New insights in long-term photovoltaic performance characterization of cellulose-based gel electrolytes for stable dye-sensitized solar cells

2014 ◽  
Vol 146 ◽  
pp. 44-51 ◽  
Author(s):  
Gian Paolo Salvador ◽  
Diego Pugliese ◽  
Federico Bella ◽  
Annalisa Chiappone ◽  
Adriano Sacco ◽  
...  
Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 3035
Author(s):  
Jan Lukas Storck ◽  
Marius Dotter ◽  
Sonia Adabra ◽  
Michelle Surjawidjaja ◽  
Bennet Brockhagen ◽  
...  

To overcome the long-term stability problems of dye-sensitized solar cells (DSSC) due to solvent evaporation and leakage, gelling the electrolyte with polymers is an appropriate option. Especially for future applications of textile-based DSSCs, which require cost-effective and environmentally friendly materials, such an improvement of the electrolyte is necessary. Therefore, the temporal progressions of efficiencies and fill factors of non-toxic glass-based DSSCs resulting from different gel electrolytes with poly(ethylene oxide) (PEO) are investigated over 52 days comparatively. Dimethyl sulfoxide (DMSO) proved to be a suitable non-toxic solvent for the proposed gel electrolyte without ionic liquids. A PEO concentration of 17.4 wt% resulted in an optimal compromise with a relatively high efficiency over the entire period. Lower concentrations resulted in higher efficiencies during the first days but in a poorer long-term stability, whereas a higher PEO concentration resulted in an overall lower efficiency. Solvent remaining in the gel electrolyte during application was found advantageous compared to previous solvent evaporation. In contrast to a commercial liquid electrolyte, the long-term stability regarding the efficiency was improved successfully with a similar fill factor and thus equal quality.


2005 ◽  
Vol 73 (10) ◽  
pp. 887-896 ◽  
Author(s):  
Kohjiro HARA ◽  
Sanekazu IGARI ◽  
Shingo TAKANO ◽  
Gaku FUJIHASHI

2019 ◽  
Vol 7 (24) ◽  
pp. 14743-14752 ◽  
Author(s):  
Seung Mo Seo ◽  
Chang Ki Kim ◽  
Hwan Kyu Kim

Two kinds of triblock copolymers (SGT-602 and SGT-604) were prepared and applied to dye-sensitized solar cells (DSSCs). The polymer gel electrolytes with a TiO2 nanofiller achieved comparable efficiencies to liquid-state DSSCs (η: 9.86%), and exhibited excellent long-term device stability under 1 sun illumination at 50 °C.


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