Lithium-Ion Intercalation by Calcium-Ion Addition in Propylene Carbonate-Trimethyl Phosphate Electrolyte Solution

2018 ◽  
Vol 165 (2) ◽  
pp. A349-A354 ◽  
Author(s):  
Saya Takeuchi ◽  
Tomokazu Fukutsuka ◽  
Kohei Miyazaki ◽  
Takeshi Abe
Keyword(s):  
Propylene Carbonate ◽  
Electrolyte Solution ◽  
Calcium Ion ◽  
Lithium Ion ◽  
Trimethyl Phosphate ◽  
Ion Intercalation ◽  
Phosphate Electrolyte

Acyclic Acetals in Propylene Carbonate-Based Electrolytes for Advanced and Safer Graphite-Based Lithium Ion Batteries

2020 ◽  
Vol 167 (4) ◽  
pp. 040509 ◽  
Author(s):  
J. Atik ◽  
S. Röser ◽  
R. Wagner ◽  
D. Berghus ◽  
M. Winter ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Propylene Carbonate ◽  
Lithium Ion

Interfacial lithium-ion transfer between the graphite negative electrode and the electrolyte solution

Carbon ◽  
2021 ◽  
Vol 176 ◽  
pp. 655
Author(s):  
Tomokazu Fukutsuka ◽  
Yuto Miyahara ◽  
Kohei Miyazaki ◽  
Takeshi Abe
Keyword(s):  
Electrolyte Solution ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Ion Transfer

Enhanced Lithium-Ion Intercalation Properties of V2O5 Xerogel Electrodes with Surface Defects

2011 ◽  
Vol 115 (11) ◽  
pp. 4959-4965 ◽  
Author(s):  
Dawei Liu ◽  
Yanyi Liu ◽  
Anqiang Pan ◽  
Kenneth P. Nagle ◽  
Gerald T. Seidler ◽  
...  
Keyword(s):  
Surface Defects ◽  
Lithium Ion ◽  
V2o5 Xerogel ◽  
Ion Intercalation

scholarly journals Electrochemical Solvent Cointercalation into Graphite in Propylene Carbonate-Based Electrolytes: A Chronopotentiometric Characterization

2018 ◽  
Vol 2018 ◽  
pp. 1-5 ◽  
Author(s):  
Hee-Youb Song ◽  
Soon-Ki Jeong
Keyword(s):  
Propylene Carbonate ◽  
Redox Reactions ◽  
High Current Density ◽  
Coulombic Efficiency ◽  
Pyrolytic Graphite ◽  
Lithium Ion ◽  
In Situ Raman Spectroscopy ◽  
Force Microscopy ◽  
Atomic Force

Interfacial reactions strongly influence the performance of lithium-ion batteries, with the main interfacial reaction between graphite and propylene carbonate- (PC-) based electrolytes corresponding to solvent cointercalation. Herein, the redox reactions of solvated lithium ions occurring at the graphite interface in 1 M·LiClO4/PC were probed by chronopotentiometry, in situ atomic force microscopy (AFM), and in situ Raman spectroscopy. The obtained results revealed that high coulombic efficiency (97.5%) can be achieved at high current density, additionally showing the strong influence of charge capacity on the above redox reactions. Moreover, AFM imaging indicated the occurrence of solvent cointercalation during the first reduction, as reflected by the presence of hills and blisters on the basal plane of highly oriented pyrolytic graphite subjected to the above process.

Effects of Aromatic Esters as Propylene Carbonate-Based Electrolyte Additives in Lithium-Ion Batteries

2005 ◽  
Vol 152 (9) ◽  
pp. A1837 ◽  
Author(s):  
Jyh-Tsung Lee ◽  
Mao-Sung Wu ◽  
Fu-Ming Wang ◽  
Yueh-Wei Lin ◽  
Meng-Yi Bai ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Propylene Carbonate ◽  
Lithium Ion ◽  
Electrolyte Additives ◽  
Aromatic Esters

Research Progress and Application of Modified Silicon-Based Anode Materials for Lithium-Ion Batteries

2021 ◽  
Vol 1036 ◽  
pp. 35-44
Author(s):  
Ling Fang Ruan ◽  
Jia Wei Wang ◽  
Shao Ming Ying
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Volume Expansion ◽  
Anode Materials ◽  
Active Material ◽  
Three Dimensional ◽  
Lithium Ion ◽  
Research Progress ◽  
Ion Intercalation ◽  
Silicon Based

Silicon-based anode materials have been widely discussed by researchers because of its high theoretical capacity, abundant resources and low working voltage platform,which has been considered to be the most promising anode materials for lithium-ion batteries. However,there are some problems existing in the silicon-based anode materials greatly limit its wide application: during the process of charge/discharge, the materials are prone to about 300% volume expansion, which will resultin huge stress-strain and crushing or collapse on the anods; in the process of lithium removal, there is some reaction between active material and current collector, which creat an increase in the thickness of the solid phase electrolytic layer(SEI film); during charging and discharging, with the increase of cycle times, cracks will appear on the surface of silicon-based anode materials, which will cause the batteries life to decline. In order to solve these problems, firstly, we summarize the design of porous structure of nanometer sized silicon-based materials and focus on the construction of three-dimensional structural silicon-based materials, which using natural biomass, nanoporous carbon and metal organic framework as structural template. The three-dimensional structure not only increases the channel of lithium-ion intercalation and the rate of ion intercalation, but also makes the structure more stable than one-dimensional or two-dimensional. Secondly, the Si/C composite, SiOx composite and alloying treatment can improve the volume expansion effection, increase the rate of lithium-ion deblocking and optimize the electrochemical performance of the material. The composite materials are usually coated with elastic conductive materials on the surface to reduce the stress, increase the conductivity and improve the electrochemical performance. Finally, the future research direction of silicon-based anode materials is prospected.

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