scholarly journals Electrochemical Performance of Lithium-Ion Capacitors Using Pre-Lithiated Multiwalled Carbon Nanotubes as Anode

NANO ◽  
2017 ◽  
Vol 12 (04) ◽  
pp. 1750051 ◽  
Author(s):  
Manyuan Cai ◽  
Xiaogang Sun ◽  
Yanyan Nie ◽  
Wei Chen ◽  
Zhiwen Qiu ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Energy Density ◽  
Electrochemical Performance ◽  
Multiwalled Carbon Nanotubes ◽  
Current Density ◽  
Lithium Ion ◽  
Multiwalled Carbon ◽  
Charge Discharge

Pre-lithiated multiwalled carbon nanotube anode was prepared by internal short circuit approach(ISC) for 5[Formula: see text]min, 30[Formula: see text]min, 60[Formula: see text]min and 120[Formula: see text]min respectively. Lithium ion capacitors (LICs) were assembled by using pre-lithiated multiwalled carbon nanotubes as anodes and activated carbon (AC) as cathodes. The structure of multiwalled carbon nanotubes and electrodes were investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The electrochemical performance of pre-lithiated multiwalled carbon nanotube electrodes and pristine carbon nanotube electrodes were tested by galvanostatic charge/discharge and electrochemical impedance. The results indicated that pre-lithiation carbon nanotubes greatly improved the charge/discharge performance of LICs. The energy density was four times than conventional electric double-layer capacitors (EDLCs) at the current density of 100[Formula: see text]mA/g. The LICs achieved a specific capacitance of 59.3[Formula: see text]F/g at the current density of 100[Formula: see text]mA/g with 60[Formula: see text]min pre-lithiatiation process. The maximum energy density and power density was 96[Formula: see text]Wh/kg and 4035[Formula: see text]W/kg, respectively. The energy density still remained about 89.0% after 1000 cycles. The LIC showed excellent supercapacitor performance.

Neuron-like polyelectrolyte–carbon nanotube composites for ultra-high loading of metal nanoparticles

2014 ◽  
Vol 38 (10) ◽  
pp. 4799-4806 ◽  
Author(s):  
Md. Shahinul Islam ◽  
Won San Choi ◽  
Tae Sung Bae ◽  
Young Boo Lee ◽  
Ha-Jin Lee
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Metal Nanoparticles ◽  
Multiwalled Carbon Nanotubes ◽  
High Loading ◽  
Multiwalled Carbon ◽  
Simple Protocol ◽  
Nanotube Composites ◽  
Carbon Nanotube Composites

We report a simple protocol for the fabrication of multiwalled carbon nanotubes (MWCNTs) with a neuron-like structure for loading ultra-high densities of metal nanoparticles (NPs).

SILK FIBROIN FILMS CRYSTALLIZED BY MULTIWALLED CARBON NANOTUBES

2008 ◽  
Vol 22 (09n11) ◽  
pp. 1807-1812 ◽  
Author(s):  
H.-S. KIM ◽  
W.-I. PARK ◽  
Y. KIM ◽  
H.-J. JIN
Keyword(s):  
Electron Microscopy ◽  
Carbon Nanotubes ◽  
Multiwalled Carbon Nanotubes ◽  
Silk Fibroin ◽  
Composite Films ◽  
Tensile Modulus ◽  
Multiwalled Carbon ◽  
Regenerated Silk Fibroin ◽  
Silk Films ◽  
Β Sheet

Silk films prepared from regenerated silk fibroin are normally stabilized by β-sheet formation through the use of solvents (methanol, water etc.). Herein, we report a new method of preparing water-stable films without a β-sheet conformation from regenerated silk fibroin solutions by incorporating a small amount (0.2 wt%) of multiwalled carbon nanotubes (MWCNTs). To extend the biomaterial utility of silk proteins, forming water-stable silk-based materials with enhanced mechanical properties is essential. Scanning electron microscopy and transmission electron microscopy were used to observe the morphology of the MWCNT-incorporated silk films. The wide-angle X-ray diffraction provided clear evidence of the crystallization of the silk fibroin induced by MWCNT in the composite films without any additional annealing processing. The tensile modulus and strength of the composite films were improved by 108% and 51%, respectively, by the incorporation of 0.2 wt% of MWCNTs, as compared with those of the pure silk films. The method described in this study will provide an alternative means of crystallizing silk fibroin films without using an organic solvent or blending with any other polymers, which may be important in biomedical applications.

scholarly journals Autonomous self-healing multiwalled carbon nanotube nanocomposites with piezoresistive effect

RSC Advances ◽  
2017 ◽  
Vol 7 (33) ◽  
pp. 20422-20429 ◽  
Author(s):  
Tongfei Wu ◽  
Biqiong Chen
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Multiwalled Carbon Nanotubes ◽  
Multiwalled Carbon Nanotube ◽  
Self Healing ◽  
Multiwalled Carbon ◽  
Piezoresistive Effect

Viscoelastic rubber reinforced by multiwalled carbon nanotubes exhibited rapid, autonomous, mechanically and electrically self-healing properties and piezoresistive behavior.

scholarly journals Surface Properties of Silica–MWCNTs/PDMS Composite Coatings Deposited on Plasma Activated Glass Supports

2021 ◽  
Vol 11 (19) ◽  
pp. 9256
Author(s):  
Michał Chodkowski ◽  
Iryna Ya. Sulym ◽  
Konrad Terpiłowski ◽  
Dariusz Sternik
Keyword(s):  
Electron Microscopy ◽  
Carbon Nanotubes ◽  
Scanning Electron Microscopy ◽  
Multiwalled Carbon Nanotubes ◽  
Composite Coatings ◽  
Thermal Analyses ◽  
Sol Gel ◽  
Visible Range ◽  
Multiwalled Carbon ◽  
Scanning Electron

In this paper, we focus on fabrication and physicochemical properties investigations of silica–multiwalled carbon nanotubes/poly(dimethylsiloxane) composite coatings deposited on the glass supports activated by cold plasma. Air or argon was used as the carrier gas in the plasma process. Multiwalled carbon nanotubes were modified with poly(dimethylsiloxane) in order to impart their hydrophobicity. The silica–multiwalled carbon nanotubes/poly(dimethylsiloxane) nanocomposite was synthesized using the sol–gel technique with acid-assisted tetraethyl orthosilicate hydrolysis. The stability and the zeta potential of the obtained suspension were evaluated. Then, the product was dried and used as a filler in another sol–gel process, which led to the coating application via the dip-coating method. The substrates were exposed to the hexamethyldisilazane vapors in order to improve their hydrophobicity. The obtained surfaces were characterized by the wettability measurements and surface free energy determination as well as optical profilometry, scanning electron microscopy, and transmittance measurements. In addition, the thermal analyses of the carbon nanotubes as well as coatings were made. It was found that rough and hydrophobic coatings were obtained with a high transmittance in the visible range. They are characterized by the water contact angle larger than 90 degrees and the transmission at the level of 95%. The X-ray diffraction studies as well as scanning electron microscopy images confirmed the chemical and structural compositions of the coatings. They are thermally stable at the temperature up to 250 °C. Moreover, the thermal analysis showed that the obtained composite material has greater thermal resistance than the pure nanotubes.

Covalent functionalization of multiwalled carbon nanotubes with super-hydrophobic property

2018 ◽  
Vol 38 (6) ◽  
pp. 537-543 ◽  
Author(s):  
Minghua Li ◽  
Zhiyuan Xu ◽  
Jinyang Chen ◽  
San-E Zhu
Keyword(s):  
Electron Microscopy ◽  
Carbon Nanotubes ◽  
Multiwalled Carbon Nanotubes ◽  
Chemical Interaction ◽  
Hydrophobic Property ◽  
Covalent Functionalization ◽  
Multiwalled Carbon ◽  
Surface Contact Angle ◽  
Loading Ratio ◽  
Functionalized Mwcnts

AbstractSurface covalent functionalization of multiwalled carbon nanotubes (MWCNTs) is carried out by coupling of isocyanate-decorated MWCNTs with hydroxyl-terminated polydimethylsiloxane (HTPS), resulting in the formation of functionalized MWCNTs. Thermogravimetry analysis (TGA) of functionalized MWCNTs-1,2,3 exhibits the similar peaks in the temperature range of 200–500°C, which all correspond to the degradation of chemically grafted polyurethane on the nanotube surface. Field emission scanning electron microscopy (FE-SEM) reveals that as the polyurethane grafted onto the surface of MWCNTs loading ratio increased, the surface roughness of the MWCNTs is reduced. The chemical interaction of HTPS with isocyanate-decorated nanotube surface using the grafting-to strategy in a one-step process is confirmed by Fourier transform infrared spectroscopy (FT-IR). The surface contact angle of MWCNTs-3 with the largest content of polyurethane reached 171°, indicating that the surface covered with low surface energy polyurethane shows a super-hydrophobic property. The good dispersion of polyurethane-functionalized MWCNT-3, particularly at high content in the NR nanocomposites, is evidenced from transmission electron microscopy (TEM).

scholarly journals Fabrication of cm scale buckypapers of horizontally aligned multiwalled carbon nanotubes highly filled with Fe3C: the key roles of Cl and Ar-flow rates

2016 ◽  
Vol 52 (22) ◽  
pp. 4195-4198 ◽  
Author(s):  
Filippo S. Boi ◽  
Jian Guo ◽  
Shanling Wang ◽  
Yi He ◽  
Gang Xiang ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Multiwalled Carbon Nanotubes ◽  
Multiwalled Carbon ◽  
Flow Rates

A key challenge in the fabrication of ferromagnetically filled carbon-nanotube buckypapers in the presence of Cl-radicals is the achievement of a preferential horizontal nanotube-alignment.

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