espinoza Vázquez ◽  
Francisco Javier Rodríguez Gómez
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Corrosion Inhibitor ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Electrochemical Technique ◽  
Metallic Surface ◽  
Hydrodynamic Conditions ◽  
Metallic Material ◽  
Corrosive Solution

AbstractDimethylformamide (DMF) has been tested as corrosion inhibitor in a metallic material like API 5LX70 in a corrosive solution of 3% of NaCl and using electrochemical technique as electrochemical impedance spectroscopy. The results showed that 20 ppm is the best concentration to protect the metallic surface of API 5L X70 with η∼ 94%. Hydrodynamic conditions (100 and 1000 rpm) demonstrated that the DMF at different concentration afforded moderate protection against corrosion with inhibition efficiency ∼70%. Finally, the adsorption of this compound follows the Langmuir isotherm with a chemisorption-physisorption process.

ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY FOR PALM COOKING OIL DISCRIMINATOR USING PLANAR ELECTROMAGNETIC SENSOR ARRAY

2016 ◽  
Vol 78 (7-4) ◽  
Author(s):  
Ahmad Amsyar Azman ◽  
Ruzairi Abdul Rahim ◽  
Sallehuddin Ibrahim ◽  
Aizat Azmi ◽  
Agus Arsad ◽  
...  
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Palm Oil ◽  
Sensor Array ◽  
Electrochemical Impedance ◽  
Food Industries ◽  
Cooking Oil ◽  
Electromagnetic Sensor ◽  
The Cost

Cooking oil is an important product in the Malaysia food industries. Most of the cooking oil products is based on palm oil. However, there are activities in selling cheaper cooking oil by labelling as high quality in cooking oil product. Traditional methods have been developed to measure the quality of the cooking oil product such as the chromatography technique but the cost for the system setup is expensive and requires a large amount of time to analyse the sample. Thus, a suitable and reliable system with less analysis time is needed for widespread industrial uses. This paper has presented a discriminative technique for palm cooking oil using Electrochemical Impedance Spectroscopy (EIS) with planar electromagnetic sensor array. The sensor consists of a meander sensor and an interdigital sensors which interact with the test samples. Three types of palm cooking oil such as double refined palm oil, refined and deodorized palm oil with peanut and sesame oil, and filtered palm oil were prepared. The results obtained showed that the presented technique was able to differentiate the samples between 20 kHz to 1 Mhz. The results obtained correlate with the theories on EIS technique and planar electromagnetic sensor which are presented in this paper.      

scholarly journals Reducing the resistance for the use of electrochemical impedance spectroscopy analysis in materials chemistry

RSC Advances ◽  
2021 ◽  
Vol 11 (45) ◽  
pp. 27925-27936
Author(s):  
Nadia O. Laschuk ◽  
E. Bradley Easton ◽  
Olena V. Zenkina
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Intermediate Level ◽  
Materials Characterization ◽  
Electrochemical Technique ◽  
Materials Chemistry ◽  
Spectroscopy Analysis ◽  
Non Destructive ◽  
Impedance Spectroscopy Analysis

This manuscript highlights a beginner-to-intermediate level scope of electrochemical impedance spectroscopy (EIS), which is an indispensable, non-destructive electrochemical technique that can be applied for materials characterization.

scholarly journals Electrochemical Impedance Spectroscopy (EIS) in Food, Water, and Drug Analyses: Recent Advances and Applications

2020 ◽  
Author(s):  
Marwa El-Azazy
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
High Sensitivity ◽  
Electrochemical Technique ◽  
Water Safety ◽  
Food Contaminants ◽  
Sensitivity And Selectivity ◽  
Ac Current ◽  
Eis Measurements

Electrochemical impedance spectroscopy (EIS) is a potent electrochemical technique with a variety of applications. EIS measurements involve the application of an alternating current (AC) voltage (or current) to the system under investigation, followed by measurement of the response in the form of AC current (or voltage) as a function of frequency. By and large, EIS is an exceptionally attractive in terms of applications. Being nondestructive with a feasibility of implementation to the system to be measured and the usefulness of data obtained in characterizing the studied systems, electrochemical impedance spectroscopy has realms of applications. As food and water safety and security is becoming a universal concern, the need for a technique that can detect water and food contaminants with relatively high sensitivity and selectivity is evolving. EIS has started to realize its potential with a wide-term use in water and food analyses.

1,7′-dimethyl-2′-propyl-1H,3′H-2,5′-bibenzo[d]imidazole as a corrosion inhibitor of mild steel in 1 M HCl

2010 ◽  
Vol 64 (1) ◽  
Author(s):  
Niketan Patel ◽  
Smita Jauhari ◽  
Girishkumar Mehta
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Mild Steel ◽  
Mass Loss ◽  
Corrosion Inhibitor ◽  
Electrochemical Impedance ◽  
Protective Layer ◽  
Charge Transfer Resistance ◽  
Active Centers ◽  
Transfer Resistance

AbstractInhibition effect of imidazole derivative 1,7′-dimethyl-2′-propyl-1H,3′H-2,5′-bibenzo[d]imidazole (DPBI) against mild steel corrosion in 1 M HCl solutions was evaluated using the conventional mass loss method, potentiodynamic polarization, linear polarization, and electrochemical impedance spectroscopy. The mass loss results showed that DPBI is an excellent corrosion inhibitor; electrochemical polarizations data revealed the mixed mode of inhibition; and the results of electrochemical impedance spectroscopy showed that the change in the impedance parameters, charge transfer resistance, and double layer capacitance with the change in the concentration of the inhibitor is due to the adsorption of the molecule leading to the formation of a protective layer on the surface of mild steel. The inhibition action of this compound was assumed to occur via adsorption on the steel surface through the active centers of the molecule.

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