Enhancing Pitting Corrosion Resistance of Severely Cold-Worked High Nitrogen Austenitic Stainless Steel by Nitric Acid Passivation

2019 ◽  
Vol 166 (13) ◽  
pp. C365-C374
Author(s):  
Jun Li ◽  
Qingchuan Wang ◽  
Yixun Yang ◽  
Zhiqiang Wu ◽  
Lili Tan ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Nitric Acid ◽  
Austenitic Stainless Steel ◽  
Pitting Corrosion ◽  
High Nitrogen ◽  
Pitting Corrosion Resistance ◽  
Cold Worked

The Influence of Cold Working on Semiconducting Properties of Passive Film and Pitting Corrosion Resistance of High Nitrogen Austenitic Stainless Steel

2011 ◽  
Vol 415-417 ◽  
pp. 784-788
Author(s):  
Li Wei Xu ◽  
Hua Bing Li ◽  
Qi Feng Ma ◽  
Zhou Hua Jiang ◽  
Dong Ping Zhan
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Austenitic Stainless Steel ◽  
Cold Rolling ◽  
Passive Film ◽  
Pitting Corrosion ◽  
High Nitrogen ◽  
Pitting Corrosion Resistance ◽  
Semiconducting Properties ◽  
Rolling Deformation

The effect of cold working on semiconducting properties of passive film and pitting corrosion resistance of 19Cr-18Mn-2Mo-0.9N high nitrogen austenitic stainless were investigated by anodic polarization, AC impedance and capacitance measurement methods. With increasing the cold rolling deformation ranging from 0% to 60%, the passive region of high nitrogen austenitic stainless steel decreases, and the corrosion potential, EIS radius and polarization resistance all decreases. The Mott-Schottky result indicates that the pitting corrosion resistance deteriorates with increment of cold rolling deformation. The results show that the passive films formed on high nitrogen austenitic stainless steel with different cold rolling deformation behave as n-type semiconductors. With increasing the cold rolling deformation grade, the donor density (ND) increases, but the thickness of the space-charge layer (W) decreases. The decreasing of the thickness of space-charge layer with increment of cold rolling deformation is attributed to the inceasing defect which deteriorates the stability of the passive film.

Influences of Nitrogen Content and Aging Precipitates on Pitting Corrosion Resistance Properties of High Nitrogen Austenitic Stainless Steel

2013 ◽  
Vol 448-453 ◽  
pp. 102-106
Author(s):  
Zu Rui Zhang ◽  
Zhen Ye Zhao ◽  
Chun Zhi Li ◽  
Zhou Hua Jiang ◽  
Hua Bing Li
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Austenitic Stainless Steel ◽  
Nitrogen Content ◽  
Pitting Corrosion ◽  
Corrosion Potential ◽  
High Nitrogen ◽  
Pitting Corrosion Resistance ◽  
The Matrix ◽  
Nose Temperature

This study is concerning the influences of nitrogen content and aging precipitates on pitting corrosion resistance properties of high nitrogen austenitic stainless steel (HNS) through potentiodynamic polarization method. The microstructure of aged HNS is analized by scanning electron microscopy (SEM). The main results obtained are as follow: the formation of intergranular, cellular Cr2N and intermetallic χ precipitates makes the depletion of Cr and Mo in the matrix and deteriorates the resistance to pitting corrosion in aged specimens. Cr2N starts to precipitate in the form of lamellar structure to cellular precipitates, the pitting corrosion drops to about 0 VSCE. HNSs perform the same tendency that the pitting corrosion potential firstly decreases then increases and reduce to the minimum value at nose temperature. All the pitting corrosion potential of HNS-B aged for 2h at different temperature presents more than that of HNS-A. The pitting corrosion resistance is mainly controlled by nitrogen content before great precipitates of cellular Cr2N and intermetallic χ phase rich in Cr and Mo. It is also mainly controlled by the content and the type of precipitates after great precipitates of cellular Cr2N.

NIROSTA 4429

Alloy Digest ◽  
2000 ◽  
Vol 49 (5) ◽  
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Pitting Corrosion ◽  
Intergranular Corrosion ◽  
Heat Treating ◽  
Low Carbon ◽  
High Nitrogen ◽  
Temperature Performance ◽  
Pitting Corrosion Resistance

Abstract Nirosta 4429 is a low-carbon, high-nitrogen version of type 316 stainless steel. The low carbon imparts intergranular corrosion resistance while the nitrogen imparts both higher strength and some increased pitting corrosion resistance. It is recommended for use as welded parts that need not or cannot be annealed after welding. This datasheet provides information on composition, physical properties, elasticity, and tensile properties. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, and joining. Filing Code: SS-787. Producer or source: ThyssenKrupp Nirosta.

Effect of Rare Earth on the Inclusions and Pitting Resistance of Austenitic Stainless Steel

2013 ◽  
Vol 718-720 ◽  
pp. 29-32 ◽  
Author(s):  
Xiao Liu ◽  
Yu Bo
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Rare Earth ◽  
Austenitic Stainless Steel ◽  
Pitting Corrosion ◽  
Stainless Steels ◽  
Anodic Polarization ◽  
Austenitic Stainless Steels ◽  
Metallographic Examination ◽  
Pitting Corrosion Resistance

The anodic polarization curves of 21Cr-11Ni austenitic stainless steels with various RE contents in 3.5% NaCl neutral solutions have been measured by electrochemical methods. The effect of RE on pitting corrosion resistance of 21Cr-11Ni stainless steels has been studied by the metallographic examination. The results show that sulfide and other irregular inclusions are modified to round or oval-shaped RE2O2S and RES after adding RE to 21Cr-11Ni stainless steesl. RE makes sulfide, and other irregular inclusions change to dispersed round or oval-shaped RE inclusions, effectively inhibits the occurrence of pitting corrosion, thereby enhancing the corrosion resistance of 21Cr-11Ni austenitic stainless steels.

scholarly journals Testing of intergranular and pitting corrosion in sensitized welded joints of austenitic stainless steel

10.30544/274 ◽  
2017 ◽  
Vol 23 (2) ◽  
pp. 109-117 ◽  
Author(s):  
Bore V. Jegdic ◽  
Biljana Bobić ◽  
Milica Bošnjakov ◽  
Behar Alić
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
Austenitic Stainless Steel ◽  
Weld Metal ◽  
Base Metal ◽  
Pitting Corrosion ◽  
Heat Affected Zone ◽  
Intergranular Corrosion ◽  
Chromium Concentration ◽  
Pitting Corrosion Resistance

Pitting corrosion resistance and intergranular corrosion of the austenitic stainless steel X5Cr Ni18-10 were tested on the base metal, heat affected zone and weld metal. Testing of pitting corrosion was performed by the potentiodynamic polarization method, while testing of intergranular corrosion was performed by the method of electrochemical potentiokinetic reactivation with double loop. The base metal was completely resistant to intergranular corrosion, while the heat affected zone showed a slight susceptibility to intergranular corrosion. Indicators of pitting corrosion resistance for the weld metal and the base metal were very similar, but their values are significantly higher than the values for the heat affected zone. This was caused by reduction of the chromium concentration in the grain boundary areas in the heat affected zone, even though the carbon content in the examined stainless steel is low (0.04 wt. % C).

SANDVIK 3R64

Alloy Digest ◽  
1997 ◽  
Vol 46 (6) ◽  
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Austenitic Stainless Steel ◽  
Physical Properties ◽  
Pitting Corrosion ◽  
Heat Treating ◽  
Temperature Performance ◽  
Pitting Corrosion Resistance ◽  
Type 316L

Abstract Sandvik 3R64 is an austenitic stainless steel with a high molybdenum content. Significant properties are improved general and pitting corrosion resistance in comparison with Type 316L. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on high temperature performance and corrosion resistance as well as heat treating and joining. Filing Code: SS-686. Producer or source: Sandvik.

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