scholarly journals Determination of Water Evaporation Rates in Gas Diffusion Layers of Fuel Cells

2018 ◽  
Vol 165 (9) ◽  
pp. F652-F661 ◽  
Author(s):  
Sreeyuth Lal ◽  
Adrien Lamibrac ◽  
Jens Eller ◽  
Felix N. Büchi
Energies ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2967
Author(s):  
Adrian Mularczyk ◽  
Andreas Michalski ◽  
Michael Striednig ◽  
Robert Herrendörfer ◽  
Thomas J. Schmidt ◽  
...  

Facilitating the proper handling of water is one of the main challenges to overcome when trying to improve fuel cell performance. Specifically, enhanced removal of liquid water from the porous gas diffusion layers (GDLs) holds a lot of potential, but has proven to be non-trivial. A main contributor to this removal process is the gaseous transport of water following evaporation inside the GDL or catalyst layer domain. Vapor transport is desired over liquid removal, as the liquid water takes up pore space otherwise available for reactant gas supply to the catalytically active sites and opens up the possibility to remove the waste heat of the cell by evaporative cooling concepts. To better understand evaporative water removal from fuel cells and facilitate the evaporative cooling concept developed at the Paul Scherrer Institute, the effect of gas speed (0.5–10 m/s), temperature (30–60 °C), and evaporation domain (0.8–10 mm) on the evaporation rate of water from a GDL (TGP-H-120, 10 wt% PTFE) has been investigated using an ex situ approach, combined with X-ray tomographic microscopy. An along-the-channel model showed good agreement with the measured values and was used to extrapolate the differential approach to larger domains and to investigate parameter variations that were not covered experimentally.


Author(s):  
Yuan Gao

This study is using the multiple relaxation time Lattice Boltzmann method to calculate the permeability of carbon fiber paper and carbon fiber cloth gas diffusion layers (GDL). The 3D gas diffusion layers are generated by X-ray computed tomography, This method involve generation of 3D digital model of gas diffusion layers acquired through X-ray micro-tomography at resolution of a few micros. The reconstructed 3D images were then read into the LBM model to calculate the anisotropic permeability of carbon fiber paper and carbon fiber cloth GDL. We investigated the relationships between the anisotropic permeability and porosity and compare the difference between the two different kinds of GDLs when they have the similar porosity. We also calculate the permeability with different viscosity and compare the two results from the carbon fiber paper and carbon fiber cloth. It is useful for selection of materials for high performance gas diffusion media and can improve the performance of the fuel cells.


2020 ◽  
Vol 97 (7) ◽  
pp. 615-626
Author(s):  
Pablo A. García-Salaberri ◽  
Iryna V. Zenyuk ◽  
Jeff T. Gostick ◽  
Adam Z. Weber

Energies ◽  
2019 ◽  
Vol 12 (5) ◽  
pp. 855 ◽  
Author(s):  
Reza Omrani ◽  
Bahman Shabani

This paper introduces novel empirical as well as modified models to predict the electrical conductivity of sintered metal fibres and closed-cell foams. These models provide a significant improvement over the existing models and reduce the maximum relative error from as high as just over 30% down to about 10%. Also, it is shown that these models provide a noticeable improvement for closed-cell metal foams. However, the estimation of electrical conductivity of open-cell metal foams was improved marginally over previous models. Sintered porous metals are widely used in electrochemical devices such as water electrolysers, unitised regenerative fuel cells (URFCs) as gas diffusion layers (GDLs), and batteries. Having a more accurate prediction of electrical conductivity based on variation by porosity helps in better modelling of such devices and hence achieving improved designs. The models presented in this paper are fitted to the experimental results in order to highlight the difference between the conductivity of sintered metal fibres and metal foams. It is shown that the critical porosity (maximum achievable porosity) can play an important role in sintered metal fibres to predict the electrical conductivity whereas its effect is not significant in open-cell metal foams. Based on the models, the electrical conductivity reaches zero value at 95% porosity rather than 100% for sintered metal fibres.


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