Optimizing Polymer-Based Gel Electrolytes for Long-Term Stable Dye-Sensitized Solar Cells

Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 3035
Author(s):  
Jan Lukas Storck ◽  
Marius Dotter ◽  
Sonia Adabra ◽  
Michelle Surjawidjaja ◽  
Bennet Brockhagen ◽  
...  

To overcome the long-term stability problems of dye-sensitized solar cells (DSSC) due to solvent evaporation and leakage, gelling the electrolyte with polymers is an appropriate option. Especially for future applications of textile-based DSSCs, which require cost-effective and environmentally friendly materials, such an improvement of the electrolyte is necessary. Therefore, the temporal progressions of efficiencies and fill factors of non-toxic glass-based DSSCs resulting from different gel electrolytes with poly(ethylene oxide) (PEO) are investigated over 52 days comparatively. Dimethyl sulfoxide (DMSO) proved to be a suitable non-toxic solvent for the proposed gel electrolyte without ionic liquids. A PEO concentration of 17.4 wt% resulted in an optimal compromise with a relatively high efficiency over the entire period. Lower concentrations resulted in higher efficiencies during the first days but in a poorer long-term stability, whereas a higher PEO concentration resulted in an overall lower efficiency. Solvent remaining in the gel electrolyte during application was found advantageous compared to previous solvent evaporation. In contrast to a commercial liquid electrolyte, the long-term stability regarding the efficiency was improved successfully with a similar fill factor and thus equal quality.


2019 ◽  
Vol 7 (24) ◽  
pp. 14743-14752 ◽  
Author(s):  
Seung Mo Seo ◽  
Chang Ki Kim ◽  
Hwan Kyu Kim

Two kinds of triblock copolymers (SGT-602 and SGT-604) were prepared and applied to dye-sensitized solar cells (DSSCs). The polymer gel electrolytes with a TiO2 nanofiller achieved comparable efficiencies to liquid-state DSSCs (η: 9.86%), and exhibited excellent long-term device stability under 1 sun illumination at 50 °C.


2012 ◽  
Vol 201 ◽  
pp. 395-401 ◽  
Author(s):  
Jinsun Yoon ◽  
Doc ki Kang ◽  
Jongok Won ◽  
Jun-Young Park ◽  
Yong Soo Kang

Author(s):  
Ammar Khan ◽  
Muhammad Akma Kamarudin ◽  
Sehrish Iqbal ◽  
Hafiyya Malik ◽  
Habib-ur Rehman ◽  
...  

2017 ◽  
Vol 9 (24) ◽  
pp. 20454-20466 ◽  
Author(s):  
Marcos A. Santana Andrade ◽  
Armi Tiihonen ◽  
Kati Miettunen ◽  
Peter Lund ◽  
Ana F. Nogueira ◽  
...  

2018 ◽  
Vol 20 (2) ◽  
pp. 1276-1285 ◽  
Author(s):  
Ottavia Bettucci ◽  
Valeria Saavedra Becerril ◽  
T. M. W. J. Bandara ◽  
Maurizio Furlani ◽  
Maria Abrahamsson ◽  
...  

Effect of cation size on the performances of dye-sensitized solar cells containing alkaline iodide-based gel electrolytes in combination with an organic dye was evaluated for the first time using a multidisciplinary approach.


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