Electrochemical Lithium Intercalation in  VO 2 (  B  )  in Aqueous Electrolytes

1996 ◽  
Vol 143 (9) ◽  
pp. 2730-2735 ◽  
Author(s):  
Meijie Zhang ◽  
J. R. Dahn
Keyword(s):  
Lithium Intercalation ◽  
Aqueous Electrolytes

Superionic Lithium Intercalation through 2 nm x 2 nm Columns in the Crystallographic Shear Phase Nb18W8O69

2019 ◽  
Author(s):  
Kent Griffith ◽  
Clare Grey
Keyword(s):  
High Performance ◽  
Rate Capability ◽  
Block Size ◽  
Lithium Intercalation ◽  
Resonance Spectroscopy ◽  
Complex Metal Oxides ◽  
Battery Electrode ◽  
Crystallographic Shear ◽  
Battery Material ◽  
First Time

Nb18W8O69 (9Nb2O5×8WO3) is the tungsten-rich end-member of the Wadsley–Roth crystallographic shear (cs) structures within the Nb2O5–WO3 series. It has the largest block size of any known, stable Wadsley–Roth phase, comprising 5 ´ 5 units of corner-shared MO6 octahedra between the shear planes, giving rise to 2 nm ´ 2 nm blocks. Rapid lithium intercalation is observed in this new candidate battery material and 7Li pulsed field gradient nuclear magnetic resonance spectroscopy – measured in a battery electrode for the first time at room temperature – reveals superionic lithium conductivity. In addition to its promising rate capability, Nb18W8O69 adds a piece to the larger picture of our understanding of high-performance Wadsley–Roth complex metal oxides.

scholarly journals 1.8 V Aqueous Symmetric Carbon-Based Supercapacitors with Agarose-Bound Activated Carbons in an Acidic Electrolyte

Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1731
Author(s):  
Chih-Chung Lai ◽  
Feng-Hao Hsu ◽  
Su-Yang Hsu ◽  
Ming-Jay Deng ◽  
Kueih-Tzu Lu ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Sulfuric Acid ◽  
Energy Density ◽  
Activated Carbons ◽  
High Energy ◽  
Aqueous Electrolytes ◽  
Alternative Material ◽  
Aqueous Cells ◽  
Acidic Electrolyte ◽  
Cycling Behavior

The specific energy of an aqueous carbon supercapacitor is generally small, resulting mainly from a narrow potential window of aqueous electrolytes. Here, we introduced agarose, an ecologically compatible polymer, as a novel binder to fabricate an activated carbon supercapacitor, enabling a wider potential window attributed to a high overpotential of the hydrogen-evolution reaction (HER) of agarose-bound activated carbons in sulfuric acid. Assembled symmetric aqueous cells can be galvanostatically cycled up to 1.8 V, attaining an enhanced energy density of 13.5 W h/kg (9.5 µW h/cm2) at 450 W/kg (315 µW/cm2). Furthermore, a great cycling behavior was obtained, with a 94.2% retention of capacitance after 10,000 cycles at 2 A/g. This work might guide the design of an alternative material for high-energy aqueous supercapacitors.

Electrolytes for Reversible Zinc Electrodeposition for Dynamic Windows

2021 ◽  
Author(s):  
Desmond C Madu ◽  
Shakirul M Islam ◽  
Hanqing Pan ◽  
Christopher Barile
Keyword(s):  
Aqueous Electrolytes ◽  
Zinc Electrodeposition ◽  
Metal Electrodeposition ◽  
Electronically Tunable

Reversible metal electrodeposition is a promising approach for the construction of dynamic windows with electronically tunable transmission. In this manuscript, we study a series of aqueous electrolytes that support reversible...

scholarly journals Understanding the capacitance of thin composite films based on conducting polymer and carbon nanostructures in aqueous electrolytes

2021 ◽  
pp. 138356
Author(s):  
Anita Cymann-Sachajdak ◽  
Magdalena Graczyk-Zajac ◽  
Grzegorz Trykowski ◽  
Monika Wilamowska-Zawłocka
Keyword(s):  
Conducting Polymer ◽  
Carbon Nanostructures ◽  
Composite Films ◽  
Aqueous Electrolytes

ChemInform Abstract: Sol-Gel Synthesis of Carbon/Silica Gel Electrodes for Lithium Intercalation.

ChemInform ◽  
2010 ◽  
Vol 31 (8) ◽  
pp. no-no
Author(s):  
Gerko Oskam ◽  
Peter C. Searson ◽  
T. Richard Jow
Keyword(s):  
Silica Gel ◽  
Sol Gel ◽  
Lithium Intercalation ◽  
Sol Gel Synthesis

Electrodeposited Au−Fe, Au−Ni, and Au−Co Alloy Nanoparticles from Aqueous Electrolytes

Langmuir ◽  
2002 ◽  
Vol 18 (8) ◽  
pp. 3226-3232 ◽  
Author(s):  
Da-ling Lu ◽  
Kazunari Domen ◽  
Ken-ichi Tanaka
Keyword(s):  
Aqueous Electrolytes ◽  
Alloy Nanoparticles
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