scholarly journals Regioselective Thiocyanation of Aromatic and Heteroaromatic Compounds by Using Boron Sulfonic Acid as a New, Efficient, and Cheap Catalyst in Water

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Sami Sajjadifar ◽  
Omid Louie
Keyword(s):  
Sulfonic Acid ◽  
Aqueous Media ◽  
Environmentally Friendly ◽  
Heteroaromatic Compounds ◽  
Highly Efficient ◽  
Simple Protocol

Highly efficient regioselective thiocyanations of indoles andN,N-disubstituted anilines are achieved via a green and simple protocol using boron sulfonic acid (BSA) as a new catalyst and KSCN/H2O2as a mild and environmentally friendly oxidant in aqueous media.

Environmentally friendly and highly efficient synthesis of benzoxazepine and malonamide derivatives using HPA/TPI-Fe3 O4 nanoparticles as recoverable catalyst in aqueous media

2016 ◽  
Vol 31 (5) ◽  
pp. e3603 ◽  
Author(s):  
Esmail Vessally ◽  
Rahim Hosseinzadeh-Khanmiri ◽  
Mirzaagha Babazadeh ◽  
Ebrahim Ghorbani-Kalhor ◽  
Ladan Edjlali
Keyword(s):  
Aqueous Media ◽  
Environmentally Friendly ◽  
Efficient Synthesis ◽  
Highly Efficient ◽  
Recoverable Catalyst

Highly efficient and selective photocatalytic CO2 to CO conversion in aqueous solution

2020 ◽  
Vol 56 (27) ◽  
pp. 3851-3854 ◽  
Author(s):  
Xiaomin Chai ◽  
Hai-Hua Huang ◽  
Huiping Liu ◽  
Zhuofeng Ke ◽  
Wen-Wen Yong ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Photocatalytic Performance ◽  
Aqueous Media ◽  
Highly Efficient ◽  
Co Conversion

A Co-based complex displayed the highest photocatalytic performance for CO2 to CO conversion in aqueous media.

Catalytic asymmetric hydrogenation reaction by in situ formed ultra-fine metal nanoparticles in live thermophilic hydrogen-producing bacteria

Nanoscale ◽  
2021 ◽  
Author(s):  
Wei Bing ◽  
Faming Wang ◽  
Yuhuan Sun ◽  
Jinsong Ren ◽  
Xiaogang Qu
Keyword(s):  
Metal Nanoparticles ◽  
Catalytic Hydrogenation ◽  
Asymmetric Hydrogenation ◽  
Environmentally Friendly ◽  
Hydrogenation Reaction ◽  
Highly Efficient ◽  
Hydrogenation Reactions ◽  
Live Bacteria ◽  
Catalytic Asymmetric Hydrogenation

An environmentally friendly biomimetic strategy has been presented and validated for the catalytic hydrogenation reaction in live bacteria. In situ formed ultra-fine metal nanoparticles can realize highly efficient asymmetric hydrogenation reactions.

scholarly journals Highly efficient reusable superhydrophobic sponge prepared by a facile, simple and cost effective biomimetic bonding method for oil absorption

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jiaqi Wang ◽  
Yan Chen ◽  
Qinyao Xu ◽  
Miaomiao Cai ◽  
Qian Shi ◽  
...  
Keyword(s):  
Environmentally Friendly ◽  
Absorption Capacity ◽  
Oil Absorption ◽  
Water Contact ◽  
Water Separation ◽  
Highly Efficient ◽  
Study Results ◽  
Different Types ◽  
Modification Method ◽  
Bonding Method

AbstractSuperhydrophobic sponges have considerable potential for oil/water separation. Most of the methods used for superhydrophobic modification of sponges require toxic or harmful solvents, which have the drawbacks of hazardous to environment, expensive, and complex to utilize. Moreover, the hydrophobic layer on the surface of sponge is often easily destroyed. In this paper, a highly efficient superhydrophobic sponge with excellent reusability was developed by using a facile, simple and environmentally friendly dopamine biomimetic bonding method. Different types of sponges, such as melamine, polyethylene or polyurethane sponge wastes, were used as raw materials to prepare superhydrophobic sponges, which possess the advantages of inexpensive and abundant. The effects of different dopamine polymerization time and different hydrophobic agent dosage on the hydrophobicity and oil absorption capacity of melamine sponges were optimized. The study results showed that the water contact angle of the superhydrophobic sponge could reach 153° with excellent organic solvent absorption capacity of 165.9 g/g. Furthermore, the superhydrophobic sponge retained approximately 92.1% of its initial absorption capacity after 35 reutilization cycles. More importantly, the dopamine biomimetic bonding superhydrophobic modification method can be used for different types of sponges. Therefore, a universally applicable, facile, simple and environmentally friendly superhydrophobic modification method for sponges was developed.

scholarly journals Mo@GAA-Fe3O4 MNPs: a highly efficient and environmentally friendly heterogeneous magnetic nanocatalyst for the synthesis of polyhydroquinoline derivatives

RSC Advances ◽  
2021 ◽  
Vol 11 (18) ◽  
pp. 10497-10511
Author(s):  
Mehraneh Aghaei-Hashjin ◽  
Asieh Yahyazadeh ◽  
Esmayeel Abbaspour-Gilandeh
Keyword(s):  
Ethyl Acetoacetate ◽  
Ammonium Acetate ◽  
Environmentally Friendly ◽  
Magnetic Nanocatalyst ◽  
Methyl Acetoacetate ◽  
Highly Efficient ◽  
Fe3o4 Mnps

Polyhydroquinolines were obtained from a sequential four-component reaction between dimedone or 1,3-cyclohexandione, ethyl acetoacetate, or methyl acetoacetate as a β-ketoester, aldehydes, and ammonium acetate, with Mo@GAA-Fe3O4 MNPs as a green nanocatalyst.

ChemInform Abstract: Sulfonates of N-Triazinylammonium Salts as Highly Efficient, Inexpensive and Environmentally Friendly Coupling Reagents for Peptide Synthesis

ChemInform ◽  
2008 ◽  
Vol 39 (28) ◽  
Author(s):  
Beata Kolesinska ◽  
Justyna Fraczyk ◽  
Giuseppina Sabatino ◽  
Anna M. Papini ◽  
Zbigniew J. Kaminski
Keyword(s):  
Peptide Synthesis ◽  
Environmentally Friendly ◽  
Coupling Reagents ◽  
Highly Efficient

scholarly journals DABCO Catalyzed Synthesis of Xanthene Derivatives in Aqueous Media

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Pradeep Paliwal ◽  
Srinivasa Rao Jetti ◽  
Anjna Bhatewara ◽  
Tanuja Kadre ◽  
Shubha Jain
Keyword(s):  
Reaction Time ◽  
Aqueous Media ◽  
Environmentally Friendly ◽  
The Other ◽  
Short Reaction Time ◽  
Xanthene Derivatives ◽  
Reaction Proceeds ◽  
Conventional Methods

The reaction of 5,5-dimethylcyclohexane-1,3-dione with various heteroarylaldehydes afforded the corresponding heteroaryl substituted xanthene derivatives 1(a–f). The reaction proceeds via the initial Knoevenagel, subsequent Michael, and final heterocyclization reactions using 1,4-diazabicyclo[2.2.2]octane (DABCO) as a catalyst in aqueous media. The synthesized heteroaryl substituted xanthenes 1(a–f) reacted with malononitrile to obtain different alkylidenes 2(a–f). Short reaction time, environmentally friendly procedure, avoiding of cumbersome apparatus, and excellent yields are the main advantages of this procedure which makes it more economic than the other conventional methods.

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