Temperature Effects on Excited‐State Deactivation in Luminescent Photoelectrochemical Cells Employing Tellurium‐Doped Cadmium Sulfide Electrodes

1980 ◽  
Vol 127 (8) ◽  
pp. 314C-316C
Author(s):  
Bradley R. Karas
1983 ◽  
Vol 61 (5) ◽  
pp. 888-893 ◽  
Author(s):  
Marye Anne Fox ◽  
James R. Hohman ◽  
Prashant V. Kamat

Tin oxide and titanium dioxide semiconductor electrodes have been covalently modified by the attachment of functionalized olefins and arenes through surface silanation or via a cyanuric chloride linkage. The excited state and electrochemical properties of the molecules so attached are significantly affected by the semiconductor. Photocurrent measurements and time-resolved laser coulostatic monitoring have been employed to elucidate the mechanism of charge injection on these modified surfaces.


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