scholarly journals Poly (acrylic acid sodium) grafted carboxymethyl cellulose as a high performance polymer binder for silicon anode in lithium ion batteries

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Liangming Wei ◽  
Changxin Chen ◽  
Zhongyu Hou ◽  
Hao Wei
2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Jaebin Nam ◽  
Eunsoo Kim ◽  
Rajeev K.K. ◽  
Yeonho Kim ◽  
Tae-Hyun Kim

Abstract A ureido-pyrimidinone (UPy)-functionalized poly(acrylic acid) grafted with poly(ethylene glycol)(PEG), designated PAU-g-PEG, was developed as a high performance polymer binder for Si anodes in lithium-ion batteries. By introducing both a ureido-pyrimidinone (UPy) unit, which is capable of self-healing through dynamic hydrogen bonding within molecules as well as with Si, and an ion-conducting PEG onto the side chain of the poly(acrylic acid), this water-based self-healable and conductive polymer binder can effectively accommodate the volume changes of Si, while maintaining electronic integrity, in an electrode during repeated charge/discharge cycles. The Si@PAU-g-PEG electrode retained a high capacity of 1,450.2 mAh g−1 and a Coulombic efficiency of 99.4% even after 350 cycles under a C-rate of 0.5 C. Under a high C-rate of 3 C, an outstanding capacity of 2,500 mAh g−1 was also achieved, thus demonstrating its potential for improving the electrochemical performance of Si anodes.


2017 ◽  
Vol 5 (42) ◽  
pp. 22156-22162 ◽  
Author(s):  
Liangming Wei ◽  
Zhongyu Hou

Inspired by the chemical finishing method for textile, theN-methylol acrylamide functionalized carboxymethyl cellulose binder has been developed for Si anodes. This binder can help maintain integration of the Si electrodes, leading to significant improvement in cycling performance of the Si based lithium ion batteries.


2019 ◽  
Vol 87 (1) ◽  
pp. 94-99 ◽  
Author(s):  
Xinxin WANG ◽  
Jian LIU ◽  
Zhengliang GONG ◽  
Chaofan HUANG ◽  
Shuaishuai HE ◽  
...  

RSC Advances ◽  
2018 ◽  
Vol 8 (51) ◽  
pp. 29230-29236 ◽  
Author(s):  
Xiangyu Zeng ◽  
Yongji Shi ◽  
Yu Zhang ◽  
Ruixian Tang ◽  
Liangming Wei

The PVTES-NaPAA binder possesses a three-dimensional crosslinked network and exhibits an excellent cycling performance.


2019 ◽  
Vol 135 ◽  
pp. 109113 ◽  
Author(s):  
Lubing Yu ◽  
Jian Liu ◽  
Shuaishuai He ◽  
Chaofan Huang ◽  
Lihui Gan ◽  
...  

2021 ◽  
pp. 160240
Author(s):  
Yiwei Qiu ◽  
Chenying Zhang ◽  
Chengkun Zhang ◽  
Qingshui Xie ◽  
Zhensong Qiao ◽  
...  

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