scholarly journals Characterisation of Used PP-Based Car Bumpers and Their Recycling Properties

2013 ◽  
Vol 2013 ◽  
pp. 1-12 ◽  
Author(s):  
M. P. Luda ◽  
V. Brunella ◽  
D. Guaratto
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Impact Resistance ◽  
Dynamic Mechanical Properties ◽  
Speed Test ◽  
The Matrix ◽  
Internal Mixer ◽  
Mineral Fillers ◽  
The Impact

Three used PP-based car bumpers are characterized by many techniques (fractionation, IR, TGA, DSC, DMTA, and SEM). They show different impact and static and dynamic mechanical properties depending on their composition and morphology. It appears that block copolymer compatibilizers constituted by polyethylene-polypropylene sequences allow a better compatibility between the rubber domains and the PP matrix leading to relatively high impact resistance. Indeed if the ethylene sequences of the copolymer are large enough to crystallize, the decreased mobility of the whole system impairs the impact resistance. In addition, a higher amount of rubber in domains regular in shape and of greater dimension (1–3 μm) promotes a more homogeneous dispersion of external force inside the material, decreasing the risk of fracture. The amount of mineral fillers regulates the elastic modulus (the higher the load, the higher the modulus); however, a fairly good interfacial adhesion is required for satisfactory impact strength. All PP-based bumpers have been mechanically recycled in an internal mixer to redistribute oxidized species and to reestablish phase compatibilization. Recycling improves mechanical properties in slow speed test but fails to increase impact strength particularly in filled bumper, in which the quality of the matrix/filler interphase is hard to improve by simple remixing.

scholarly journals Effect of Mineral Fillers on the Mechanical Properties of Commercially Available Biodegradable Polymers

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 394
Author(s):  
Wouter Post ◽  
Lambertus J. Kuijpers ◽  
Martin Zijlstra ◽  
Maarten van der Zee ◽  
Karin Molenveld
Keyword(s):  
Mechanical Properties ◽  
Biodegradable Polymers ◽  
Plastic Material ◽  
Impact Resistance ◽  
Plastic Materials ◽  
The Matrix ◽  
Polybutylene Succinate ◽  
Mineral Fillers ◽  
The Impact ◽  
Plastic Products

In the successful transition towards a circular materials economy, the implementation of biobased and biodegradable plastics is a major prerequisite. To prevent the accumulation of plastic material in the open environment, plastic products should be both recyclable and biodegradable. Research and development actions in the past few decades have led to the commercial availability of a number of polymers that fulfil both end-of-life routes. However, these biobased and biodegradable polymers typically have mechanical properties that are not on par with the non-biodegradable plastic products they intend to replace. This can be improved using particulate mineral fillers such as talc, calcium carbonate, kaolin, and mica. This study shows that composites thereof with polybutylene succinate (PBS), polyhydroxybutyrate-hexanoate (PHBH), polybutylene succinate adipate (PBSA), and polybutylene adipate terephthalate (PBAT) as matrix polymers result in plastic materials with mechanical properties ranging from tough elastic towards strong and rigid. It is demonstrated that the balance between the Young’s modulus and the impact resistance for this set of polymer composites is subtle, but a select number of investigated compositions yield a combination of industrially relevant mechanical characteristics. Finally, it is shown that the inclusion of mineral fillers into biodegradable polymers does not negate the microbial disintegration of these polymers, although the nature of the filler does affect the biodegradation rate of the matrix polymer.

Mechanical properties of unidirectional aligned bagasse fibers/vinyl ester composite

2016 ◽  
Vol 36 (2) ◽  
pp. 157-163 ◽  
Author(s):  
Ayyanar Athijayamani ◽  
Balasubramaniam Stalin ◽  
Susaiyappan Sidhardhan ◽  
Azeez Batcha Alavudeen
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Impact Strength ◽  
Vinyl Ester ◽  
Flexural Modulus ◽  
Tensile Modulus ◽  
Short Beam ◽  
Beam Shear ◽  
The Matrix ◽  
The Impact

Abstract The present study describes the preparation of aligned unidirectional bagasse fiber-reinforced vinyl ester (BFRVE) composites and their mechanical properties such as tensile, flexural, shear and impact strength. Composites were prepared by a hand lay-up technique developed in our laboratory with the help of a hot press. Mechanical properties were obtained for different fiber contents by varying the number of layers. The obtained tensile property values were compared with the theoretical results. The results show that the tensile strength increased linearly up to 44 wt% and then dropped. However, the tensile modulus increased linearly from 17 wt% to 60 wt%. In the case of flexural properties, the flexural strength increased up to 53 wt% and started to decrease. However, the flexural modulus also increased linearly up to 60 wt%. The impact strength values were higher than the matrix materials for all the specimens. The short beam shear strength values were also increased up to 53 wt% and then dropped. The modified Bowyer and Bader (MBB) model followed by the Hirsch model shows a very good agreement with experimental results in both tensile strength and modulus.

Study on Application of Modified Polyethylene in Preparation of Wood-Plastic Composites

2010 ◽  
Vol 150-151 ◽  
pp. 379-385
Author(s):  
Qun Lü ◽  
Qing Feng Zhang ◽  
Hai Ke Feng ◽  
Guo Qiao Lai
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Impact Strength ◽  
Flexural Strength ◽  
High Density Polyethylene ◽  
Wood Flour ◽  
Wood Plastic Composites ◽  
Plastic Composites ◽  
The Matrix ◽  
The Impact

The wood-plastic composites (WPC) were prepared via compress molding by using the blends of high density polyethylene (HDPE) and modified polyethylene (MAPE) as the matrix and wood flour (WF) as filler. The effect of MAPE content in the matrix on the mechanical properties of the matrix and WPC was investigated. It was shown that the change of MAPE content in the matrix had no influence on the tensile strength of the matrix, but markedly reduced the impact strength of the matrix. Additionally, it had significant influence on the strength of WPC. When the content of wood flour and the content of the matrix remained fixed, with increasing the content of MAPE in the matrix, the tensile strength and the flexural strength of WPC tended to increase rapidly initially and then become steady. Moreover, with the increasing of MAPE concentration, the impact strength of WPC decreased when the low content of wood flour (30%) was filled, but increased at high wood flour loading (70%).

scholarly journals Plasticization of Polylactide with Myrcene and Limonene as Bio-Based Plasticizers: Conventional vs. Reactive Extrusion

Polymers ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1363 ◽  
Author(s):  
Berit Brüster ◽  
Yann-Olivier Adjoua ◽  
Reiner Dieden ◽  
Patrick Grysan ◽  
Carlos Eloy Federico ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Impact Strength ◽  
Reactive Extrusion ◽  
The Matrix ◽  
Reactive Blend ◽  
The Impact ◽  
Inclusion Matrix

Polylactide (PLA) was blended by conventional and reactive extrusion with limonene (LM) or myrcene (My) as bio-based plasticizers. As-processed blends were carefully analyzed by a multiscale and multidisciplinary approach to tentatively determine their chemical structure, microstructure, thermal properties, tensile and impact behaviors, and hydrothermal stability. The main results indicated that LM and My were efficient plasticizers for PLA, since compared to neat PLA, the glass transition temperature was reduced, the ultimate tensile strain was increased, and the impact strength was increased, independently of the type of extrusion. The addition of a free radical initiator during the extrusion of PLA/LM was beneficial for the mechanical properties. Indeed, the probable formation of local branched/crosslinked regions in the PLA matrix enhanced the matrix crystallinity, the tensile yield stress, and the tensile ultimate stress compared to the non-reactive blend PLA/LM, while the other properties were retained. For PLA/My blends, reactive extrusion was detrimental for the mechanical properties since My polymerization was accelerated resulting in a drop of the tensile ultimate strain and impact strength, and an increase of the glass transition temperature. Indeed, large inclusions of polymerized My were formed, decreasing the available content of My for the plasticization and enhancing cavitation from inclusion-matrix debonding.

scholarly journals MECHANICAL PROPERTIES OF THE VIET NAM SISAL FIBRE REINFORCED POLYPROPYLENE COMPOSITE

2011 ◽  
Vol 14 (2) ◽  
pp. 29-36
Author(s):  
Nieu Huu Nguyen ◽  
Binh Thanh Phan ◽  
Sau Huynh
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Loss Modulus ◽  
Flexural Modulus ◽  
Dynamic Mechanical Properties ◽  
Sisal Fiber ◽  
Sisal Fibre ◽  
Dynamic Mechanical ◽  
Sisal Fibers ◽  
The Impact

The static mechanical and dynamic mechanical properties of the treated sisal fiber reinforced polypropylene composites were improved by adding the compatiblizer PPgMA (polypropylene-grafted-maleic anghydride). The mechanical properties of the composites have been evaluated. By increasing PPgMA dosages from 2% and 3.5% by weight of PP matrix; the impact strength of the composites were significantly improved by 27% and 38%; the elongation increased by 21% and 36%; the tensile strength increased by 35% and 95%; the elastic modulus increased by 21% and 94% and the flexural modulus increased by 2% and 83% respectively. The dynamic mechanical properties (the storage modulus E’, the loss modulus E” and the loss factor tanδ) have been investigated in relation to the compatibility between the PP matrix and the treated sisal fibers. E’ and E” increased by increasing dosage of PPgMA and Tg decreased a little when increasing the contents of PPgMA. At higher temperatures, tanδ increased and at lower temperature tanδ decreased when increasing dosage of PPgMA. It is shown that PP/treated sisal fibers/PPgMA composites have shown the effects of cohesion when increasing the PPgMA. The fiber dispersion was studied by the transmission optical microscope (TOM). The morphology of the composites samples fractured by the impact strength tests have been studied using scanning electronic microscopy (SEM). The results show the improvement of the interaction forces between treated sisal fibers and PP matrix at higher levels of PPgMA.

THE INFLUENCE BREEDING ON THE MECHANICAL PROPERTIES OF THE HOOF HORN IN CZECH WARMBLOOD HORSES

2015 ◽  
Author(s):  
Petr VALÁŠEK ◽  
Miroslav MÜLLER ◽  
Michaela JAMELSKÁ
Keyword(s):  
Mechanical Properties ◽  
Wear Resistance ◽  
Impact Strength ◽  
Impact Resistance ◽  
Biological Materials ◽  
Inorganic Polymers ◽  
Significant Difference ◽  
The Impact

The aim of this experiment was to compare the mechanical properties of the hoof horn of horses, mainly Czech warmblood, in relation to their stabling conditions – explicitly, grazing farming (pasture) with deep bedding stables. The sampling of the hoof horn was always made after a change of the horse´s stabling method. This paper assesses the changes in some mechanical properties of the hoof as a result of changes in their stabling environment. Moreover, the hardness, the wear resistance and the impact resistance of the hoof horn was evaluated. The results of the experiment showed a statistically significant difference between the studied mechanical properties of the hoof horn and the compared stabling conditions. Conducting the experiment led to a new methodology for evaluating the mechanical properties of biological materials coming from polymeric testing. The experiment describes a possible methodology for testing biological materials based on the evaluation of the mechanical properties of inorganic polymers. An effect of the influence stabling environment has to the hardness and the impact strength of the hoof horn was confirmed. An effect of the influence stabling environment has on hoof´s resistance against abrasiveness was not confirmed.

Quality of surface finish on furniture doors of MDF board

2019 ◽  
Vol 105 ◽  
pp. 102-106
Author(s):  
GABRIELA SLABEJOVÁ ◽  
MÁRIA ŠMIDRIAKOVÁ ◽  
IVAN VOZAF
Keyword(s):  
Mechanical Properties ◽  
Surface Finish ◽  
Impact Resistance ◽  
Physical And Mechanical Properties ◽  
Coating Material ◽  
Film Hardness ◽  
The Impact

Quality of Surface Finish on Furniture Doors of MDF Board. The paper deals with the assessment of the quality of furniture door surface. The properties were tested on the following types of the surface finish on MDF doors: PVC foil (glossy and matt), acrylic foil, and PUR pigmented coating material. The following physical and mechanical properties of the surfaces were assessed: the film hardness, the impact resistance, and the resistance against scuffing. The polyurethane surface finish and the glossy PVC foil achieved the same film hardness. The impact resistance of the polyurethane finish was significantly lower than the impact resistance of the PVC foils and the acrylic foil. The resistance against scuffing was lower for the polyurethane finish if compared to the foiled surfaces.

SHPB Dynamic Experiment on Silica Fume Concrete

2013 ◽  
Vol 631-632 ◽  
pp. 771-775 ◽  
Author(s):  
Rong Jun Chen ◽  
Hong Wei Liu ◽  
Rui Zeng
Keyword(s):  
Mechanical Properties ◽  
Strain Rate ◽  
Silica Fume ◽  
High Speed ◽  
Split Hopkinson Pressure Bar ◽  
Dynamic Compression ◽  
Impact Resistance ◽  
Dynamic Mechanical Properties ◽  
Hopkinson Pressure Bar ◽  
The Impact

Dynamic mechanical properties of silica fume concrete in a number of strain rate under the conditions of dynamic compression mechanical properties subjected to various strain rates were studied, and gained the stress versus strain curves, details of an experimental investigation using 74 mm-diameter split Hopkinson pressure bar(SHPB) apparatus were presented. The results showed that: The admixture of silica fume concrete impact resistance, especially under the impact of the performance of high-speed has a very important influence, with the impact velocity increased, the strain rate increase, and its impact more obvious.

Mechanical Properties and Phase Morphology of Poly(Lactic Acid)/Acrylonitrile-Butadiene Rubber/Organoclay Nanocomposites Prepared by Melt Blending

2018 ◽  
Vol 775 ◽  
pp. 13-19
Author(s):  
Sirirat Wacharawichanant ◽  
Kasana Chomphunoi ◽  
Chawisa Wisuttrakarn ◽  
Manop Phankokkruad
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
Impact Strength ◽  
Phase Morphology ◽  
Poly Lactic Acid ◽  
Butadiene Rubber ◽  
Melt Blending ◽  
Acrylonitrile Butadiene Rubber ◽  
Internal Mixer ◽  
The Impact

This work investigated the mechanical properties and phase morphology of poly(lactic acid) (PLA)/acrylonitrile-butadiene rubber (NBR) blends and nanocomposites, which prepared by melt blending in an internal mixer. The contents of NBR were 5, 10, 15 and 20 wt% and the content of organoclay was 3 phr. The impact test showed that the impact strength of PLA/NBR blends increased with an increase of NBR content and the impact strength of the blends was more than eight times by adding NBR 10 wt% when compared with neat PLA. The tensile test showed that Young’s modulus and tensile strength of PLA/NBR blends and nanocomposites decreased after adding NBR and organoclay. While the strain at break of the NBR blends increased with increasing NBR content. This result is attributed to the rubber phase in NBR in a cause the increment of elongation and elasticity in PLA/NBR blends. The morphology of PLA/NBR blends observed the fractured surface was rougher than that of pure PLA. This observation indicates that the addition of NBR in PLA can change the brittle fracture of PLA to ductile fracture, which has an effect to the strain at break or elongation of PLA. However, the morphology of the PLA/NBR blends were also observed the phase separation of the dispersed NBR phase and PLA matrix phase, and appeared the voids in a polymer matrix. The addition of organoclay had an effect slightly on the morphology of the blends. From X-ray diffraction, results found that PLA/organoclay and PLA/NBR/organoclay nanocomposites showed the intercalated structure, which PLA chains were inserted into the interlayer of clay due to the increase of d-spacing.

Effect of combined drink cans and steel fibers on the impact resistance and mechanical properties of concrete

2020 ◽  
Vol 14 (2) ◽  
pp. 6734-6742
Author(s):  
A. Syamsir ◽  
S. M. Mubin ◽  
N. M. Nor ◽  
V. Anggraini ◽  
S. Nagappan ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Compressive Strength ◽  
Reinforced Concrete ◽  
Impact Resistance ◽  
Fiber Reinforced Concrete ◽  
Steel Fibers ◽  
Fiber Reinforced ◽  
Indirect Tensile ◽  
The Impact

This study investigated the combine effect of 0.2 % drink cans and steel fibers with volume fractions of 0%, 0.5%, 1%, 1.5%, 2%, 2.5% and 3% to the mechanical properties and impact resistance of concrete. Hooked-end steel fiber with 30 mm and 0.75 mm length and diameter, respectively was selected for this study.  The drinks cans fiber were twisted manually in order to increase friction between fiber and concrete. The results of the experiment showed that the combination of steel fibers and drink cans fibers improved the strength performance of concrete, especially the compressive strength, flexural strength and indirect tensile strength. The results of the experiment showed that the combination of steel fibers and drink cans fibers improved the compressive strength, flexural strength and indirect tensile strength by 2.3, 7, and 2 times as compare to batch 1, respectively. Moreover, the impact resistance of fiber reinforced concrete has increase by 7 times as compared to non-fiber concretes. Moreover, the impact resistance of fiber reinforced concrete consistently gave better results as compared to non-fiber concretes. The fiber reinforced concrete turned more ductile as the dosage of fibers was increased and ductility started to decrease slightly after optimum fiber dosage was reached. It was found that concrete with combination of 2% steel and 0.2% drink cans fibers showed the highest compressive, split tensile, flexural as well as impact strength.    

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