Parametric Study, Sensitivity Analysis, and Optimization of Polyol Synthesis of Silver Nanowires

2017 ◽  
Vol 6 (4) ◽  
pp. P132-P137 ◽  
Author(s):  
Shohreh Hemmati ◽  
Dale P. Barkey
2011 ◽  
Vol 11 (11) ◽  
pp. 4963-4969 ◽  
Author(s):  
Sahin Coskun ◽  
Burcu Aksoy ◽  
Husnu Emrah Unalan

RSC Advances ◽  
2015 ◽  
Vol 5 (38) ◽  
pp. 29872-29877 ◽  
Author(s):  
Kan-Sen Chou ◽  
Chung-Yen Hsu ◽  
Bo-Tau Liu

Silver nanowires were successfully synthesized by a polyol reduction method in a continuous-flow reactor with a yield of 2 g h−1.


2020 ◽  
Vol 2020 ◽  
pp. 1-19
Author(s):  
Christiana A. Filippou ◽  
Nicholas C. Kyriakides ◽  
Christis Z. Chrysostomou

A numerical study was conducted to investigate the in-plane behavior of a masonry-infilled reinforced concrete (RC) frame retrofitted with textile-reinforced mortar (TRM). A two-dimensional finite element model was developed using DIANA finite element analysis (FEA) software to simulate the 2 : 3 scaled three-storey masonry-infilled RC frame retrofitted with TRM that was studied experimentally in the past. The three-storey structure used in the test was with a nonseismic design and detailing, and was subjected to in-plane displacement-control cyclic loading. The current study evaluates the capabilities of a representative numerical model to simulate the results of the experimental test, and after the calibration of the numerical model sensitivity analysis and parametric study were performed. In order to create an accurate numerical model, suitable constitutive models, based on the smeared crack approach, were used to characterize the nonlinear response of concrete, masonry infill, and TRM. The calibration of the models was based on the experimental results or inverse fitting based on optimizing the simulation of the response. The numerical model proved capable of simulating the in-plane behavior of the retrofitted masonry-infilled RC frame with good accuracy in terms of initial stiffness, and its deterioration, shear capacity, and cracking patterns. The calibrated model was then used to perform sensitivity analysis in order to examine the influence of infill-frame interface properties (tangential and normal stiffness) on the behavior of the retrofitted infilled frame. The numerical results showed that the gap opening is influenced significantly by the stiffness of the interface. In addition, a parametric study was performed in order to evaluate the importance of the full-bond condition between the TRM and the masonry-infilled RC frame. The numerical results indicate that the composite action between the TRM and the masonry-infilled RC frame improves the global stiffness and lateral resistance of the infilled frame, and it reduces the gap opening between the masonry infill and the RC frame.


2019 ◽  
Vol 141 (2) ◽  
Author(s):  
Hermes Chirino ◽  
Ben Xu

Compared to solar photovoltaics, concentrated solar power (CSP) can store excessive solar thermal energy, extend the power generation, and levelize the mismatch between the demand and supply. Thermal energy storage (TES) system filled with phase change material (PCM) is a key to make CSP competitive, and it is also a promising indirect energy storage technique. It is of great interests to the solar thermal engineering community to apply the latent heat thermal energy storage (LHTES) system for large-scale CSP application, because PCMs can store more energy due to the latent heat during the melting/freezing process. Therefore, a comprehensive parametric analysis of LHTES system is necessary in order to identify the most sensitive ranges of various parameters to design the LHTES system with better systematic performances. In this study, unlike the existing parametric study based on dimensional parameters, we aimed to provide a more general analysis using dimensionless parameters; therefore, an 11-dimensionless-parameter space of LHTES system was developed, by considering the technical constraints (material properties and operation parameters), without economic constraints. The parametric study and sensitivity analysis were then performed based on a 1D enthalpy-based transient model, and the energy storage efficiency was used as the objective function to minimize the number of variables in the parameter space. It was found that Stanton number (St), dimensionless PCM radius (r/D), and void fraction (ε) are the three most important dimensionless parameters. It is expected that the discovery of this study can bring more discussions in the solar thermal engineering community about the implementation of LHTES system in CSP plant, to further explore the significances of these three dimensionless parameters to the operation of the LHTES system.


2020 ◽  
Vol 2020 ◽  
pp. 1-25 ◽  
Author(s):  
Shohreh Hemmati ◽  
Michael T. Harris ◽  
Dale P. Barkey

Silver nanowires (AgNWs) have a broad range of applications including nanoelectronics, energy conversion, health care, solar cells, touch screens, sensors and biosensors, wearable electronics, and drug delivery systems. As their characteristics depend strongly on their size and morphology, it is essential to find the optimal and most cost-effective synthesis method with precise control over the size and morphology of the wires. Various methods for AgNW synthesis have been reported along with process optimization and novel techniques to increase the yield and aspect ratios of synthesized AgNWs. The most promising processes for synthesis of AgNWs are wet chemical techniques, in which the polyol process is low cost and simple and provides high yield compared to other chemical methods. Reaction mechanism is one of the most important factors in strategies to control the process. Our purpose here is to provide an overview on the main findings regarding synthesis, preparation, and characterization of AgNWs. Recent efforts in the polyol synthesis of AgNWs are summarized with respect to product morphology and size, reaction conditions, and characterization techniques. The effect of essential factors such as reagent concentration and preparation, temperature, and reaction atmosphere that control the size, morphology, and yield of synthesized AgNWs is reviewed. Moreover, a review on the novel modified polyol process and reactor design such as continuous millifluidic and flow reactors to increase the yield of synthesized AgNWs on large scales is provided. The most recent proposed growth mechanisms and kinetics behind the polyol process are addressed. Finally, comparatively few available studies in green and sustainable development of 1D silver nanostructures through the application of natural products with inherent growth termination, stabilization, and capping characteristics are reviewed to provide an avenue to natural synthesis pathways to AgNWs. Future directions in both chemical and green synthesis approaches of AgNWs are addressed.


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