scholarly journals Numerical Solution of Moving Phase Boundary and Diffusion-Induced Stress of Sn Anode in the Lithium-Ion Battery

2017 ◽  
Vol 164 (11) ◽  
pp. E3661-E3670
Author(s):  
Chun-Hao Chen ◽  
Eric Chason ◽  
Pradeep R. Guduru
Keyword(s):  
Numerical Solution ◽  
Phase Boundary ◽  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Induced Stress ◽  
Diffusion Induced Stress ◽  
And Diffusion ◽  
Sn Anode

scholarly journals A Diffusion Model in a Two-Phase Interfacial Zone for Nanoscale Lithium-Ion Battery Materials

2012 ◽  
Author(s):  
Cheng-Kai ChiuHuang ◽  
Hsiao-Ying Shadow Huang
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion Battery ◽  
Electric Vehicle ◽  
Cathode Materials ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Capacity Loss ◽  
Induced Stress ◽  
Stress Formation ◽  
Diffusion Induced Stress

The development of lithium-ion batteries plays an important role to stimulate electric vehicle (EV) and plug-in electric vehicle (PHEV) industries and it is one of many solutions to reduce US oil import dependence. To develop advanced vehicle technologies that use energy more efficiently, retaining the lithium-ion battery capacity is one of major challenges facing by the electrochemical community today. During electrochemical processes, lithium ions diffuse from and insert into nanoscaled cathode materials in which stresses are formed. It is considered that diffusion-induced stress is one of the factors causing electrode material capacity loss and failure. In this study, we present a model which is capable for describing diffusion mechanisms and stress formation in nano-platelike cathode materials, LiFePO4 (Lithium-iron-phosphate). We consider particle size >100 nm in this study since it has been suggested that very small nanoparticles (<100 nm) may not undergo phase separation during fast diffusion. To evaluate diffusion-induced stress accurately, factors such as the diffusivity and phase boundary movements are considered. Our result provides quantitative lithium concentrations inside LiFePO4 nanoparticles. The result could be used for evaluating stress formation and provides potential cues for precursors of capacity loss in lithium-ion batteries. This study contributes to the fundamental understanding of lithium ion diffusion in electrode materials, and results from this model help better electrode materials design in lithium-ion batteries.

Fracture analysis of bi-layer electrode in lithium-ion battery caused by diffusion-induced stress

2020 ◽  
Vol 235 ◽  
pp. 107189
Author(s):  
Aibing Zhang ◽  
Baolin Wang ◽  
Guangyong Li ◽  
Ji Wang ◽  
Jianke Du
Keyword(s):  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Fracture Analysis ◽  
Induced Stress ◽  
Diffusion Induced Stress

Fracture damage of nanowire lithium-ion battery electrode affected by diffusion-induced stress and bending during lithiation

RSC Advances ◽  
2014 ◽  
Vol 4 (40) ◽  
pp. 21072-21078 ◽  
Author(s):  
Bingbing Chen ◽  
Jianqiu Zhou ◽  
Xuming Pang ◽  
Pengfei Wei ◽  
Yunbo Wu ◽  
...  
Keyword(s):  
Lithium Ion Battery ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Volume Changes ◽  
Significant Volume ◽  
Induced Stress ◽  
Lithium Diffusion ◽  
Battery Electrode ◽  
Diffusion Induced Stress ◽  
Fracture Damage

Lithium-ion battery electrode materials generally experience significant volume changes during lithium diffusion during charging and discharging.

scholarly journals Progress on Failure Mechanism of Lithium Ion Battery Caused by Diffusion Induced Stress

2020 ◽  
Vol 35 (10) ◽  
pp. 1071 ◽  
Author(s):  
WANG Yanan ◽  
LI Hua ◽  
WANG Zhengkun ◽  
LI Qingfeng ◽  
LIAN Chen ◽  
...  
Keyword(s):  
Lithium Ion Battery ◽  
Failure Mechanism ◽  
Lithium Ion ◽  
Induced Stress ◽  
Diffusion Induced Stress

Effect of electrochemical reaction on diffusion-induced stress in hollow spherical lithium-ion battery electrode

Ionics ◽  
2016 ◽  
Vol 23 (3) ◽  
pp. 617-625 ◽  
Author(s):  
Zhen Liu ◽  
Rui Cai ◽  
Bingbing Chen ◽  
Tong Liu ◽  
Jianqiu Zhou
Keyword(s):  
Lithium Ion Battery ◽  
Electrochemical Reaction ◽  
Lithium Ion ◽  
Induced Stress ◽  
Battery Electrode ◽  
Diffusion Induced Stress

Interaction between dislocation mechanics on diffusion induced stress and electrochemical reaction in a spherical lithium ion battery electrode

RSC Advances ◽  
2015 ◽  
Vol 5 (91) ◽  
pp. 74835-74843 ◽  
Author(s):  
Zhijun Liu ◽  
Jianqiu Zhou ◽  
Bingbing Chen ◽  
Jianwei Zhu
Keyword(s):  
Lithium Ion Battery ◽  
Electrochemical Reaction ◽  
Lithium Ion ◽  
Induced Stress ◽  
Dislocation Mechanics ◽  
Battery Electrode ◽  
Diffusion Induced Stress

The effect of coupling dislocation induced stress with electrochemical reaction in a spherical battery electrode is investigated.

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