Electron Injection into Anodic Valve Metal Oxides

1972 ◽  
Vol 119 (11) ◽  
pp. 1531 ◽  
Author(s):  
N. I. Jaeger ◽  
G. P. Klein ◽  
B. Myrvaagnes
2012 ◽  
Vol 90 ◽  
pp. 59-61 ◽  
Author(s):  
M. Vasilopoulou ◽  
D.G. Georgiadou ◽  
L.C. Palilis ◽  
P. Argitis ◽  
S. Kennou ◽  
...  

ChemInform ◽  
2010 ◽  
Vol 24 (14) ◽  
pp. no-no
Author(s):  
E. A. MEULENKAMP ◽  
J. J. KELLY ◽  
G. BLASSE
Keyword(s):  

2018 ◽  
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pp. 28478-28490 ◽  
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Tanmay Banerjee ◽  
Sean P. Hill ◽  
M. Alejandra Hermosilla-Palacios ◽  
Brandon D. Piercy ◽  
Jess Haney ◽  
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1993 ◽  
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pp. 84-91 ◽  
Author(s):  
E. A. Meulenkamp ◽  
J. J. Kelly ◽  
G. Blasse
Keyword(s):  

Author(s):  
R. Ai ◽  
H.-J. Fan ◽  
L. D. Marks

It has been known for a long time that electron irradiation induces damage in maximal valence transition metal oxides such as TiO2, V2O5, and WO3, of which transition metal ions have an empty d-shell. This type of damage is excited by electronic transition and can be explained by the Knoteck-Feibelman mechanism (K-F mechanism). Although the K-F mechanism predicts that no damage should occur in transition metal oxides of which the transition metal ions have a partially filled d-shell, namely submaximal valence transition metal oxides, our recent study on ReO3 shows that submaximal valence transition metal oxides undergo damage during electron irradiation.ReO3 has a nearly cubic structure and contains a single unit in its cell: a = 3.73 Å, and α = 89°34'. TEM specimens were prepared by depositing dry powders onto a holey carbon film supported on a copper grid. Specimens were examined in Hitachi H-9000 and UHV H-9000 electron microscopes both operated at 300 keV accelerating voltage. The electron beam flux was maintained at about 10 A/cm2 during the observation.


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