Mechanism of Electrochemical Oxygen Reduction Reaction at Two-Dimensional Pt-doped MoSe2 Material: An Efficient Electrocatalyst

Author(s):  
Shrish Nath Upadhyay ◽  
Srimanta Pakhira

The O2 reduction reaction (ORR) is one promising reaction in clean energy conversion systems such as fuel cells, metal-air batteries, electrochemical reactions, etc. Pt shows excellent electrocatalytic activities for ORR,...

2015 ◽  
Vol 1 (1) ◽  
pp. e1400129 ◽  
Author(s):  
Jianglan Shui ◽  
Min Wang ◽  
Feng Du ◽  
Liming Dai

The availability of low-cost, efficient, and durable catalysts for oxygen reduction reaction (ORR) is a prerequisite for commercialization of the fuel cell technology. Along with intensive research efforts of more than half a century in developing nonprecious metal catalysts (NPMCs) to replace the expensive and scarce platinum-based catalysts, a new class of carbon-based, low-cost, metal-free ORR catalysts was demonstrated to show superior ORR performance to commercial platinum catalysts, particularly in alkaline electrolytes. However, their large-scale practical application in more popular acidic polymer electrolyte membrane (PEM) fuel cells remained elusive because they are often found to be less effective in acidic electrolytes, and no attempt has been made for a single PEM cell test. We demonstrated that rationally designed, metal-free, nitrogen-doped carbon nanotubes and their graphene composites exhibited significantly better long-term operational stabilities and comparable gravimetric power densities with respect to the best NPMC in acidic PEM cells. This work represents a major breakthrough in removing the bottlenecks to translate low-cost, metal-free, carbon-based ORR catalysts to commercial reality, and opens avenues for clean energy generation from affordable and durable fuel cells.


2017 ◽  
Vol 5 (16) ◽  
pp. 7257-7284 ◽  
Author(s):  
Hengcong Tao ◽  
Yunnan Gao ◽  
Neetu Talreja ◽  
Fen Guo ◽  
John Texter ◽  
...  

2D materials for the electrochemical oxygen reduction reaction, oxygen evolution reaction, hydrogen evolution reaction, and CO2reduction are critically reviewed.


2020 ◽  
Vol 12 (35) ◽  
pp. 39074-39081 ◽  
Author(s):  
Jihye Park ◽  
Zhihua Chen ◽  
Raul A. Flores ◽  
Gustaf Wallnerström ◽  
Ambarish Kulkarni ◽  
...  

Author(s):  
Mauro C dos Santos ◽  
Lanna Lucchetti ◽  
James Almeida ◽  
Pedro Alves da Silva Autreto

The 2-electron pathway of the oxygen reduction reaction is an unwanted process in the development of fuel cells. In contrast, it has gained the scientific community’s attention due to its...


2021 ◽  
Author(s):  
Xieweiyi Ye ◽  
Yakun Xue ◽  
Kaijia Li ◽  
Wen Tang ◽  
Xiao Han ◽  
...  

Improving the activity and durability of Pt-based electrocatalysts used in the acidic oxygen reduction reaction (ORR) is a great task for the commercial applications of proton-exchange membrane fuel cells. Alloying...


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