Long-term, Redox and Thermal Cycling Stability of Electrolyte Supported Cells

2019 ◽  
Vol 25 (2) ◽  
pp. 411-419 ◽  
Author(s):  
Andreas Glauche ◽  
Thomas Betz ◽  
Sindy Mosch ◽  
Nikolai Trofimenko ◽  
Mihails Kusnezoff
2021 ◽  
Vol 202 ◽  
pp. 113990
Author(s):  
Yanshuang Hao ◽  
Liqiang He ◽  
Shuai Ren ◽  
Yuanchao Ji ◽  
Xiaobing Ren

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Die Su ◽  
Yi Pei ◽  
Li Liu ◽  
Zhixiao Liu ◽  
Junfang Liu ◽  
...  

AbstractWearable and portable mobile phones play a critical role in the market, and one of the key technologies is the flexible electrode with high specific capacity and excellent mechanical flexibility. Herein, a wire-in-wire TiO2/C nanofibers (TiO2 ww/CN) film is synthesized via electrospinning with selenium as a structural inducer. The interconnected carbon network and unique wire-in-wire nanostructure cannot only improve electronic conductivity and induce effective charge transports, but also bring a superior mechanic flexibility. Ultimately, TiO2 ww/CN film shows outstanding electrochemical performance as free-standing electrodes in Li/K ion batteries. It shows a discharge capacity as high as 303 mAh g−1 at 5 A g−1 after 6000 cycles in Li half-cells, and the unique structure is well-reserved after long-term cycling. Moreover, even TiO2 has a large diffusion barrier of K+, TiO2 ww/CN film demonstrates excellent performance (259 mAh g−1 at 0.05 A g−1 after 1000 cycles) in K half-cells owing to extraordinary pseudocapacitive contribution. The Li/K full cells consisted of TiO2 ww/CN film anode and LiFePO4/Perylene-3,4,9,10-tetracarboxylic dianhydride cathode possess outstanding cycling stability and demonstrate practical application from lighting at least 19 LEDs. It is, therefore, expected that this material will find broad applications in portable and wearable Li/K-ion batteries.


2020 ◽  
Vol 846 ◽  
pp. 156437
Author(s):  
Yan Zhang ◽  
Bisai Li ◽  
Bin Tang ◽  
Zeen Yao ◽  
Xiongjie Zhang ◽  
...  

Author(s):  
Dustin Lee ◽  
Jing-Kai Lin ◽  
Chun-Huang Tsai ◽  
Szu-Han Wu ◽  
Yung-Neng Cheng ◽  
...  

The effects of isothermally long-term and thermal cycling tests on the performance of an ASC type commercial solid oxide fuel cell (SOFC) have been investigated. For the long-term test, the cells were tested over 5000 h in two stages, the first 3000 h and the followed 2000 h, under the different flow rates of hydrogen and air. Regarding the thermal cycling test, 60 cycles in total were also divided into two sections, the temperature ranges of 700 °C to 250 °C and 700 °C to 50 °C were applied for the every single cycle of first 30 cycles and the later 30 cycles, respectively. The results of long-term test show that the average degradation rates for the cell in the first 3000 h and the followed 2000 h under different flow rates of fuel and air are 1.16 and 2.64%/kh, respectively. However, there is only a degradation of 6.6% in voltage for the cell after 60 thermal cycling tests. In addition, it is found that many pores formed in the anode of the cell which caused by the agglomeration of Ni after long-term test. In contrast, the vertical cracks penetrating through the cathode of the cell and the in-plane cracks between the cathode and barrier layer of the cell formed due to the coefficient of thermal expansion (CTE) mismatch after 60 thermal cycling tests.


2018 ◽  
Vol 6 (4) ◽  
pp. 4688-4694 ◽  
Author(s):  
Jianbiao Wang ◽  
Lin Chen ◽  
Lingxing Zeng ◽  
Qiaohua Wei ◽  
Mingdeng Wei

2021 ◽  
Vol MA2021-01 (4) ◽  
pp. 246-246
Author(s):  
Chirayu Khunrugsa ◽  
Poramane Chiochan ◽  
Farkfun Duriyasart ◽  
Chonticha Jangsan ◽  
Pattranit Kullawattanapokin ◽  
...  

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