Characterization of Nanoporous Metal-Ionic Liquid Composites for the Electrochemical Oxygen Reduction Reaction

2015 ◽  
Vol 162 (10) ◽  
pp. H759-H766 ◽  
Author(s):  
E. Benn ◽  
H. Uvegi ◽  
J. Erlebacher
Carbon Trends ◽  
2021 ◽  
Vol 3 ◽  
pp. 100038
Author(s):  
Jian Gao ◽  
Xiujuan Chu ◽  
Xiaoyao Tan ◽  
Hongqi Sun ◽  
Zhen Yin ◽  
...  

2013 ◽  
Vol 17 (04) ◽  
pp. 252-258 ◽  
Author(s):  
Qinggang He ◽  
Xiao Cheng ◽  
Ying Wang ◽  
Ruimin Qiao ◽  
Wanli Yang ◽  
...  

The dicobalt complex [ Co2(L2) ] of a Schiff-base pyrrole macrocycle adopts a Pacman structure in solution and the solid state and shows much greater catalytic activity and selectivity for the four-electron oxygen reduction reaction (ORR) than the mononuclear cobalt phthalocyanine (CoPc) counterpart. Soft X-ray absorption spectroscopy (XAS) shows that the Co center in Co2(L2) is of the same valence as mononuclear CoPc . However, the former complex shows higher unoccupied Co 3d density which is believed to be beneficial for electron transfers. Furthermore, the XAS data suggests that the crystal fields for Co2(L2) and CoPc are different, and that an interaction remains between two Co atoms in Co2(L2) . DFT calculations imply that the sterically hindered, cofacial structure of the dicobalt complex is critical for the operation of the four-electron reaction pathway during the ORR.


2021 ◽  
Vol MA2021-02 (36) ◽  
pp. 1024-1024
Author(s):  
Hassan Shirzadi Jahromi ◽  
Shivi Saxena ◽  
Sudharsan Sridhar ◽  
Muralidhar K Ghantasala ◽  
Ramakrishna Guda ◽  
...  

Author(s):  
Shrish Nath Upadhyay ◽  
Srimanta Pakhira

The O2 reduction reaction (ORR) is one promising reaction in clean energy conversion systems such as fuel cells, metal-air batteries, electrochemical reactions, etc. Pt shows excellent electrocatalytic activities for ORR,...


2021 ◽  
Vol 104 (8) ◽  
pp. 59-71
Author(s):  
Hassan Shirzadi Jahromi ◽  
Shivi Saxena ◽  
Sudharsan Sridhar ◽  
Muralidhar K Ghantasala ◽  
Ramakrishna Guda ◽  
...  

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