An Efficient Two-Polymer Binder for High-Performance Silicon Nanoparticle-Based Lithium-Ion Batteries: A Systematic Case Study with Commercial Polyacrylic Acid and Polyvinyl Butyral Polymers

2019 ◽  
Vol 166 (3) ◽  
pp. A5275-A5286 ◽  
Author(s):  
Anna Urbanski ◽  
Ahmad Omar ◽  
Jing Guo ◽  
Andreas Janke ◽  
Uta Reuter ◽  
...  
2014 ◽  
Vol 1643 ◽  
Author(s):  
Sharon Kotz ◽  
Ankita Shah ◽  
Sivasubramanian Somu ◽  
KM Abraham ◽  
Sanjeev Mukerjee ◽  
...  

ABSTRACTSilicon is emerging as a very attractive anode material for lithium ion batteries due to its low discharge potential, natural abundance, and high theoretical capacity of 4200 mAh/g, more than ten times that of graphite (372 mAh/g). This high charge capacity is the result of silicon’s ability to incorporate 4.4 lithium atoms per silicon atom; however, the incorporation of lithium also leads to a 300-400% volume expansion during charging, which can cause pulverization of the material and loss of access to the silicon. The architecture of the anode must therefore be able to adapt to this volume increase. Here we present a layered carbon nanotube and silicon nanoparticle electrode structure, fabricated using directed assembly techniques. The porous carbon nanotube layers maintain electrical connectivity through the active material and increase the surface area of the current collector. Using this architecture, we obtain an initial capacity in excess of 4000 mAh/g, as well as increased power and energy density as compared to anodes fabricated using the standard procedure of slurry casting.


2019 ◽  
Vol 55 (3) ◽  
pp. 361-364 ◽  
Author(s):  
Donghee Gueon ◽  
Jun Hyuk Moon

We report simple yet rationally designed, polydopamine-wrapped, silicon nanoparticle-impregnated macroporous CNT particles for high-capacity lithium-ion batteries.


2014 ◽  
Vol 24 (37) ◽  
pp. 5904-5910 ◽  
Author(s):  
Jiangxuan Song ◽  
Mingjiong Zhou ◽  
Ran Yi ◽  
Terrence Xu ◽  
Mikhail L. Gordin ◽  
...  

2012 ◽  
Vol 25 (11) ◽  
pp. 1571-1576 ◽  
Author(s):  
Myung-Hyun Ryou ◽  
Jangbae Kim ◽  
Inhwa Lee ◽  
Sunjin Kim ◽  
You Kyeong Jeong ◽  
...  

2019 ◽  
Vol 4 (27) ◽  
pp. 8082-8088 ◽  
Author(s):  
Fei Wang ◽  
Tingting Cheng ◽  
Jingui Zong ◽  
Mingshu Zhao ◽  
Sen Yang ◽  
...  

2016 ◽  
Vol 8 (5) ◽  
pp. 2899-2904 ◽  
Author(s):  
Yitian Bie ◽  
Jun Yang ◽  
Xiaolin Liu ◽  
Jiulin Wang ◽  
Yanna Nuli ◽  
...  

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