scholarly journals Plausible Applicability of Aqueous Congo Red Dye System as Secondary Gamma-ray Dosimeter

2008 ◽  
Vol 5 (3) ◽  
pp. 572-576
Author(s):  
I. Das Sarma ◽  
D. V. Parwate

Aqueous congo red dye solutions in the concentration range of 0.01–0.03mM were irradiated for varying γ doses 0.050 kGy to 0.150 kGy. The molar extinction coefficient of the dye solution of congo red was found to be 2.70×105at its absorption maxima 499.0 nm. No change in λmaxwas observed on irradiation. As the dye solutions are sensitive towards γ–irradiation, decolouration occurs on irradiation. The G–values for the doses in between the range of 0.035 kGy to 0.125 kGy were found to be practically constant for pure aqueous systems. Hence this was used to determine the dose of the gamma source. With the addition of alcohols in the systems, degradation of the dyes due to radiations decreased considerably.

Nukleonika ◽  
2019 ◽  
Vol 64 (2) ◽  
pp. 49-53 ◽  
Author(s):  
Majid Muneer ◽  
Muhammad Saeed ◽  
Ijaz Ahmad Bhatti ◽  
Atta-ul Haq ◽  
Muhammad Kaleem Khosa ◽  
...  

Abstract Synthetic dyes are persistent pollutants with poor biodegradability. The present study is about the degradation of direct Congo red dye in aqueous media using the Co-60 gamma radiation source. The experimental conditions such as gamma-ray absorbed doses, amount of oxidant (H2O2) and pH conditions were evaluated. The λmax of dye solution was noted as 498 nm, and then, decrease in absorbance and reduction in chemical oxygen demand (COD) were examined. The complete colour removal of dye was observed at 5 kGy, while a significant COD removal was observed at 15 kGy gamma-ray absorbed dose in conjunction with oxidant for 50 mg/L concentration. It was found that pH has no influence on degradation efficiency. A possible degradation pathway was proposed. The radiolytic end products were monitored by Fourier transform infrared (FTIR) and gas chromatography coupled with mass spectrometry (GC-MS) to explore the degradation mechanism. It was imperative to study the oxidative degradation pathway to provide directions for potential applicability of advanced oxidation process (AOP) in industrial wastewater treatment.


2020 ◽  
Vol 198 ◽  
pp. 422-433
Author(s):  
Abdallah Rahali ◽  
Ali Riazi ◽  
Badredine Moussaoui ◽  
Ahmed Boucherdoud ◽  
Nihal Bektaş

TAPPI Journal ◽  
2018 ◽  
Vol 17 (03) ◽  
pp. 157-164 ◽  
Author(s):  
Shengdan Wang ◽  
Wenhua Gao ◽  
Kefu Chen ◽  
Jinsong Zeng ◽  
Jun Xu ◽  
...  

Cellulose nanofibrils (CNF) were prepared by cellulase in conjunction with mechanical disintegration from the bleached softwood kraft pulp and labelled by Congo red dye. The labelled CNF were used to investigate the retention and distribution of CNF in paper handsheets. The retention of the labelled CNF was obtained by measuring the absorbance of white water using an ultraviolet-visible spectrophotometer. The results showed that this method for measuring the retention was rapid, feasible, and sensitive, owing to the high correlation coefficient R2 (0.9993) of the standard curve. The labelled CNF showed even distribution in paper handsheets. The colorimetric values of paper handsheets were explored with a residual ink analyzer.


2020 ◽  
Vol 18 (1) ◽  
pp. 287-294
Author(s):  
Harsasi Setyawati ◽  
Handoko Darmokoesoemo ◽  
Irmina Kris Murwani ◽  
Ahmadi Jaya Permana ◽  
Faidur Rochman

AbstractThe demands of ecofriendly technologies to produce a reliable supply of renewable energy on a large scale remains a challenge. A solar cell based on DSSC (Dye-Sensitized Solar Cell) technology is environmentally friendly and holds the promise of a high efficiency in converting sunlight into electricity. This manuscript describes the development of a light harvester system as a main part of a DSSC. Congo red dye has been functionalized with metals (Fe, Co, Ni), forming a series of complexes that serve as a novel light harvester on the solar cell. Metal-congo red complexes have been characterized by UV-VIS and FTIR spectroscopy, and elemental analyses. The performance of metal complexes in capturing photons from sunlight has been investigated in a solar cell device. The incorporation of metals to congo red successfully improved of the congo red efficiency as follows: Fe(II)-congo red, Co(II)-congo red and Ni(II)-congo red had efficiencies of 8.17%, 6.13% and 2.65%, respectively. This research also discusses the effect of metal ions on the ability of congo red to capture energy from sunlight.


2021 ◽  
Vol 765 (1) ◽  
pp. 012089
Author(s):  
R Taufik ◽  
M Mohamad ◽  
R Wannahari ◽  
N F Shoparwe ◽  
WHW Osman ◽  
...  

2021 ◽  
pp. 101183
Author(s):  
Munazza Maqbool ◽  
Sana Sadaf ◽  
Haq N. Bhatti ◽  
Sehrish Rehmat ◽  
Abida Kausar ◽  
...  

2021 ◽  
Vol 22 ◽  
pp. 101402 ◽  
Author(s):  
Saraf Khan ◽  
Adnan Khan ◽  
Nisar Ali ◽  
Shehzad Ahmad ◽  
Waqar Ahmad ◽  
...  

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