scholarly journals Raman Spectroscopy of Isotactic Polypropylene-Halloysite Nanocomposites

2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
Elamin E. Ibrahim ◽  
Dorina Magdalena Chipara ◽  
Ram Thapa ◽  
Karen Lozano ◽  
Mircea Chipara

Raman spectroscopy investigations on nanocomposites obtained by dispersing halloysite within isotactic polypropylene are reported. A detailed analysis of the modifications of the regularity band associated to the polymeric matrix is presented. The Raman lines assigned to the polymeric matrix are broadened and weakened as the loading with halloysite is increased. The analysis of Raman lines indicates that the polymeric matrix becomes less crystalline upon the loading with halloysite and that the nanofiller is experiencing a weak dehydration upon dispersion within the polymeric matrix, probably due to the related thermal processing used to achieve the dispersion of halloysite.

2019 ◽  
Vol 4 (6) ◽  
Author(s):  
Markus Lankers

Abstract Micro Raman spectroscopy has been applied very early in environmental analytics. However, until now the field of application is quite limited. The main reasons for the low acceptance are high cost of the method and the low throughput. New developments in technology lead to cheaper instrumentation. Automation of Raman microscopy of particles might be a solution for a higher throughput and a broader application in environmental analytics. A more detailed analysis of aerosols and microplastic is good examples that could benefit from this development.


2000 ◽  
Vol 638 ◽  
Author(s):  
WK Choi ◽  
V Ng ◽  
YW Ho ◽  
TB Chen ◽  
V Ho

AbstractThe high resolution transmission electron microscopy and Raman spectroscopy results of germanium nanocrystals embedded in SiO2 synthesized by rapid thermal processing (RTA) have been presented. From the results of samples with different Ge concentrations, it was concluded that there is a narrow window in the Ge concentration that can produce nanocrystals. We also showed that it is possible to vary RTA duration or temperature to produce Ge nanocrystals with varying sizes. Our results therefore suggest that it is possible to utilize (i) annealing duration and; (ii) temperature to tune crystal sizes for optoelectronic applications.


2007 ◽  
Vol 21 (16) ◽  
pp. 987-995 ◽  
Author(s):  
M. TODICA ◽  
C. V. POP ◽  
E. DINTE ◽  
C. FARCAU ◽  
S. ASTILEAN

The possibility to use poly(ethylene oxide) as a polymeric matrix for some pharmaceutical products was analyzed. The behavior of the polymer in the aqueous solutions and the possible interactions between the polymer and the clotrimazole were investigated by Raman spectroscopy. Repeated action of the water on the polymeric conformation is a reversible process and the introduction of the clotrimazole in the polymeric gel do not modify the properties of the active substance of the pharmaceutical product.


2009 ◽  
Vol 63 (12) ◽  
pp. 1377-1381 ◽  
Author(s):  
J. Martin ◽  
P. Bourson ◽  
A. Dahoun ◽  
J. M. Hiver

2001 ◽  
Vol 79 (14) ◽  
pp. 2148-2150 ◽  
Author(s):  
S. J. Koester ◽  
K. Rim ◽  
J. O. Chu ◽  
P. M. Mooney ◽  
J. A. Ott ◽  
...  

2007 ◽  
Vol 1024 ◽  
Author(s):  
George Sarau ◽  
Michael Becker ◽  
Andreas Berger ◽  
Jens Schneider ◽  
Silke Christiansen

AbstractMicro-Raman spectroscopy is used to measure stress distributions in 1.5 µm thick polycrystalline silicon thin film solar cells on glass. These measurements are combined with transmission electron microscopy and atomic force microscopy to assign the measured local stresses to the sample's microstructure. Expansion and contraction of the silicon lattice in the layer and the borosilicate glass substrate during the thermal processing of the solar cell as well as quartz beads of µm size that reside on the glass substrate for light-trapping purposes induce internal stresses that locally vary with structural features. While the thermal processing induces an average tensile stress in the silicon layer originating from the thermal mismatch between glass and silicon, the latter results in lateral stress gradients up to 208 ± 12 MPa in the mapped area.


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