scholarly journals Biocrude Production through Pyrolysis of Used Tyres

2014 ◽  
Vol 2014 ◽  
pp. 1-9 ◽  
Author(s):  
Julius I. Osayi ◽  
Sunny Iyuke ◽  
Samuel E. Ogbeide

A review of the pyrolysis process of used tyre as a method of producing an alternative energy source is presented in this paper. The study reports the characteristics of used tyre materials and methods of recycling, types and principles of pyrolysis, the pyrolysis products and their composition, effects of process parameters, and kinetic models applied to pyrolysis. From publications, the proximate analysis of tyre rubber shows that it is composed of about 28.6 wt.% fixed carbon, 62 wt.% volatile material, 8.5 wt.% ash, and 0.9 wt.% moisture. Elemental analysis reveals that tyre rubber has an estimated value of 82 wt.% of C, 8 wt.% of H, 0.4 wt.% of N, 1.3 wt.% of S, 2.4 wt.% of O, and 5.9 wt.% of ash. Thermogravimetry analysis confirms that the pyrolysis of used tyre at atmospheric pressure commences at 250°C and completes at 550°C. The three primary products obtained from used tyre pyrolysis are solid residue (around 36 wt.%), liquid fraction or biocrude (around 55 wt.%), and gas fraction (around 9 wt.%). Although there is variation in the value of kinetic parameters obtained by different authors from the kinetic modeling of used tyre, the process is generally accepted as a first order reaction based on Arrhenius theory.

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Janduir Egito da Silva ◽  
Guilherme Quintela Calixto ◽  
Rodolfo Luiz Bezerra de Araújo Medeiros ◽  
Marcus Antônio de Freitas Melo ◽  
Dulce Maria de Araújo Melo ◽  
...  

AbstractThis study aims to analyze the products of the catalytic pyrolysis of naturally colored cotton residues, type BRS (seeds from Brazil), called BRS-Verde, BRS-Rubi, BRS-Topázio and BRS-Jade. The energy characterization of biomass was evaluated through ultimate and proximate analysis, higher heating value, cellulose, hemicellulose and lignin content, thermogravimetric analysis and apparent density. Analytical pyrolysis was performed at 500 °C in an analytical pyrolyzer from CDS Analytical connected to a gas chromatograph coupled to the mass spectrometer (GC/MS). The pyrolysis vapors were reformed at 300 and 500 °C through thermal and catalytic cracking with zeolites (ZSM-5 and HZSM-5). It has been noticed that pyrolysis vapor reforming at 500 °C promoted partial deoxygenation and cracking reactions, while the catalytic reforming showed better results for the product deoxygenation. The catalyst reforming of pyrolysis products, especially using HZSM-5 at 500 °C, promoted the formation of monoaromatics such as benzene, toluene, xylene and styrene, which are important precursors of polymers, solvents and biofuels. The main influence on the yields of these aromatic products is due to the catalytic activity of ZSM-5 favored by increased temperature that promotes cracking reactions due expanded zeolites channels.


2019 ◽  
Vol 6 (1) ◽  
pp. 1
Author(s):  
Ida Febriana ◽  
Zurohaina Zurohaina ◽  
Sahrul Effendy

Charcoal briquettes are smokeless fuels which are a type of solid fuel whose fly substance is made low enough so that the smoke generated on its utilization will not interfere with health. In this study charcoal briquettes were made from bintaro shell waste and betung bamboo using tapioca flour adhesives. This study aims to obtain the best quality sub-bituminous coal briquettes and coal briquettes. In this study the carbonization temperature used was 400ᵒC and the composition of raw materials for bintaro shells and betung bamboo was 50:50, the composition of raw materials for sub-bituminous coal and straw 90:10. The method used in this research is experiment or experimental method, with fuel value collection using ASTM D5865-03 standard. The results obtained from this study are for charcoal briquettes with 4000C carbonization temperature Inherent Moisture value of 1.91%, ash 2.29%, volatile matter 23.79%, fixed carbon 72.01% and calorific value 5878.7 kal / gr, and for coal briquettes obtained value Inherent Moisture 0.52%, ash 4.42%, volatile matter 17.98%, fixed carbon 77.08% and calorific value 7152.6 kal / gr. The fuel value of coal briquettes is greater than that of charcoal briquettes, but the combustion value of charcoal briquettes includes a good calorific value as an alternative energy source, and is in accordance with the SNI standard of 5000 kal / gr, even close to the Japanese standard 6000 cal / gr. Keywords: Bintaro, briquette, calorific value


2020 ◽  
Vol 56 (1-2) ◽  
pp. 42-47
Author(s):  
D. V. Gvozdyakov ◽  
V. E. Gubin ◽  
K. B. Larionov ◽  
A. V. Zenkov

1971 ◽  
Vol 93 (4) ◽  
pp. 594-602
Author(s):  
P. N. Shankar

The handling of changes of phase in perturbation treatments of two-phase nozzle flow requires particular care. Droplet solidification, the phase change considered here, introduces two novel complications in a perturbation treatment of the problem. First, the boundaries of the zone of solidification are shifted by first-order corrections to the droplet temperature and liquid fraction, and these shifts introduce, in turn, further first-order corrections. This feedback effect is of particular interest and the magnitudes of the corrections are very significant. Second, a singular perturbation procedure is required to handle the problem at points where solidification first starts and where it is completed. The techniques presented here should be applicable to other problems involving phase change in two-phase flow.


2021 ◽  
Author(s):  
Yuliana Rodriguez Lamar ◽  
José Noboa ◽  
Andrés S. Torres Miranda ◽  
Daniela Almeida Streitwieser

Abstract The inappropriate disposal of plastic waste cause serious environmental problems. Nowadays, alternative processes are being studied for the sustainable reutilization of plastics. One of these options is the cracking into shorter liquid hydrocarbon fractions, while maintaining its basic chemical structure. The energetic potential from the original plastics structure remains and the fractions can be used as fuels and chemical precursors. This research addresses the kinetic study of thermal cracking of polypropylene (PP) and high- and low-density polyethylene (HDPE and LDPE) in a batch reactor. The kinetics of the reaction can be described as a first-order rate with the lowest activation energy using PP, followed by HDPE and LDPE with values of 367.28 kJ/mol, 453.37 kJ/mol and 457.96 kJ/mol, respectively. The yield obtained for the liquid fraction is highest for LDPE, with a value of 72% at 390°C, followed by HDPE and LDPE with 69% and 62% at 375°C. The liquid fractions obtained from the process were characterized according to ASTM standards, obtaining that LDPE and HDPE fractions have similar properties to diesel, while PP is closer to gasoline. The fractions were also analyzed by means of gas chromatography identifying the main products of the reaction and establishing a possible reaction mechanism.


2021 ◽  
Vol 22 (2) ◽  
pp. 10-20
Author(s):  
Amadou Dioulde Donghol Diallo ◽  
Ma’an Fahmi Rashid Alkhatib ◽  
Md Zahangir Alam ◽  
Maizirwan Mel

Empty fruit bunch (EFB), a biomass-based waste, was deemed a potential replacement for fossil fuel. It is renewable and carbon neutral. The efficient management of this potential energy will help to deal with the problem associated with fossil fuels. However, a key parameter for evaluating the quality of raw material (EFB) as a fuel in energy applications is the calorific value (CV). When this CV is low, then its potential utilization as feedstock will be restricted. To tackle this shortcoming, we propose to add municipal solid waste to enhance energetic value. Thus, two major issues will be solved: managing solid residues and contributing an alternative energy source. This study aimed to investigate the possibility of mixing EFB and municipal solid waste (MSW) to make clean energy that is conscious of the environment (climate change) and sustainable development. The selected MSW, comprising of plastics, textiles, foam, and cardboard, were mixed, with EFB at various ratios. Proximate analysis was used to determine moisture content, ash, volatiles, and fixed carbon, whilst elemental analysis, is used to determine CHNS/O for MSW, EFB and their various mixtures. The CV of each element was also measured. The research revealed a significant increase in the calorific value of EFB by mixing it with MSW according to MSW/EFB ratios: 0.25; 0.42; 0.66; 1.00 and 1.50 the corresponding calorific values in (MJ/kg) were 19.77; 21.22; 22.67; 27.04 and 28.47 respectively. While the calorific value of pure EFB was 16.86 MJ/kg, the mixing of EFB with MSW promoted the increase in the CV of EFB to an average of 23.83MJ/kg. Another potential environmental benefit of applying this likely fuel was the low chlorine (0.21 wt. % to 0.95 wt. %) and sulfur concentrations (0.041 wt. % to 0.078 wt.%). This potential fuel could be used as solid refuse fuel (SRF) or refuse-derived fuel (RDF) in a pyrolysis or gasification process with little to no environmental effects. ABSTRAK: Tandan buah kosong (EFB), sisa berasaskan biojisim, adalah berpotensi sebagai pengganti bahan bakar fosil. Ia boleh diperbaharui dan karbon neutral. Pengurusan berkesan pada potensi tenaga ini dapat membantu mengatasi masalah melibatkan bahan bakar fosil. Namun, kunci parameter bagi menilai kualiti bahan mentah (EFB) sebagai bahan bakar dalam aplikasi tenaga adalah nilai kalori (CV). Apabila CV rendah, potensi menjadi stok suapan adalah terhad. Sebagai penyelesaian, kajian ini mencadangkan sisa pepejal bandaran ditambah bagi meningkatkan nilai tenaga. Oleh itu, dua isu besar dapat diselesaikan: mengurus sisa pepejal dan menambah sumber tenaga alternatif. Kajian ini bertujuan mengkaji potensi campuran tandan buah kosong (EFB) dan sisa pepejal bandaran (MSW) bagi menghasilkan tenaga bersih dari sudut persekitaran (perubahan iklim) dan pembangunan lestari. Pemilihan MSW, terdiri daripada plastik, tekstil, gabus dan kadbod, dicampurlan dengan pelbagai nisbah EFB. Analisis proksimat telah digunakan bagi mendapatkan  kandungan kelembapan, abu, ruapan, dan karbon tetap, manakala analisis asas telah digunakan bagi mendapatkan CHNS/O bersama MSW, EFB dan pelbagai campuran lain. Nilai kalori (CV) setiap elemen turut diukur. Dapatan kajian menunjukkan penambahan ketara dalam nilai kalori EFB dengan campuran bersama MSW berdasarkan nisbah MSW/EFB 0.25; 0.42; 0.66; 1.00 dan 1.50 nilai kalori sepadan (MJ/kg) adalah 19.77; 21.22; 22.67; 27.04 dan 28.47 masing-masing. Manakala nilai kalori EFB tulen adalah 16.86 MJ/kg, campuran EFB dan MSW menunjukkan kenaikan CV dengan EFB pada purata 23.83MJ/kg. Antara potensi semula jadi lain adalah dengan mencampurkan bahan bakar ini dengan kalori rendah (0.21 wt. % kepada 0.95 wt. %) dan kepekatan sulfur (0.041 wt. % kepada 0.078 wt.%). Bahan bakar ini berpotensi sebagai bahan bakar pepejal sampah (SRF) atau bahan bakar yang terhasil dari pepejal sampah (RDF) melalui proses pirolisis atau proses gasifikasi yang sedikit atau tiada kesan langsung terhadap persekitaran.


2020 ◽  
Vol 10 (2) ◽  
pp. 17-22
Author(s):  
Alpian ◽  
Raynold Panjaitan ◽  
Adi Jaya ◽  
Yanciluk ◽  
Wahyu Supriyati ◽  
...  

Charcoal briquettes can be an alternative energy and can be produced from Gerunggang and Tumih types of wood. These two types of wood are commonly found in Kalampangan Village as pioneer plants on burned peatlands. The research objective was to determine the chemical properties of charcoal briquettes produced from biomass waste from land processing without burning with several compositions of Gerunggang wood and Tumih wood. The chemical properties of charcoal briquettes refer to the Indonesian National Standard (SNI 01-6235-2000) and Standard Permen ESDM No. 047 of 2006. The results showed that all composition treatments in the ash content test, fixed carbon content and calorific value met the standards, while the test for volatile content in all treatment compositions did not meet the Indonesian National Standard (SNI 01-6235-2000). The composition of the most potential chemical properties and following the two standards used is the composition of 100% Tumih with ash content of 7.67%, volatile matter content of 27.23%, fixed carbon of 55.00%, and heating value of 5902.18 cal/g.


2015 ◽  
Vol 10 (1) ◽  
pp. 343-349 ◽  
Author(s):  
Dobariya Umesh ◽  
P Sarsavadiya ◽  
Krishna Vaja ◽  
Khardiwar Mahadeo

The study was undertaken to investigate the properties of cotton stalk fuel from the agricultural residues. The whole cotton stalk plant is converted into shredded material with the help of cotton stalk shredder. The capacity of cotton stalk shredder machine is 218 kg/h. The proximate analysis of the shredded cotton stalk in terms of bulk density 34.92 kg / m3 moisture content 13.63 %, volatile matter 74.52 %, ash content (4.95 %, fixed carbon 20.53 % and calorific value of cotton stalk biomass (3827 cal/g) respectively. were showed that agricultural residues are the most potential and their quantitative availability, Since the aim by using shredded cotton stalk as feed stock for energy conversion process of the developed gasifier.


2021 ◽  
Vol 4 (2) ◽  
pp. 133-137
Author(s):  
Muhammad Iqbal Ahmad ◽  
Mohd Sukhairi Mat Rasat ◽  
Shahril Nizam Mohamed Soid ◽  
Mazlan Mohamed ◽  
Zairi Ismael Rizman ◽  
...  

In this study, torrefaction via microwave irradiation was introduced towards oil palm empty fruit bunches (EFB) samples. The samples of 10 g was fed into the quartz type crucible inside the microwave with the power input limit to 385 W. Continous nitrogen up to 50 ml/min were induced and promoted the non oxidative atmosphere in the closed crucible. This proved the increased of energy properties as high 23.6 MJ/kg for torrefied samples comparable to raw 14.8 MJ/kg. On the result of proximate analysis, fixed carbon shows the increase trends whereby the volatile matter decreased. Torrefaction has been found to improve the energy properties of oil palm EFB biomass as a fuel.


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