Cross-Linked Co3O4 Nanowalls Synthesized by Electrochemical Oxidation of Metallic Cobalt Layer for Oxygen Evolution

2012 ◽  
Vol 1 (2) ◽  
pp. H8-H10 ◽  
Author(s):  
N. Zhang ◽  
Y. Fan ◽  
H. Fan ◽  
H. Shao ◽  
J. Wang ◽  
...  
2018 ◽  
Vol 30 (17) ◽  
pp. 5941-5950 ◽  
Author(s):  
Su-Ho Cho ◽  
Ki Ro Yoon ◽  
Kihyun Shin ◽  
Ji-Won Jung ◽  
Chanhoon Kim ◽  
...  

2016 ◽  
Vol 3 (2) ◽  
pp. 236-242 ◽  
Author(s):  
Pengzuo Chen ◽  
Kun Xu ◽  
Yun Tong ◽  
Xiuling Li ◽  
Shi Tao ◽  
...  

Metallic cobalt nitrides arising from electron delocalization modulation have been proven to be highly efficient OER electrocatalysts.


Recycling ◽  
2018 ◽  
Vol 3 (3) ◽  
pp. 42 ◽  
Author(s):  
Eric Garcia ◽  
Hosane Taroco

In this paper, a new environmentally-friendly anode for hydrogen production was developed based on 430 stainless steel with an electrodeposited cobalt layer. The novelty of this work is the cobalt source once the electrodeposition bath was obtained from acid dissolution of a spent Li-ion battery cathode. The oxygen evolution reaction on electrodeposited cobalt in 1 M KOH is compatible with the E. Kobussen mechanism. The water discharge is related with reaction determinant step in low overpotential. The cobalt electrodeposition (3 Ccm−2) promotes a significant improvement of 430 stainless steel anodic properties for oxygen evolution reaction. When the overpotential reaches 370 mV, the density current for 430 stainless steel with electrodeposit cobalt is 19 mA·cm−2 against 0.80 mA·cm−2 for 430 stainless steel without cobalt. Thus, the anode construction described in this paper is an excellent option for Li-ion battery recycling.


Small ◽  
2021 ◽  
pp. 2102027
Author(s):  
Lei Yang ◽  
Hongye Qin ◽  
Zihao Dong ◽  
Tongzhou Wang ◽  
Guichang Wang ◽  
...  

Catalysts ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 844
Author(s):  
Dana Ao ◽  
Yue Shi ◽  
Shuyuan Li ◽  
Ying Chang ◽  
Aiju Xu ◽  
...  

Methanol oxidation (MOR) and urea oxidation (UOR) have been considered for new types of fuel cells, but the lack of highly active nonnoble metal catalysts restricts such cells. A NiCo-modified biomass carbon (milk as the carbon source)-based catalyst with a 3D structure is synthesized by using salt templates. The results show that 3D-C-NiCo (1:1) exhibits excellent MOR and UOR properties with a potential of 1.33 V vs. RHE and 1.35 V vs. RHE at 10 mA cm−2, respectively. MOR and UOR reactions not only can replace the oxygen evolution reaction (OER) in consumption of electrolytic water but also can effectively degrade wastewater pollution rich in methanol and urea.


2019 ◽  
Vol 84 (2) ◽  
pp. 187-198 ◽  
Author(s):  
Olesia Shmychkova ◽  
Tatiana Luk’yanenko ◽  
Larisa Dmirtikova ◽  
Alexander Velichenko

An investigation is reported on lead dioxide electrodeposition from methanesulfonate electrolytes additionally containing Ni2+ ions. It is shown that lead dioxide electrodes micromodified by nickel have different physico-chemical properties vs. nonmodified PbO2-anodes that are formed during the deposition. Electrocatalytical reactivity of electrodes involved in comparison to both the oxygen evolution, as well as to the electrooxidation of 2,4- dichlorophenoxyacetic (2,4-D) acid is investigated. Processes of electrochemical oxidation of 2,4-D on various materials occur qualitatively with the same mechanism and differ only in the rate. It is shown that the Ni-PbO2-anode possesses the highest electrocatalytic activity: the destruction rate of 2,4-D on it increases in 1.5 times in comparison with nonmodified lead dioxide. The COD of a 0.4 mM solution of 2,4-D, determined by the dichromate method, is 90.0 mg dm-3 which is 94 % of the theoretical value.


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