scholarly journals Electrochemical and Spectroscopic Characterization of Aluminium(III)-para-methyl-meso-tetraphenylporphyrin Complexes Containing Substituted Salicylates as Axial Ligands

2013 ◽  
Vol 2013 ◽  
pp. 1-10
Author(s):  
Gauri D. Bajju ◽  
Deepmala ◽  
Sunil Kumar Anand ◽  
Sujata Kundan ◽  
Narinder Singh
Keyword(s):  
Spectroscopic Characterization ◽  
Redox Properties ◽  
Proton Nuclear Magnetic Resonance ◽  
Spectroscopic Techniques ◽  
Axial Coordination ◽  
H Nmr ◽  
Axial Ligands ◽  
Reduction Mechanisms ◽  
C Nmr

A series of aluminium(III)-p-methyl-meso-tetraphenylporphyrin (p-CH3TPP-Al(III)) containing axially coordinated salicylate anion [p-CH3TPP-Al-X)], where X = salicylate (SA), 4-chlorosalicylate (4-CSA), 5-chlorosalicylate (5-CSA), 5-flourosalicylate (5-FSA), 4-aminosalicylate (4-ASA), 5-aminosalicylate (5-ASA), 5-nitrosalicylate (5-NSA), and 5-sulfosalicylate (5-SSA), have been synthesized and characterized by various spectroscopic techniques including ultraviolet-visible (UV-vis), infrared (IR) spectroscopy, proton nuclear magnetic resonance (1H NMR) spectroscopy,13C NMR, and elemental analysis. A detailed study of electrochemistry of all the synthesized compounds has been done to compare their oxidation and reduction mechanisms and to explain the effect of axial coordination on their redox properties.

Synthesis and characterization of a new (phthalocyani-nato)bis(carboxylate) silicon(IV) compound with increased solubility

2002 ◽  
Vol 06 (03) ◽  
pp. 198-202 ◽  
Author(s):  
José L. Sosa-Sánchez ◽  
Alberto Galindo ◽  
Dino Gnecco ◽  
Sylvain Bernès ◽  
George R. Fern ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Structure Determination ◽  
Spectroscopic Characterization ◽  
X Ray Diffraction ◽  
H Nmr ◽  
Axial Ligands ◽  
Nmr Characterization ◽  
Soluble Silicon ◽  
Soluble Material

The synthesis and spectroscopic characterization of a new soluble silicon(IV) phthalocyanine complex is presented. The compound shows an increased solubility compared to its SiPcCl 2 precursor and this allowed solution 1 H NMR characterization. The assignment of the 1 H NMR signals for the axial ligands is greatly facilitated due to the anisotropic high ring current effects from the macrocycle. In addition, good quality crystals were grown from this more soluble material for molecular structure determination by single-crystal X-ray diffraction analysis. The molecular structure determination shows that the complex crystallizes in a non-centrosymmetric space group due to the inherent chirality of the naproxene ligands. Bond lengths and angles fit well to other analogous compounds previously reported.

scholarly journals Synthesis and Spectroscopic Characterization of Some New Axially Ligated Indium(III) Macrocyclic Complexes and Their Biological Activities

2014 ◽  
Vol 2014 ◽  
pp. 1-7
Author(s):  
Gauri D. Bajju ◽  
Altaf Ahmed ◽  
Deepmala Gupta ◽  
Ashu Kapahi ◽  
Gita Devi
Keyword(s):  
Biological Activities ◽  
Spectroscopic Characterization ◽  
Axial Ligand ◽  
Free Base ◽  
H Nmr ◽  
Pyramidal Geometry ◽  
The Stability ◽  
Square Pyramidal Geometry ◽  
C Nmr

The synthesis and spectroscopic characterization of new axially ligated indium(III) porphyrin complexes were reported. Chloroindium(III) porphyrin (TPPIn-Cl) was obtained in good yield by treating the corresponding free base with indium trichloride. The action of the different phenols on chloroderivatives (TPPIn-Cl) led to the corresponding phenolato complexes (TPPIn-X). These derivatives were characterized on the basis of mass spectrometry,1H-NMR, IR, and UV-visible data. The separation and isolation of these derivatives have been achieved through chromatography. The spectral properties of free base porphyrin and its corresponding metallated and axially ligated indium(III) porphyrin compounds were compared with each other. A detailed analysis of UV-Vis,1H-NMR, and IR suggested the transformation from free base porphyrin to indium(III) porphyrin. Besides,13C-NMR and fluorescence spectra were also reported and interpreted. The stability of these derivatives has also been studied through thermogravimetry. The complexes were also screened for anticancerous activities. Among all the complexes, 4-MePhO-InTPP shows highest anticancerous activity. The title complexe, TPPIn-X (where X = different phenolates), represents a five-coordinate indium(III) porphyrin complex in a square-pyramidal geometry with the phenolate anion as the axial ligand.

scholarly journals Synthesis and Spectroscopic Characterization of Some New Biological Active Azo–Pyrazoline Derivatives

2012 ◽  
Vol 9 (3) ◽  
pp. 1613-1622 ◽  
Author(s):  
Farouq E. Hawaiz ◽  
Mohammad K. Samad
Keyword(s):  
Addition Reaction ◽  
Coupling Reaction ◽  
Spectroscopic Characterization ◽  
Hydroxyl Group ◽  
Significant Activity ◽  
H Nmr ◽  
Ft Ir ◽  
High Yields ◽  
C Nmr

A number of 3-[4-(benzyloxy)-3-(2-Chlorophenylazo)-phenyl]-5-(substituted-phenyl)-1-substituted-2-pyrazolines( 4a-j) and (5a-j) have been synthesized by diazotization of 2-chloroaniline and its coupling reaction with 4-hydroxy acetophenone, followed by benzyloxation of the hydroxyl group to give the substrate [4-benzyloxy-3-(2-chlorophenylazo)-acetophenone (1)].The prepared starting material (1) has been reacted with different substituted benzaldehydes to give a new series of chalcone derivatives 1-[(4-benzyloxy)-3-(2-chloro-phenylazo)-phenyl]-3-(substituted phenyl)-2-propen-1-one (3a-j), in high yields and in a few minutes, and the later compounds were treated with hydrazine hydrate according to Michael addition reaction to afford a new biolological active target compounds (4a-j) and (5a-j). Furthermore, The structures of the newly synthesized compounds were confirmed by FT-IR,13C-NMR,13C-DEPT &1H-NMR spectral data. The chalcone and pyrazoline derivatives were evaluated for their anti bacterial activity againstEscherichia colias gram negative andStaphylococcus aureusas gram positive, the results showed significant activity against both types of bacteria.

Synthesis and Characterization of Imidazo[1,2-a]Pyrimidine

2015 ◽  
Vol 52 ◽  
pp. 1-4
Author(s):  
A.M. Shah ◽  
A.J. Rojivadiya
Keyword(s):  
Mass Spectroscopy ◽  
Synthesis And Characterization ◽  
Spectroscopic Techniques ◽  
One Pot ◽  
H Nmr ◽  
Ft Ir ◽  
C Nmr

An efficient protocol for the synthesis of imidazo [1,2-a] pyrimidine was developed by using three component one-pot Biginelli synthesis. The synthesized compounds were characterized by spectroscopic techniques like FT-IR, 1H NMR, 13C NMR, and mass spectroscopy.

Formation and characterization of five- and six-coordinate iron(III) corrolazine complexes

2012 ◽  
Vol 16 (05n06) ◽  
pp. 518-529 ◽  
Author(s):  
Satoshi Kurahashi ◽  
Takahisa Ikeue ◽  
Tamotsu Sugimori ◽  
Masashi Takahashi ◽  
Masahiro Mikuriya ◽  
...  
Keyword(s):  
Ground State ◽  
Electronic Structures ◽  
Axial Ligand ◽  
Squid Magnetometry ◽  
Close Inspection ◽  
H Nmr ◽  
Axial Ligands ◽  
Excess Amount ◽  
C Nmr

Electronic structures of five- and six-coordinate iron(III) corrolazine complexes are determined by means of 1H NMR, 13C NMR, EPR, and Mössbauer spectroscopy as well as SQUID magnetometry. A series of five-coordinate complexes, [FeIII(TBP8Cz)(L)]* where the axial ligands(L) are cyanide(CN-), imidazole(HIm), 1-methylimidazole(1-MeIm), 4-(N,N-dimethylamino)pyridine(DMAP), pyridine(Py), 4-cyanopyridine(4-CNPy), and tert-butylisocyanide(tBuNC), are obtained by the addition of 1 to 2 equiv. of the ligands to the dichloromethane solutions of FeIII(TBP8Cz) at 298 K: TBP8Cz is a trianion of 2,3,7,8,12,13,17,18-octakis(4-tert-butylphenyl)corrolazine. These complexes commonly show the S = 3/2 at 298 K. By contrast, formation of the six-coordinate complexes depends on the nature of the axial ligands. While the addition of 3 equiv. of CN- has completely converted FeIII(TBP8Cz) to (Bu4N)2[FeIII(TBP8Cz)(CN)2] at 298 K, the conversion to the bis-adduct is only attained below ca. 200 K in the case of HIm, 1-MeIm, and DMAP even in the presence of 50 equiv. of the ligands. If the axial ligand is Py, 4-CNPy, or tBuNC, the formation of [FeIII(TBP8Cz)(L)2] is confirmed only at an extremely low temperature (15 K). Close inspection of the 1H NMR and EPR spectra has revealed that all the bis-adducts adopt the (dxy)2(dxz, dyz)3 ground state. While FeIII(TBP8Cz) forms paramagnetic bis- and mono-adduct in toluene solution at 298 K in the presence of excess amount of CN- and tBuNC, respectively, the corresponding porphyrazine complex, [FeIII(TBP8Pz)]Cl , forms diamagnetic bis-CN and bis-tBuNC under the same conditions: TBP8Pz is a dianion of 2,3,7,8,12,13,17,18-octakis(4-tert-butylphenyl)-porphyrazine. Thus, the iron(III) ion of porphyrazine complex is more easily reduced than that of the corresponding corrolazine complex.

scholarly journals Synthesis and Spectroscopic Characterization of l-Aspartic Acid Complexes with Metals of the Lanthanides Family

2013 ◽  
Vol 11 ◽  
pp. 91-115 ◽  
Author(s):  
Musa E. Mohamed
Keyword(s):  
Aspartic Acid ◽  
Spectroscopic Characterization ◽  
Downfield Shift ◽  
H Nmr ◽  
Lanthanide Series ◽  
Chiral Carbon ◽  
Metal Contents ◽  
Metal Effect ◽  
C Nmr

The complexes between l-aspartic acid and metals of lanthanide series (La3+, Pr3+, Eu3+, Gd3+) have been prepared and characterized using a variety of techniques including, infrared spectroscopy, 1H NMR, 13C NMR, elemental analysis and metal contents. The sought metal effect on the electronic environment of the chiral carbon and its neighbouring atoms was observed in case of Europium and Praseodymium. The 13C downfield shift indicates a lower electron density at the carbon with consequent downfield shift observed on the α-H attached to it increasing its acidity.

scholarly journals Preparation and spectroscopic studies of Fe(II), Ru(II), Pd(II) and Zn(II) complexes of Schiff base containing terephthalaldehyde and their transfer hydrogenation and Suzuki-Miyaura coupling reaction

2019 ◽  
Vol 17 (1) ◽  
pp. 571-580 ◽  
Author(s):  
Nevin Turan ◽  
Kenan Buldurun ◽  
Naki Çolak ◽  
İsmail Özdemir
Keyword(s):  
Schiff Base ◽  
Coupling Reaction ◽  
Spectroscopic Characterization ◽  
Spectroscopic Studies ◽  
Transfer Hydrogenation ◽  
Spectroscopic Techniques ◽  
Catalytic Activities ◽  
H Nmr ◽  
Optimized Conditions ◽  
C Nmr

AbstractThis study describes synthesis, spectroscopic characterization and catalytic activities of Fe(II), Ru(II), Pd(II) and Zn(II) complexes with a novel Schiff base ligand (L) derived from methyl 2-amino-5,5,7,7-tetramethyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate and terephthalaldehyde. We used spectroscopic techniques including IR, UV-Vis, 1H-NMR, 13C-NMR, elemental analysis and also mass analysis and magnetic susceptibility measurements to identify the products. The Pd(II) complex was used as a potential catalyst for Suzuki-Miyaura coupling reaction of some aryl halides under optimized conditions. The effect of various bases such as NaOH, KOH, and KOBut was investigated in transfer hydrogenation (TH) of ketones by isopropyl alcohol as the hydrogen source. Ru(II) and Pd(II) complexes showed catalytic activity while Zn(II) and Fe(II) metal complexes failed to do that.

scholarly journals Synthesis and Spectroscopic Characterization of Lead(II)bis{O,O'-ditolyldithiophosphates} and their Adducts with 2,2'-Bipyridyl and 1,10-Phenanthroline

2011 ◽  
Vol 8 (s1) ◽  
pp. S113-S118
Author(s):  
Disha Jain Alok Chaturvedi ◽  
R.K. Upadhayay
Keyword(s):  
Spectroscopic Characterization ◽  
Spectroscopic Studies ◽  
Ammonium Salts ◽  
Molar Ratio ◽  
Spectroscopic Techniques ◽  
Lead Atom ◽  
H Nmr

The reaction of lead(II) dichloride with ammonium salts ofO,O'-ditolyldithiophosphoric acid have been carried out in 1:2 molar ratio by refluxing in benzene. These compounds have been further used to synthesize the adduct of the type lead(II)bis{O,O'-ditolyldithiophosphates}.2,2'-bipyridyl and lead(II)bis {O,O'-ditolyldithiophosphates}.1,10-phenanthroline by the reaction of lead(II)bis{O,O'-ditolyldithiophosphates} and 2,2'-bipyridyl and 1,10-phenanthro-line in the presence of unimolar dichloromethane and ethanol. All these complexes have been characterized by spectroscopic techniques such as IR,1H NMR and31P NMR. On the basis of spectroscopic studies tetracoordinated nature of lead atom in ditolyldithiophosphates complexes and hexacoordinated nature in their adducts have been established.

scholarly journals Synthesis and Evaluation of Changes Induced by Solvent and Substituent in Electronic Absorption Spectra of New Azo Disperse Dyes Containig Barbiturate Ring

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Hooshang Hamidian ◽  
Najmeh Zahedian ◽  
Dadkhoda Ghazanfari ◽  
Samieh Fozooni
Keyword(s):  
Aromatic Aldehyde ◽  
Electronic Absorption Spectra ◽  
Thiobarbituric Acid ◽  
Disperse Dyes ◽  
Spectroscopic Techniques ◽  
H Nmr ◽  
Ft Ir ◽  
Azo Disperse Dyes ◽  
C Nmr

Six azo disperse dyes were prepared by diazotizing 4-amino hippuric acid and coupled with barbituric acid and 2-thiobarbituric acid. Then, the products were reacted with aromatic aldehyde, sodium acetate, and acetic anhydride, and oxazolone derivatives were formed. Characterization of the dyes was carried out by using UV-Vis, FT-IR,1H NMR and13C NMR, and mass spectroscopic techniques. The solvatochromic behavior of azo disperse dyes was evaluated in various solvents. The effects of substituents of aromatic aldehyde, barbiturate, and thiobarbiturate ring on the color of dyes were investigated.

Functional chalcone-substituted tetrakis-metallophthalocyanines: Synthesis and spectroscopic characterization

2019 ◽  
Vol 44 (3-4) ◽  
pp. 148-151
Author(s):  
Volkan Çakır
Keyword(s):  
Spectroscopic Characterization ◽  
H Nmr ◽  
Vis Spectroscopy ◽  
New Compounds ◽  
C Nmr

In this study, a new phthalonitrile derivative, ( E)-4-(3-(3-(3-methoxyphenyl)acryloyl)phenoxy)phthalonitrile, and four peripherally ( E)-4-(3-(3-(3-methoxyphenyl)acryloyl)phenoxy) tetrasubstituted new Ni(II), Zn(II), Co(II), and Cu(II) phthalocyanine derivatives are synthesized and characterized. ( E)-4-(3-(3-(3-Methoxyphenyl)acryloyl)phenoxy)phthalonitrile is synthesized by heating ( E)-1-(3-hydroxyphenyl)-3-(3-methoxyphenyl)prop-2-en-1-one and 4-nitrophthalonitrile in the presence of K2CO3 in dry DMF at 60°C for 96 h. The metallophthalocyanines are prepared by cyclotetramerization of ( E)-4-(3-(3-(3-methoxyphenyl)acryloyl)phenoxy)phthalonitrile with NiCl2, Zn(CH3COO)2, CoCl2, and CuCl2 in n-pentanol in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene. Characterization of the new compounds is performed by means of IR, 1H NMR, 13C NMR, and mass and UV-Vis spectroscopy techniques.

Sign in / Sign up

Export Citation Format

Share Document