Mn(OAc)3-promoted hydroxylation of α-carbomethoxy-γ-lactones by molecular oxygen
The Mn(OAc)3-mediated hydroxylation of a series of α-carbomethoxy-γ-lactones by molecular oxygen is described. The reaction is regio- and stereoselective and gives α-carbomethoxy-α-hydroxy-γ-lactones. Key words: manganese acetate, γ-lactones, hydroxylation, molecular oxygen.
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1970 ◽
Vol 19
(2)
◽
pp. 181-187
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1970 ◽
Vol 19
(1)
◽
pp. 50-53
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