In-Operando Detection of Carbon Depositions and Carbon Formation Predictions for Industrial-Sized SOFCs Fueled with Synthetic Diesel Reformate

2017 ◽  
Vol 78 (1) ◽  
pp. 2451-2460 ◽  
Author(s):  
Vanja Subotic ◽  
Christoph Schluckner ◽  
Bernhard Stoeckl ◽  
David Reichholf ◽  
Vincent Lawlor ◽  
...  
Keyword(s):  
Carbon Formation ◽  
In Operando ◽  
Synthetic Diesel

scholarly journals What does carbon tolerant really mean? Operando vibrational studies of carbon accumulation on novel solid oxide fuel cell anodes prepared by infiltration

2020 ◽  
Vol 22 (17) ◽  
pp. 9815-9823
Author(s):  
Martha M. Welander ◽  
Daniel B. Drasbæk ◽  
Marie L. Traulsen ◽  
Bhaskar R. Sudireddy ◽  
Peter Holtappels ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Solid Oxide Fuel Cell ◽  
Carbon Accumulation ◽  
Solid Oxide ◽  
Oxide Fuel ◽  
Carbon Formation ◽  
Niobium Doped ◽  
Vibrational Studies ◽  
In Operando ◽  
Fuel Cell Anodes

In operando studies of carbon formation on novel niobium doped SrTiO3 based SOFC anodes.

scholarly journals Threshold catalytic onset of carbon formation on CeO2 during CO2 electrolysis: mechanism and inhibition

2019 ◽  
Vol 7 (25) ◽  
pp. 15233-15243 ◽  
Author(s):  
Jiayue Wang ◽  
Sean R. Bishop ◽  
Lixin Sun ◽  
Qiyang Lu ◽  
Gulin Vardar ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Carbon Deposition ◽  
Pair Formation ◽  
Carbon Formation ◽  
X Ray ◽  
In Operando ◽  
Co2 Electrolysis

Suppressing Ce3+–Ce3+ pair formation avoids carbon deposition on CeO2-based electrode during CO2 electrolysis, found by in operando X-ray photoelectron spectroscopy.

Stochastic Computing via In Operando Modulation of Rectification in Molecular Tunneling Junctions

2020 ◽  
Author(s):  
Xinkai Qiu ◽  
Sylvia Rousseva ◽  
Gang Ye ◽  
Jan C. Hummelen ◽  
Ryan Chiechi
Keyword(s):  
Self Assembly ◽  
Variable Temperature ◽  
Self Assembled Monolayers ◽  
Microfluidic Channels ◽  
Proof Of Concept ◽  
Glycol Ethers ◽  
Stochastic Computing ◽  
Assembled Monolayers ◽  
In Operando ◽  
Tunneling Junctions

This paper describes the reconfiguration of molecular tunneling junctions during operation via the self-assembly of bilayers of glycol ethers. We use well-established functional groups to modulate the magnitude and direction of rectification in assembled tunneling junctions by exposing them to solutions containing different glycol ethers. Variable-temperature measurements establish that rectification occurs by a bias-dependent tunneling-hopping mechanism and that glycol ethers, beside being an unusually efficient tunneling medium, behave identically to alkanes. We fabricated memory bits from crossbar junctions prepared by injecting eutectic Ga-In into microfluidic channels. Two 8-bit registers were able to perform logical AND operations on bit strings encoded into chemical packets as microfluidic droplets that alter the composition of the crossbar junctions through self-assembly to effect memristor-like properties. This proof of concept work demonstrates the potential for fieldable molecular-electronic devices based on tunneling junctions of self-assembled monolayers and bilayers.

Effect of Ni incorporation in cobalt oxide lattice on carbon formation during ethanol decomposition reaction

2019 ◽  
Vol 254 ◽  
pp. 300-311 ◽  
Author(s):  
Anchu Ashok ◽  
Anand Kumar ◽  
Janarthanan Ponraj ◽  
Said A. Mansour ◽  
Faris Tarlochan
Keyword(s):  
Cobalt Oxide ◽  
Decomposition Reaction ◽  
Carbon Formation ◽  
Ethanol Decomposition

scholarly journals Aging of atmospheric aerosols and the role of iron in catalyzing brown carbon formation

2021 ◽  
Author(s):  
Hind A. A. Al-Abadleh
Keyword(s):  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Atmospheric Aerosols ◽  
Secondary Organic Aerosol ◽  
Organic Aerosol ◽  
Atmospheric Oxidation ◽  
Carbon Formation ◽  
Brown Carbon ◽  
Volatile Organic

Extensive research has been done on the processes that lead to the formation of secondary organic aerosol (SOA) including atmospheric oxidation of volatile organic compounds (VOCs) from biogenic and anthropogenic...

scholarly journals Corrosion of ternary borosilicate glass in acidic solution studied in operando by fluid-cell Raman spectroscopy

2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Christoph Lenting ◽  
Thorsten Geisler
Keyword(s):  
Raman Spectroscopy ◽  
Nuclear Waste ◽  
Numerical Models ◽  
Adsorbed Water ◽  
Corrosion Mechanism ◽  
Borosilicate Glasses ◽  
Long Term Storage ◽  
In Operando ◽  
High Level ◽  
Fluid Cell

AbstractFluid-cell Raman spectroscopy is a space and time-resolving application allowing in operando studies of dynamic processes during solution–solid interactions. A currently heavily debated example is the corrosion mechanism of borosilicate glasses, which are the favoured material for the immobilization of high-level nuclear waste. With an upgraded fluid-cell lid design made entirely from the glass sample itself, we present the polymerization of the surface alteration layer over time in an initially acidic environment, including the differentiation between pore and surface-adsorbed water within it. Our results support an interface-coupled dissolution-precipitation model, which opposes traditional ion-exchange models for the corrosion mechanism. A sound description of the corrosion mechanism is essential for reliable numerical models to predict the corrosion rate of nuclear waste glasses during long-term storage in a geological repository.

A rigorous electrochemical ammonia electrolysis protocol with in-operando quantitative analysis

2021 ◽  
Author(s):  
Yejin Yang ◽  
Jeongwon Kim ◽  
Hyoi Jo ◽  
Arim Seong ◽  
Minzae Lee ◽  
...  
Keyword(s):  
Quantitative Analysis ◽  
Hydrogen Production ◽  
Hydrogen Storage ◽  
Liquid Fuel ◽  
High Capacity ◽  
In Operando

Ammonia has emerged as attractive liquid fuel for hydrogen production owing to its facile transportation, high capacity of hydrogen storage, and ecofriendly environmental products (N2 and H2). Moreover, the electrolysis...

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