scholarly journals Influence of local velocity on diffusion-induced stress and axial reaction force in a hollow cylindrical electrode of lithium-ion batteries with cosidering expasion rate of medium

2018 ◽  
Vol 67 (7) ◽  
pp. 070203
Author(s):  
Peng Ying-Zha ◽  
Li Yong ◽  
Zheng Bai-Lin ◽  
Zhang Kai ◽  
Xu Yong-Chuan
Author(s):  
Cheng-Kai ChiuHuang ◽  
Hsiao-Ying Shadow Huang

The development of lithium-ion batteries plays an important role to stimulate electric vehicle (EV) and plug-in electric vehicle (PHEV) industries and it is one of many solutions to reduce US oil import dependence. To develop advanced vehicle technologies that use energy more efficiently, retaining the lithium-ion battery capacity is one of major challenges facing by the electrochemical community today. During electrochemical processes, lithium ions diffuse from and insert into nanoscaled cathode materials in which stresses are formed. It is considered that diffusion-induced stress is one of the factors causing electrode material capacity loss and failure. In this study, we present a model which is capable for describing diffusion mechanisms and stress formation in nano-platelike cathode materials, LiFePO4 (Lithium-iron-phosphate). We consider particle size >100 nm in this study since it has been suggested that very small nanoparticles (<100 nm) may not undergo phase separation during fast diffusion. To evaluate diffusion-induced stress accurately, factors such as the diffusivity and phase boundary movements are considered. Our result provides quantitative lithium concentrations inside LiFePO4 nanoparticles. The result could be used for evaluating stress formation and provides potential cues for precursors of capacity loss in lithium-ion batteries. This study contributes to the fundamental understanding of lithium ion diffusion in electrode materials, and results from this model help better electrode materials design in lithium-ion batteries.


2016 ◽  
Vol 120 (2) ◽  
pp. 025302 ◽  
Author(s):  
Zengsheng Ma ◽  
Xiang Gao ◽  
Yan Wang ◽  
Chunsheng Lu

2018 ◽  
Vol 71 ◽  
pp. 320-325 ◽  
Author(s):  
Hui Wu ◽  
Zhoucan Xie ◽  
Yan Wang ◽  
Chunsheng Lu ◽  
Zengsheng Ma

2020 ◽  
Vol 235 ◽  
pp. 107189
Author(s):  
Aibing Zhang ◽  
Baolin Wang ◽  
Guangyong Li ◽  
Ji Wang ◽  
Jianke Du

Energies ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1717
Author(s):  
Davide Clerici ◽  
Francesco Mocera ◽  
Aurelio Somà

Electric cycling is one of the major damage sources in lithium-ion batteries and extensive work has been produced to understand and to slow down this phenomenon. The damage is related to the insertion and extraction of lithium ions in the active material. These processes cause mechanical stresses which in turn generate crack propagation, material loss and pulverization of the active material. In this work, the principles of diffusion induced stress theory are applied to predict concentration and stress field in the active material particles. Coupled and uncoupled models are derived, depending on whether the effect of hydrostatic stress on concentration is considered or neglected. The analytical solution of the coupled model is proposed in this work, in addition to the analytical solution of the uncoupled model already described in the literature. The analytical solution is a faster and simpler way to deal with the problem which otherwise should be solved in a numerical way with finite difference method or a finite element model. The results of the coupled and uncoupled models for three different state of charge levels are compared assuming the physical parameters of anode and cathode active material. Finally, the effects of tensile and compressive stress are analysed.


RSC Advances ◽  
2014 ◽  
Vol 4 (40) ◽  
pp. 21072-21078 ◽  
Author(s):  
Bingbing Chen ◽  
Jianqiu Zhou ◽  
Xuming Pang ◽  
Pengfei Wei ◽  
Yunbo Wu ◽  
...  

Lithium-ion battery electrode materials generally experience significant volume changes during lithium diffusion during charging and discharging.


2020 ◽  
Vol 35 (10) ◽  
pp. 1071 ◽  
Author(s):  
WANG Yanan ◽  
LI Hua ◽  
WANG Zhengkun ◽  
LI Qingfeng ◽  
LIAN Chen ◽  
...  

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