Effects of Temperature on Excited-State Descriptions of Luminescent Photoelectrochemical Cells Employing Tellurium-Doped Cadmium Sulfide Electrodes

Author(s):  
ARTHUR B. ELLIS ◽  
BRADLEY R. KARAS
1983 ◽  
Vol 61 (5) ◽  
pp. 888-893 ◽  
Author(s):  
Marye Anne Fox ◽  
James R. Hohman ◽  
Prashant V. Kamat

Tin oxide and titanium dioxide semiconductor electrodes have been covalently modified by the attachment of functionalized olefins and arenes through surface silanation or via a cyanuric chloride linkage. The excited state and electrochemical properties of the molecules so attached are significantly affected by the semiconductor. Photocurrent measurements and time-resolved laser coulostatic monitoring have been employed to elucidate the mechanism of charge injection on these modified surfaces.


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